CO2 emission from combustion fossil fuels is considered as the primary factor in the global warming. Different methods for separation CO2 from combustion flue gases are extensively used across the world. The aim of this study is to analyze the most important technological solutions of CO2 separation. For this reason chemical absorption, physical absorption, adsorption approach, membrane filtration and cryogenic process were researched. Concluding, selection of the right method for carbon dioxide capture separation is a complex issue and a range of technological and economic factors should be taken into consideration prior to application on the industrial scale.