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Abstract

As part of the work the high-pressure sorptomat - a novel apparatus for sorption tests under conditions of high gas pressure was developed. The sorption measurement is carried out using the volumetric method, and the precise gas flow pressure regulator is used in the device to ensure isobaric conditions and regulate the sorption pressure in the range of 0-10 MPa. The uniqueness and high precision of sorption measurements with the constructed apparatus are ensured by the parallel use of many pressure sensors with a wide measurement range as well as high precision of measurement - due to the use of precise pressure sensors. The obtained results showed, i.a. that the time of reaching the isobaric conditions of the measurement is about 6-7 seconds and it is so short that it can be considered a quasi-step initiation of sorption processes. Moreover, the results of the measurement pressure stabilization tests, during the CO 2 sorption test on activated carbon, have shown that the built-in pressure regulator works correctly and ensures isobaric sorption measurement conditions with the precision of pressure stabilization of ±1% of the measurement pressure. The maximum range of sorption measurement using the high-pressure sorptomat is 0-86400 cm 3/g, and the maximum measurement uncertainty is ±2% of the measured value. The activated carbon sample used for the tests was characterized by a high sorption capacity, reaching 104.4 cm 3/g at a CO 2 pressure of 1.0 MPa.
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Authors and Affiliations

Mateusz Kudasik
1
Łukasz Anioł
1
Norbert Skoczylas
1
ORCID: ORCID

  1. Strata Mechanics Research Institute of the Polish Academy of Sciences, ul. Reymonta 27, 30-059 Cracow, Poland
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Abstract

The article presents the detection of gases using an infrared imaging Fourier-transform spectrometer (IFTS). The Telops company has developed the IFTS instrument HyperCam, which is offered as a short- or long-wave infrared device. The principle of HyperCam operation and methodology of gas detection has been shown in the paper, as well as theoretical evaluation of gas detection possibility. Calculations of the optical path between the IFTS device, cloud of gases and background have been also discussed. The variation of a signal reaching the IFTS caused by the presence of a gas has been calculated and compared with the reference signal obtained without the presence of a gas in IFTS's field of view. Verification of the theoretical result has been made by laboratory measurements. Some results of the detection of various types of gases has been also included in the paper.

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Authors and Affiliations

Mariusz Kastek
Tadeusz Piątkowski
Piotr Trzaskawka

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