In the processes of coal mining, preparation and combustion, the rejects and by-products are generated. These are, among others, the rejects from the coal washing and dry deshaling processes as well as the coal combustion by-products (fly ash and slag). Current legal and industry regulations recommend determining the content of mercury in them. The regulations also define the acceptable content of mercury. The aim of the paper was to determine the mercury content in the rejects derived from the coal cleaning processes as well as in the combustion by-products in respect of their utilization. The mercury content in the representative samples of the rejects derived from the coal washing and dry deshaling processes as well as in the coal combustion by products derived from 8 coal-fired boilers was determined. The mercury content in the rejects from the coal washing process varied from 54 to 245 μg/kg, (the average of 98 μg/kg) and in the rejects from the dry deshaling process it varied from 76 to 310 μg/kg (the average of 148 μg/kg). The mercury content in the fly ash varied from 70 to 1420 μg/kg, (the average of 567 μg/kg) and in the slag it varied from 8 to 58 μg/kg (the average of 21 μg/kg). At the moment, in light of the regulations from the point of view of mercury content in the rejects from the coal preparation processes and in the coal combustion by-products, there are no significant barriers determining the way of their utilization. Nevertheless, in the future, regulations limiting the maximum content of mercury as well as the acceptable amount of leachable mercury may be introduced. Therefore, preparing for this situation by developing other alternative methods of using the rejects and by-products is recommended.
The article presents current state of the structure of hard coal enrichment plants in Poland, taking the capacity, the range of grain enrichment and the type of equipment used into account. This data were presented in a tabular format for each Polish Coal Company operating on the Polish market. The article was also present simplified: flow sheet of the steam and coking coal enrichment system. Based on the presented data, the planned needs and trends were described in terms of increasing production efficiency, minimizing water consumption and safety of work. A list of research and development works which must be undertaken were also presented as well as factors determining the technological development of the processing plants.
Coal reserves in the Czech Republic are estimated to be 10 billion tons – hard coal about 37%, brown coal about 60% and lignite 3%. Hard coal is produced in Northern Moravia. In 2017 the production of hard coal was 5.5 million tons. Brown coal is mined in North-Western Bohemia − the production of brown coal in 2017 was 38.1 million tons. Significant quantities of hard coal are exported to: Slovakia, Austria, Germany and Hungary. In accordance with the National Energy Policy, coal will remain the main source of energy in the country in the future, despite the increased use of nuclear energy and natural gas. The government expects that in 2030 energy from coal will account for 30.5% of energy produced. There are five coal companies in the Czech Republic: OKD, a.s., the only hard coal producer and four brown coal mining companies: Severočeské Doly a.s., owned by ČEZ, the largest producer of brown coal, Vršanská uhelná a.s., with coal resources until 2055, Severní energetická a.s. with the largest brown coal reserves in the Czech Republic and Sokolovska uhelná a.s., the smallest mining company extracting lignite. OKD operates coal in two mines Kopalnia Důlní závod 1 – (consists of three mines: ČSA Mine, Lazy Mine, Darkov Mine) and Mine Důlní závod 2 (ttwo mines Sever, Jih). The article also presents a pro-ecological solution for the management of waste heaps after coal enrichment – a plant for the enrichment of coal waste from the Hermanice heap.
In recent years, the Budryk Coal Mine (KWK Budryk) reached the mining depth of 1300 m, where there is about 160 million tons of coal, including 120 million tons of coking coal (type 35). The task of the Coal Processing Plant complex modernization was undertaken. The article presents the modernization of coal screening, classification and dewatering systems at the KWK Budryk Processing Plant and the implementation of screening of PROGRESS ECO sp. z o.o. SK. The modernization project defined the following technical requirements for all screens in the KWK Budryk Coal Processing Plant extension project: - Vibrating screens with a linear type drive with a drive unit placed on the drive beam of the trommel screen in the form of vibration generators; - Screen drives equipped with a starting-braking device; - The use of main screen drive bearings with a nominal service life of at least 40,000 man-hours; - All work surfaces made of materials with a strength of up to 80 mm grain and abrasion resistance; side strips and sieves fixed in a way ensuring trouble-free operation, and at the same time quick and easy replacement; - Sheets made of stainless steel; - Side walls, beams and other elements attached to them connected with screws using a system protecting against corrosion and elements separation; - The use of a work parameters monitoring and visualization system, i.e. - pitch of the riddle, - bearing operating temperatures and the condition of their wear. Three types of screens were provided: - PWP1-1Z-2,8x6,0 screeners that alternatively perform sieving or desliming processes, - PWP1-2.4x6.0 screening machines performing desliming processes, - PWP1-2.0x6.0 screens performing the classification process.
