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Abstract

The article describes the detection of a defect in a cast iron casting. It analyzes the cause of the crack in the Turbine Component casting. In this article, we are focusing on a particular turbine casting that is commonly used in automobiles as one of the components for turbochargers. The turbine is a casting made of ductile cast iron with a visible crack on the naked eye. The formation of cracks in castings is a common but undesirable phenomenon in the foundry practice. It is important to identify the errors, but also to know the cause of defects in castings. The solution is a detailed error analysis. In this paper I used metallographic analysis and magnetic powder method. The crack formation is due to tension in the casting, which results in tensile, shear, or shear forces. The crack formation kinetics is difficult because it is still very low during hardening and shortly after the casting is overloaded. The crack is most often due to core resistance or shrinkage molds that begin after the surface layer is tightened when the strength of the material is negligible to the end of the crystallisation.

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Authors and Affiliations

E. Kantoríková
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Abstract

Simulation is used today in many contexts, such as simulating technology to tune or optimize performance, safety engineering, testing, training, education, and entertainment. In some industries, simulations are commonly used, but in heat treatment this is rather an exception. The paper compares the simulation of carburization and nitrocementation of 16MnCr5 steel with a practical application. The aim was to determine the applicability of chemical heat treatment simulation. We were looking for an answer to the question: to what extent can we rely on the technological design of heat treatment? The software designed the heat treatment technology. He drew the technological process of chemical-thermal treatment of 16MnCr5 steel. The thickness of the cementite layer was 1 mm and the nitrocementation 1.2 mm. Changes in mechanical properties were observed. Cementing, nitrocementing, hardness, microhardness, metallography, and spectral analysis were practically performed. This article describes the benefits of simulation, speed and accuracy of the process. The only difference was in determining the carbon potential. The simulation confirmed the practical use and its contribution in the technological process.
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Bibliography

[1] Atraszkiewicz, R., Januszewicz, B., Kaczmarek, Ł., Stachurski, W., Dybowski, K., Rzepkowski, A. (2012). High pressure gas quenching: Distortion analysis in gears after heat treatment. Materials Science & Engineering A. 558, 550-557.
[2] Mallener, H. (1990). Maß- Und Formänderungen beim Einsatzhärten. Journal of Heat Treatment and Materials. 45(1), 66-72. (in German)
[3] Jurči, P., Stolař, P. (2006). Distortion behavior of gear parts due to carburizing and quenching with different quenching media. BHM Berg - und Hüttenmännische Monatshefte. 151, 437–441. DOI: 10.1007/BF03165203
[4] Rajan, T.V., Sharma, C.P., Sharma, A. (2001). Heat treatment Principles and Techniques. New Delhi.
[5] Farokhzadeh, K., Edrisy A. (2017). Surface Hardening by Gas Nitriding. Materials Science and Materials Engineering. 2, 107-136. https://doi.org/10.1016/B978-0-12-803581-8.09163-3
[6] NITREX. (2021). Simulation software for carburizing, carbonitriding, nitriding, & nitrocarburizing processes. Retrieved September 2021 from https://www.nitrex.com/en/solutions/process-flow-controls/products/production-software/ht-tools-pro-simulator/
[7] EN 10084. 1.7131/1.7139. Cr-Mn-legierter Einsatzstahl. (2011)
[8] Parrish, G. (1999). Carbuzing: Microstructures and Properties. (pp. 55-57). ASM International.
[9] Somers, M., Christiansen, T. (2020). Nitriding of Steels. Encyclopedia of Materials: Metals and Alloys. 2, 173-189. https://doi.org/10.1016/B978-0-12-819726-4.00036-3
[10] Llewellyn, D.T. & Cook, W.T. (1977). Heat-treatment distortion in case-carburizing steels. Metals Technology. 4(1), 265-278. https://doi.org/10.1179/030716977803292385
[11] Bepari M.M.A. (2017). Carburizing: A method of case hardening of steel. Materials Science and Materials Engineering. 2, 71-106. https://doi.org/10.1016/B978-0-12-803581-8.09187-6
[12] Skočovský, P., Bokůvka, O., Konečná, R., Tillová, E. (2014). Materials science. Edis – vydavateľstvo Žilinskej university, 343. ISBN 978-80-554-0871-2. (in Slovak).

