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Abstract

The purpose of this study is to analyse the use of agricultural land on the territory of united communities and their individual districts of Zhytomyr region as the smallest units of the administrative territorial division of Ukraine. The relevance of this study, due to current changes in national land relations, dictates the need to have information about agricultural lands, their owners, tenants and the lands status for planning agricultural production, the land-leases development, sale of land. The analysis of land use was carried out according to the following indicators: location of land plots of all owners within the community district and the whole community; their area; monetary evaluation; status of documents for each land plot, in particular the availability of lease, land cultivation presence. The initial data of the researches is the data of the state land cadastre database, and data of the real property rights register, both in general access and in need of special access. As a result of the research there were defined areas and location of lands of some landowners, who leased their lands and areas of lands not leased, also there were defined areas of lands, used illegally, without any documents on land use, defined areas of lands, used or owned by agricultural producers (farms, physical persons, legal entities). A cartographic core was created for the purpose of convenient planning of agricultural land use and land management within selected districts on the territory of the community.
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Authors and Affiliations

Oksana Drebot
1
Olena Zubova
1
Halyna Khant
1
Vitalii Hurelia
1
Nadiya Sknypa
2

  1. Polissia National University, Zhytomyr, Ukraine
  2. Luhansk National Agrarian University, Slavyansk, Ukraine
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Abstract

The hydrolysis of lignocellulosic biomass results in the production of so-called fermentation inhibitors, which reduce the efficiency of biohydrogen production. To increase the efficiency of hydrogen production, inhibitors should be removed from aqueous hydrolysate solutions before the fermentation process. This paper presents a new approach to the detoxification of hydrolysates with the simultaneous formation of in-situ deep eutectic solvents (DES). In the first stage of the study, inhibitors were identified in the real hydrolysate samples using highperformance liquid chromatography (HPLC). Four monoterpenes were tested for their potential to extract furfural (FF) with simultaneous DES formation. An optimization process of the most important parameters affecting the extraction process and DES formation (Thymol:FF) was conducted using the Central Composite Design (CCD) model. A temperature of 40 °C, pH of 7, mHBD:mHYD ratio of 2:1, and time of 50 min were selected as the optimal conditions. These results indicate the high efficiency of FF removal from hydrolysates (92.1 - 94.6 %) in a onestep process. Meanwhile, the structural properties of the formed DES measured by Fouriertransform infrared spectroscopy (FT-IR) and Nuclear magnetic resonance spectroscopy (NMR) differed only slightly from those of the DES composed of pure substances (Furfural and Thymol).
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Authors and Affiliations

Patrycja Makoś-Chełstowska
1
ORCID: ORCID
Edyta Słupek
1
ORCID: ORCID
Karolina Kucharska
1
ORCID: ORCID
Jacek Gębicki
1
ORCID: ORCID

  1. Gdansk University of Technology, Faculty of Chemistry, Department of Process Engineeringand Chemical Technology, 80-233 Gdansk, Poland

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