Thin coal seams found in the Lions Cove Formation, Polonia Glacier Group (Middle Eocene, upper part) at King George Bay, King George Island (South Shetland Islands, West Antarctica), represent lustrous (vitrine) brown-coal metaphase. The coal from the lower seam represents carbonized wood, probably angiosperm, that from the upper ones originated due to accumulation of branches or larger wood fragments and leaf remains. These coals are slightly older than metaxylite brown coal previously described from Admiralty Bay on King George Island, and dated at Eocene-Oligocene boundary. Both coal occurrences are evidences for a warm climate which prevailed in the Antarctic Peninsula sector during the Arctowski Interglacial (ca 50—32 Ma).
The possibility of the application of nontraditional method of greenhouse gas utilization by the injection of CO2 (sequestration) into porous geological deposits, treated as unconventional gas collectors, requires the fulfillment of basic criteria such as the impact on the environment and long term storage. The important issue is the physical behavior of the deposit during the porous structure saturation phase by carbon dioxide. What should be mentioned first and foremost is: the availability of CO2 transport along the porous structure and adsorption capacity. The work presents the results of water vapor sorption on coal samples from selected Hard Coal Mines of a differentiated carbon content. The received results were presented in the form of sorption and desorption isotherms performed in a temperature of 303 K. It was additionally described with a BET adsorption isotherm. Based on sorption data, a specific surface area was calculated, in accordance with BET theory. The amount of the adsorbed water vapor molecules for the analyzed coal samples was dependent on the degree of metamorphism. The obtained isotherms can be described as type II according to the BET classification. Volumetric type apparatus -adsorption- microburette liquid was used for the sorption experiments. Water vapor sorption in relation to coals allows for the quantitative determination of primary adsorption centers as a measure of adsorbed molecule interconnections with the adsorbent surface. Based on the BET adsorption equation, out of water vapor isotherms, the amount of adsorption active centers, which potentially may take part in CO2 adsorption in coal seams during injection of this gas, was determined. The sorption capacity of coals is determined by the degree of metamorphism, which also has very large impact on the sorption capacity of the deposit.
Volatility is one of the most characteristic features in the all market types. In the raw material market, including the bituminous coal market, volatility is visible in the supply and demand variations, in consequence in the prices fluctuations. Market actors usually having opposite interests, for example buy low, sell high, are vitally interested in identifying the causes of these fluctuations. Some of the factors causing the market fluctuations are quite common, others are more complicated because of circumstances complexity. This article attempts to examine the relationships between bituminous coal fines prices and the economic situation. Given the complexity of the issue, the research area has been narrowed down – territorially to Poland and temporarily – to the present decade. The average prices of coal fines in Poland are presented by the Industrial Development Agency (Agencję Rozwoju Przemysłu SA) in the form of two indices: PSCMI 1 and PSCMI 2. Both indices are calculated based on the prices of pattern bituminous coal, produced by domestic manufacturers and sold on domestic markets, the energy and heat market respectively. Statistical methods, because of their quantitative nature, are important in identifying the correlations between the coal fines prices and economic conditions. Therefore, the article presents examples of relatively strong linear correlations between the PSCMI 1 and/or PSCMI 2 and some indicators of the economic situation.
