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Abstract

The paper consists the problem of developing a scientific toolkit allowing to predict the thermal state of the ingot during its formation in all elements of the casting and rolling complex, between the crystallizer of the continuous casting machine and exit from the furnace. As the toolkit for the decision making task the predictive mathematical model of the ingot temperature field is proposed. Displacement between the various elements of the CRC is accounted for by changing the boundary conditions. Mass-average enthalpy is proposed as a characteristic of ingot cross-section temperature state. The next methods of solving a number of important problems with the use of medium mass enthalpy are developed: determination of the necessary heat capacity of ingots after the continuous casting machine for direct rolling without heating; determination of the rational time of alignment of the temperature field of ingots having sufficient heat capacity for rolling after casting; determination of the total amount of heat (heat capacity) required to supply the metal for heating ingots that have insufficient amount of internal heat.

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Authors and Affiliations

A. Biryukov
A. Ivanova
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Abstract

To obtain anti-corrosive thermo-diffusion zinc coatings, the authors use highly effective zinc saturating mixtures. This technology makes it possible to obtain coatings with a high zinc content in the δ-phase as well as a zinc-rich phase of FeZn13 (ζ-phase) on the coating surface. As a result of long-term studies into the corrosion properties of thermo-diffusion zinc (TDZ) coatings conducted by the authors, a number of features of their corrosive behavior have been established. The corrosion rate of those coatings in desalted and chloride-containing media is lower than those of galvanic or hot-dip zinc coatings. The corrosion behavior depends on the content of zinc on the surface and the texture features of the coating. The results showed that on the surface of thermo-diffusion coatings in the corrosion on media containing chloride ions, zinc hydroxychloride (simonkolleite – Zn5Cl2[OH]8[H2O]) has been formed. Compared to coatings obtained by other methods, the rate of simonkolleite formation was higher on TDZ coatings, which might have a positive effect on their resistance in aggressive atmospheres.

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Authors and Affiliations

A. Biryukov
R. Galin
D. Zakharyevich
A. Wassilkowska
A. Kolesnikov
T. Batmanova

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