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Number of results: 4
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Abstract

Recent advances in the construction of speed of sound meters made high-accuracy routine measurements possible in laboratories non-specialized in physical acoustics. Reliable values of the isentropic compressibility can be obtained from speeds of sound and densities of liquids using the Laplace formula. Strict thermodynamic relationships connect the isentropic compressibility of a medium and its density as a function of temperature and pressure with the heat capacity. These relationships result from the principles of thermodynamics and require no approximations or molecular models. In this study, the heat capacities of twelve liquids: hydrocarbons, acetonitrile, and ionic liquids were calculated from the speeds and densities taken from the literature sources. The agreement of the calculation results with the reference heat capacities, either critical values or measured calorimetrically, was satisfactory. The relative uncertainty of the calculated heat capacities was rather conservatively estimated for 5%. If the measurement procedures were optimized for heat capacity determination, better results would be attained, with the uncertainty probably smaller than 1%. Thus, the speed-and-density method is a potential alternative to classical calorimetry.
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Authors and Affiliations

Sylwia Szpaczek
1
Wojciech Marczak
1

  1. Faculty of Science and Technology, Jan Długosz University, Czestochowa, Poland
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Abstract

In this paper there are presented some results obtained by open circuit potential and electrochemical impedance spectroscopy measurements from studies performed on the behavior of tribocorrosion on metallic implant biomaterials as: 304L stainless steel, Co/nano-CeO2 nanocomposite layer and Ti6Al4V untreated and oxidized alloy to form a nanoporous TiO2 film. The open circuit potential technique used in measuring the tribocorrosion process provide information on the active or passive behavior of the investigated metallic biomaterial in the biological fluid, before, during friction and after stopping the friction. Thus it clearly show a better behavior of Co/nano-CeO2 nanocomposite coatings as compared with 304L stainless steel to tribocorrosion degradation in Hank solution; as well the better behavior of nanoporous TiO2 film formed annodically on Ti6Al4V alloy surface as compared with untreated alloy to tribocorrosion degradation in artificial saliva Fusayama Meyer. The slight decrease in polarization resistance value resulted from electrochemical impedance spectroscopy measured during friction in the case of the Co/nano-CeO2 nanocomposite layer (four times smaller), compared to 304L stainless steel, whose polarization resistance decreased more than 1000 times during friction shows the higher sensitivity of stainless steel to degradation by tribocorrosion. The same behavior is observed when comparing the polarization resistance of untreated titanium alloy recorded during friction that is about 200 hundred times smaller, while the specific polarization resistance of the oxidized alloy with the nanoporous film of titanium oxide, decreases very little during friction, highlighting the beneficial effect of modifying the titanium alloy by anodic oxidation to increase its resistance to the degradation process by tribocorrosion.
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Authors and Affiliations

L. Benea
1
ORCID: ORCID

  1. Dunarea de Jos University of Galati, Competences Centre: Interfaces-Tribocorrosion and Electrochemical Systems (CC-ITES), 47 Domneasca Street, RO-800008 Galati, Romania
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Abstract

In this experimental investigation, the critical heat flux (CHF) of aqua-based multiwalled carbon nanotube (MWCNT) nanofluids at three different volumetric concentrations 0.2%, 0.6%, and 0.8% were prepared, and the test results were compared with deionized water. Different characterization techniques, including X-ray diffraction, scanning electron microscopy and Fourier transform infrared, were used to estimate the size, surface morphology, agglomeration size and chemical nature of MWCNT. The thermal conductivity and viscosity of the MWCNT at three different volumetric concentrations was measured at a different temperature, and results were compared with deionized water. Although, MWCNT-deionized water nanofluid showed superior performance in heat transfer coefficient as compared to the base fluid. However, the results proved that the critical heat flux is increased with an increase in concentrations of nanofluids.

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Authors and Affiliations

D. Vasudevan
D. Senthil Kumar
A. Murugesan
C. Vijayakumar
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Abstract

It is well known that sound absorption and sound transmission properties of open porous materials are highly dependent on their airflow resistance values. Low values of airflow resistance indicate little resistance for air streaming through the porous material and high values are a sign that most of the pores inside the material are closed. The laboratory procedures for measuring airflow resistance have been stan- dardized by several organizations, including ISO and ASTM for both alternate flow and continuous flow. However, practical implementation of these standardized methods could be both complex and expensive. In this work, two indirect alternative measurement procedures were compared against the alternate flow standardized technique. The techniques were tested using three families of eco-friendly sound absorbent materials: recycled polyurethane foams, coconut natural fibres, and recycled polyester fibres. It is found that the values of airflow resistance measured using both alternative methods are very similar. There is also a good correlation between the values obtained through alternative and standardized methods.
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Authors and Affiliations

Romina del Rey
Jesus Alba
Jorge P. Arenas
Jaime Ramis

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