The study included bituminous coal seams (30 samples coal from the Bogdanka and Chełm deposits) of the Lublin Formation, the most coal-bearing strata in the best developed and recognized in terms of mining parts of the Lublin Coal Basin in Poland. High phosphorus concentrations in coal of the Lublin Formation were found (1375 g/Mg) as well as P2O5 in coal ash (2.267 wt%). The phosphorus contents in coal and coal ash from the 385 and 391 coal seams in the area of the Lubelski Coal Bogdanka Mine and in the area of its SE neighbor is the highest (max. 2.644 wt. % in coal and 6.055 wt. % of P2O5 in coal ash). It has been shown that mineral matter effectively affects phosphorus contents in coal and coal ash. At the same time, phosphate minerals (probably apatite and crandallite) present in kaolinite aggregates of tonsteins contain the most of phosphorus and have the greatest impact on the average P content in the 382, 385, 387, and 391. The secondary source of phosphorus in these coal seams and main source of phosphorus in these coal deposits that do not contain mineral matter of pyroclastic origin (378, 389, 394) may be clay minerals, which absorbed phosphorus compounds derived from organic matter released during coalification. Phosphorus-rich ash from the combustion of the Lublin Formation coal tend to be environmentally beneficial to the environment and also useful for improving the soil quality. Due to the low degree of coalification and high content of phosphorus in coal, this coals of little use for coking.
Explosions of coal dust are a major safety concern within the coal mining industry. The explosion and subsequent fires caused by coal dust can result in significant property damage, loss of life in underground coal mines and damage to coal processing facilities. The United States Bureau of Mines conducted research on coal dust explosions until 1996 when it was dissolved. In the following years, the American Society for Testing and Materials (ASTM) developed a test standard, ASTM E1226, to provide a standard test method characterizing the “explosibility” of particulate solids of combustible materials suspended in air. The research presented herein investigates the explosive characteristic of Pulverized Pittsburgh Coal dust using the ASTM E1226-12 test standard. The explosibility characteristics include: maximum explosion pressure, (Pmax); maximum rate of pressure rise, (dP/dt)max; and explosibility index, (Kst). Nine Pulverized Pittsburgh Coal dust concentrations, ranging from 30 to 1,500 g/m3, were tested in a 20-Liter Siwek Sphere. The newly recorded dust explosibility characteristics are then compared to explosibility characteristics published by the Bureau of Mines in their 20 liter vessel and procedure predating ASTM E1126-12. The information presented in this paper will allow for structures and devices to be built to protect people from the effects of coal dust explosions.
Gasification technology is often seen as a synonym for the clean and efficient processing of solid fuels into combustible gas containing mainly carbon monoxide and hydrogen, the two basic components of synthesis gas. First and foremost, the facts that gas may be cleaned and that a mixture with any composition may be prepared in a relatively easy and inexpensive manner influence the possibility of using gas produced in the energy and chemical industries. In the energy industry, gas may be used directly to generate heat and electricity in the systems of a steam power plant or in combined cycle systems. It is also possible to effectively separate CO2 from the system. However, in chemistry, synthesis gas may be used to produce hydrogen, methanol, synthetic gasolines, and other chemical products. The raw material for gasification is full-quality pulverized coal, but a possibility of processing low-quality sludges, combustible fractions separated from municipal waste as well as industrial waste also exists. Despite such a wide application of technology and undoubted advantages thereof, making investment decisions is still subject to high uncertainty. The paper presents the main technological applications of gasification and analyzes the economic effectiveness thereof. In this context, significant challanges for the industrial implementation of this technology are discussed
In the paper, on the basis of our studies and the available literature data, a model of changes in the number of active centers corresponding to the structure of the reactive coal particle has been developed. A new distribution function that links the specific surface area of a particle with its porosity and reaction degree has been proposed. An equation for estimation of changes in this parameter during the reaction, on the basis of the initial value, has been presented. In the range of our data and the analysis of the literature data, the model, with satisfactory accuracy, describes internal structural changes of coal and coal char particles. The present results may constitute a basis for complex modelling of coal conversion processes. Based on the results it was found that the total active centres are related to the internal surface area and porosity of the particle. For a specific coal type, this value depends on the porosity, true density and size of the particle. Changes in total active centres, when these structural properties during thermal conversion of coal are considered, are described in equations.
The article presents the challenges faced by the hard coal mining sector in Poland. The biggest challenge results from a decrease in the demand for coal, which was triggered mainly by the climate policy, including the tightening of environmental standards and an increase in the efficiency of generating units. The fundamental model of the MRÓWKA domestic coal market has been described. The model allows for determining the marginal price of a given fuel for a given generating unit in the system and the optimal mix of fuels to meet the energy demand. The results of the model calculations for the baseline and alternative scenarios were presented. It has been shown that the optimal distribution of coal mining capacities promotes the import of the discussed fuel in the north-eastern part of the country and that the individual customer valuation leads to a decrease in the competitiveness of the units located in the central-western part of the country. The paper also discusses the potential impact of the domestic oversupply on the balance sheet and the price of coal. According to the obtained results and the basic laws of economics, an oversupply of coal leads to a decrease in prices. For the analyzed variants, the dependence of prices was estimated at PLN 0.0308 / GJ for every million tons of the oversupply. The fall in prices is largely due to the fuel supply to units located close to ports or railway border crossings. Based on the presented arguments it can be concluded that the maximization of financial result from the extraction of coal should be based on an analysis taking incremental changes in fuel prices into account.
Control of the technological processes of coal enrichment takes place in the presence of wide disturbances. Thus, one of the basic tasks of the coal enrichment process control systems is the stabilization of coal quality parameters at a preset level. An important problem is the choice of the controller which is robust for a variety of disturbances. The tuning of the controller parameters is no less important in the control process . Many methods of tuning the controller use the dynamic characteristics of the controlled process (dynamic model of the controlled object). Based on many studies it was found that the dynamics of many processes of coal enrichment can be represented by a dynamic model with properties of the inertial element with a time delay. The identification of object parameters (including the time constant) in industrial conditions is usually performed during normal operation (with the influence of disturbances) from this reason, determined parameters of the dynamic model may differ from the parameters of the actual process. The control system with controller parameters tuned on the basis of such a model may not satisfy the assumed control quality requirements. In the paper, the analysis of the influence of changes in object model parameters in the course of the controlled value has been carried out. Research on the controller settings calculated according to parameters T and τ were carried out on objects with other parameter values. In the studies, a sensitivity analysis method was used. The sensitivity analysis for the three methods of tuning the PI controller for the coal enrichment processes control systems characterized by dynamic properties of the inertial element with time delay has been presented. Considerations are performed at various parameters of the object on the basis of the response of the control system for a constant value of set point. The assessment of considered tuning methods based on selected indices of control quality have been implemented.
The analysis of leaching behavior of harmful substances, such as arsenic, is one of the parameters of risk assessment resulting from the storage or economic use of coal waste. The leachability depends both on the environmental conditions of the storage area as well as on the properties of the waste material itself. There are a number of leaching tests that allow to model specific conditions or measure the specific properties of the leaching process. The conducted research aimed at comparing two methods with different application assumptions. The study of arsenic leaching from waste from the hard coal enrichment process was carried out in accordance with the Polish PN-EN 12457 standard and the US TCLP procedure. The leaching results obtained with both methods did not exceed the limit values of this parameter, defined in the Polish law. Both methods were also characterized by the good repeatability of the results. The use of an acetic acid solution (TCLP method) resulted in three times higher arsenic leaching from the examined waste compared to the use of deionized water as a leaching fluid (method PN-EN 12457). Therefore, the use of organic acid tests for mining waste intended for storage with municipal waste should be considered, as the results of the basic test based on clean water leaching may be inadequate to the actual leaching of arsenic under such environmental conditions.
The paper presents selected issues related to the development of international coal markets. World consumption of coal dropped for the second year in a row in 2016, primarily due to lower demand from China and the U S. The share of coal in global primary energy consumption decreased to 28%. World coal production accounted to 3.66 billion toe and it was lower by 6.2% when compared to the previous year. More than 60% of this decline took place in China. The decline in global production was more than four times higher than the decrease in consumption. The sufficiency of world resources of coal are estimated at 153 years – that is three times more than the sufficiency of oil and gas resources. After several years of decline, coal prices increased by 77% in 2016. The current spot prices are at the level of $80/t and are close to the 2014 prices. In the European market, after the first half of the year, coal prices reached the level of around 66% higher than in the same period of the last year. The average price in the first half amounted to PLN 12.6/GJ, which is close to the 2012 prices. The share of spot trade in the total purchase amount accounted to approx. 20%. Prices in futures contracts can be estimated on the basis of the Japan-Australia contracts prices and prices in supplies to power plants located in Germany. On average, the prices in supplies to these power plants were higher by approximately 9% in the years 2010–2016 and prices in Australia – Japan contracts were 12% higher than CIF ARA prices in 2017. Global energy coal trade reached about 1.012 billion tonnes in 2016. In 2019, a decline by 4.8% is expected primarily due to the expected reduction in the demand in major importing countries in Asia.
Coal production in 2018 increased by 3.3% and amounted to 7.81 million tons. Compared to 2010, it increased by 620 million tons. The structure of coal production in the world is very stable in the analyzed period of 2010–2018. Steam coal dominates in production with a share of 77%. Since 1990, the share of coal in the consumption of primary energy carriers has fallen by 3% in the global economy. In the EU, the share of coal in the consumption of primary energy carriers is more than twice lower than in the world, and in 2018 amounted to 13%. BP estimates the sufficiency of coal proven reserves based on 2018 data for the next 132 years. For oil and gas, they are estimated at 51 years. The decline in hard coal production in the European U nion can be dated almost continuously since 1990, which has decreased by 74%. In 2018, 74 million tons of coal were produced in the EU. In 2018, hard coal consumption in EU countries dropped to 226 million tons, i.e. by 20.6%. In 2018, global trade in steam coal amounted to 1.14 billion tons. The situation in China is crucial for the international coal market. The slight change in the import policy of this country significantly affects the situation in international trade in steam coal. In 2019, coal prices (at Newcastle, Richards Bay, ARA ports) dropped by an average of 23 U SD/ton. The average decreases for these three indices were 33%. The prices of steam coal in the forecasts presented in the paper are under pressure of the falling demand.
The purpose of the article was to characterize the international steam coal market based on the latest available data. The information goes back to the first half of 2018. The article focuses on the description of the three largest exporters and importers of steam coal. Representatives in these categories were selected using the latest global statistics on 2017. In 2017, global production of steam coal amounted to 5.68 billion tons and exceeded production in 2016 by 4%. For several years, invariably the world’s leading exporters of steam coal are: Indonesia, Australia and Russia. In total, these three countries in 2017 supplied 73% of steam coal to the international market. However, for the 46% of global steam coal imports (data for 2017), three Asian countries are responsible: China, India and Japan. For each of the six listed countries (i.e. for: three major global exporters and three major global importers), the paper presents volumes related to coal production, export or import. The directions of deliveries or major coal exporters to a given country were also included. At the end of the article, the price situation was presented, as it appeared in the first half of 2018 on the European and Asian markets.
Observing the situation in the power industry it is easy to see that there are very deep changes in it. They rely primarily on moving away from conventional energy to renewable energy. This is particularly the case for energy in the European Union. Europe strives to be a forerunner in renewable technologies and a leader in the fight against global warming. The mining industry is being abolished and coal-fired power stations are being displaced by renewable energy sources. This situation is not only a result of EU directives but also of grassroots social initiatives inspired by environmental groups. The new lignite openings are being blocked, due to the lack of public acceptance, and the construction of conventional power plants. They do not help economic arguments for the development of energy based on coal, lignite, fuel that is significantly cheaper than the other, or to provide potential investors with the creation of new jobs. Also, coal investments are suspended in other regions of the world. CoalSwarm coal research shows that 2016 saw a dramatic fall in the amount of coal investment in the world. Even in China and India, where most of the coal industry has developed in recent years, about 100 investments have been suspended. The situation in the US is unclear. Although Barack Obama signed the Paris Agreement, current United States President Donal Trump has spoken out about this agreement and in numerous speeches and is eager to return to the dominant role of coal in the American economy. Poland still maintains the carbon structure of the power industry, but the Minister of Energy has announced that the new block at the Ostrołęka power plant will be the last coal-fired power plant to be built in Poland. This statement allows us to believe that there may be a return to Poland’s energy policy in the nearest future, and the long-awaited document, Poland’s energy policy until 2050, will determine the direction of change for the coming years.
The paper presents selected issues related to the development of international coal markets. World consumption of coal dropped for the second year in a row in 2016, primarily due to the lower demand from China and the US. The share of coal in global primary energy consumption decreased to 28%. World coal production accounted to 3.66 billion toe and it was lower by 6.2% when compared to the previous year. More than 60% of this decline took place in China. The decline in global production was more than four times higher than the decrease in consumption. The sufficiency of the world resources of coal are estimated at 153 years – that is three times more than the sufficiency of oil and gas resources. After several years of decline, coal prices increased by 77% in 2016. The current spot prices are at the level of $80/ton and are close to the 2014 prices. In the European market, after the first half of the year, coal prices reached the level of around 66% higher than in the same period of the last year. The average price in the first half amounted to PLN 12.6/GJ, which is close to the 2012 prices. The share of spot trade in the total purchase amount accounted to approx. 20%. Prices in futures contracts can be estimated on the basis of the Japan-Australia contracts prices and prices in supplies to power plants located in Germany. On average, the prices in supplies to these power plants were higher by approximately 9% in the years 2010 – 2016 and prices in Australia – Japan contracts were 12% higher than CIF ARA prices in 2017. Global energy coal trade reached about 1.012 billion tons in 2016. A decline by 4.8% is expected in 2019 primarily due to the expected reduction in demand in major importing countries in Asia.
Significant quantities of coal sludge are created during the coal enrichment processes in the mechanical processing plants of hard coal mines (waste group 01). These are the smallest grain classes with a grain size below 1 mm, in which the classes below 0.035 mm constitute up to 60% of their composition and the heat of combustion is at the level of 10 MJ/kg. The high moisture of coal sludge is characteristic, which after dewatering on filter presses reaches the value of 16–28% (Wtot r) (archival paper PG SILESIA). The fine-grained nature and high moisture of the material cause great difficulties at the stage of transport, loading and unloading of the material. The paper presents the results of pelletizing (granulating) grinding of coal sludge by itself and the piling of coal sludge with additional material, which is to improve the sludge energy properties. The piling process itself is primarily intended to improve transport possibilities. Initial tests have been undertaken to show changes in parameters by preparing coal sludge mixtures (PG SILESIA) with lignite coal dusts (LEAG). The process of piling sludge and their mixtures on an AGH laboratory vibratory grinder construction was carried out. As a result of the tests, it can be concluded that all mixtures are susceptible to granulation. This process undoubtedly broadens the transport possibilities of the material. The grain composition of the obtained material after granulation is satisfactory. Up to 2 to 20 mm granules make up 90–95% of the product weight. The strength of the fresh pellets is satisfactory and comparable for all mixtures. Fresh lumps subjected to a test for discharges from a height of 700 mm can withstand from 7 to 14 discharges. The strength of the pellets after longer seasoning, from the height of 500 mm, shows different values for the analyzed samples. The values obtained for hard coal sludge and their blends with brown coal dust are at the level from 4 to 5 discharges. The strength obtained is sufficient to determine the possibility of their transport. At this stage of the work it can be stated that the addition of coal dust from lignite does not cause the deterioration of the material’s strength with respect to clean coal sludge. Therefore, there is no negative impact on the transportability of the granulated material. As a result of mixing with coal dusts, it is possible to increase their energy value (Klojzy-Karczmarczyk at al. 2018). The cost analysis of the analyzed project was not carried out.
The evaluation of threats connected with the presence of methane in coal seams is based on our knowledge of the total content of this gas in coal. The most important parameter determining the potential of coal seams to accumulate methane is the sorption capacity of coal a. It is heavily influenced by the degree of coalification of the coal substance, determined by the vitrinite reflectance R0 or the content of volatile matter V daf. The relationship between the degree of coalification and the sorption capacity in the area of the Upper Silesian Coal Basin (USCB) has not been thoroughly investigated, which is due to the zonation of methane accumulation in this area and the considerable changeability of methane content in various localities of the Basin. Understanding this relationship call for in-depth investigation, especially since it depends on the analyzed reflectance range. The present work attempts to explain the reasons for which the sorption capacity changes along with the degree of coalification in the area of Jastrzębie (the Zofiówka Monocline). The relationship between parameters R0 and V daf was investigated. The authors also analyzed changes of the maceral composition, real density and the micropore volume. Furthermore, coalification-dependent changes in the sorption capacity of the investigated coal seams were identified. The conducted analyses have indicated a significant role of petrographic factors in relation to the accumulation properties of the seams located in the investigated area of USCB.
The Bogdanka coal mine, the only currently operating mine in the Lublin Coal Basin (LCB), extracts coal from the Upper Carboniferous formations of the LCB. The average sulfur content in the No. 385/2 seam is 0.98%, while in the case of the No. 391 seam it is slightly higher and amounts to 1.15%. The iron sulfides (pyrite and marcasite) in bituminous coal seams form macroscopically visible massive, vein, and dispersed forms. A microscopic examination has confirmed their complex structure. Massive forms contain euhedral crystals and framboids. The sulfide aggregations are often associated with a halo of dispersed veins and framboids. Pyrite and marcasite often fill the fusinite cells. Framboids are highly variable when it comes to their size and the degree of compaction within the carbonaceous matter. Their large aggregations form polyframboids. The cracks are often filled with crystalline accumulations of iron sulfides (octaedric crystals). The Wavelenth Dispersive Spectrometry (WDS) microanalysis allowed the chemical composition of sulfides in coal samples from the examined depoists to be analyzed. It has been shown that they are dominated by iron sulfides FeS2 – pyrite and marcasite. The examined sulfides contain small admixtures of Pb, Hg, Zn, Cu, Ag, Sb, Co, Ni, As, and Cd. When it comes to the examined admixtures, the highest concentration of up to 0.24%, is observed for As. In addition, small amounts of galena, siderite, and barite have also been found in the examined coal samples. The amounts of the critical elements in the examined samples do not allow for their economically justified exploitation. Higher concentrations of these elements can be found in the ashes resulting from the combustion process.
Preliminary lab-scale investigations were conducted on slagging abatement in biomass-firing by fuel mixing. Three agriculture biomass fuels and olive cake were used in the experiments. Polish lignites and bituminous coals were examined as anti-sintering additives. The effects of chlorine release, potassium retention and ash sintering were examined by heating samples of biomass fuels and additives in the muffle oven and, next, firing them in the laboratory down-fired furnace at the temperature in the range of 800-1150ºC. The obtained slag samples were analysed on: chlorine and potassium content, sintering tendency and crystalline components. Among the examined coals lignite from Turów mine and bituminous coal from Bolesław Śmiały mine appeared to be the most effective in potassium retention in aluminosilicate and chlorine release from slag. Possibly the major factor of these coals which reduced ash sintering was relatively high content of kaolinite
The paper presents the results of the mechanical, electrical, CCSEM and XRD measurements of hard coal, conducted in simulated conditions of sintering in atmospheres of O2/CO2,. The changes of the coal ash resistivity are correlated with the content of the oxides and with the sintering temperature determined by the mechanical test and Leitz method. The SEM-EDS analysis was conducted for deposits on the probe. The changes of the measured ash samples, observed during sintering process in O2/CO2 atmosphere, were discussed in the ash microstructure point of view.
The national power industry is based primarily on its own energy mineral resources such as hard and brown coal. Approximately 80% of electrical energy production from these minerals gives us complete energy independence and the cost of its production from coal is the lowest in comparison to other sources. Poland has, for many decades had vast resources of these minerals, the experience of their extraction and processing, the scientific-design facilities and technical factories manufacturing machines and equipment for own needs, as well as for export. Nowadays coal is and should be an important source of electrical energy and heat for the next 25–50 years, because it is one of the most reliable and price acceptable energy sources. This policy may be disturbed over the coming decades due to the depletion of active resources of hard and brown coal. The conditions for new mines development as well as for all coal mining sector development in Poland are very complicated in terms of legislation, environment, economy and image. The authors propose a set of strategic changes in the formal conditions for acquiring mining licenses. The article gives a signal to institutions responsible for national security that without proposed changes implementation in the legal and formal process it, will probably not be possible to build next brown coal, hard coal, zinc and lead ore or other minerals new mines.