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Authors and Affiliations

E. Kantoríková
1
ORCID: ORCID
P. Fabian
1
M. Sýkorová
1

  1. Department of Technological Engineering, University of Žilina in Žilina, Univerzitná 8215/1, 010 26 Žilina, Slovakia
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Abstract

The paper deals with the effect of heating of various prepared batch materials into semisolid state with subsequent solidification of the cast under pressure. The investigated material was a subeutectic aluminium alloy AlSi7Mg0.3. The heating temperature to the semisolid was chosen at 50% liquid phase. The used material was prepared in a variety of ways: heat treatment, inoculation and by squeeze casting. Also the influence of the initial state of material on inheritance of mechanical properties and microstructure was observed. The pressure was 100 MPa. Effect on the resulting casting structure, alpha phase distribution and eutectic silicon was observed. By using semisolid squeeze casting process the mechanical properties and microstructures of the casts has changed. The final microstructure of the casts is very similar to the microstructure that can be reached by technology of thixocasting. The mechanical properties by using semisolid squeeze casting has been increased except the heat treated material.

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Authors and Affiliations

D. Martinec
R. Pastirčák
ORCID: ORCID
E. Kantoríková
ORCID: ORCID
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Abstract

The paper compares changes in the structure and mechanical properties due to the synergistic effect of alloying elements Zr and Ti. It is assumed that by increasing the content of Zr and Ti in the aluminium alloy, better mechanical properties will be achieved. Paper focuses on description of the differences between the samples casted into the shell mold and the metal mold. Main difference between mentioned molds is a different heat transfer coefficient during pouring, solidification and cooling of the metal in the mold. The main goal was to analyse the influence of Zr and Ti elements and compare the mechanical properties after the heat treatment. Curing and precipitation aging were used during the experiment. The effect of the elements on AlSi7Mg0.3 alloy created differences between the excluded Zr phases after heat treatment. Evaluation of the microstructure pointed to the decomposition of large predominantly needle Zr phases into smaller, more stable formations.
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Bibliography

[1] Bolibruchová, D., Tillová, E. (2005). Al-Si foundry alloys. Žilina.
[2] Michna, Š., Lukáč, I. (2005). et al. Encyclopedia of aluminum.
[3] Bechný, L. (1990). Foundry metallurgy and technology. ALFA Bratislava.
[4] Bolibruchová, D., Kuriš, M. & Matejka, M. (2019). Effect of Zr on selected properties and porosity of AlSi9Cu1Mg alloy for the purpose of production of high-precision castings. Manufacturing Technology. 19(4), 1213-2489.
[5] Bolibruchova, D., Macko, J. & Bruna, M. (2014). Elimination of negative effect of Fe in secondary alloys AlSi6Cu4 (EN AC 45 000, A 319) by nickel. Archives of Metallurgy and Materials, 59, 717-721
[6] Mahmudi, R., Sepehrband, P. & Ghasemi, H.M. (2006). Improved properties of A319 aluminum casting alloy modified with Zr. Materials Letters. 2606-2610. DOI 10.1016/j.matlet. 2006.01.046
[7] Peng, G., Chen, K., Fang, H. & Chen, S. (2012). A study of nanoscale Al3(Zr,Yb) dispersoids structure and thermal stability in Al–Zr–Yb alloy. Materials Science and Engineering. Volume 535, 311-315.
[8] Sha, G. & Cerezo, A. (2004). Early-stage precipitation in Al−Zn−Mg−Cu alloy (7050). Acta Materialia. 52(15), 4503-4516.
[9] Lü, X., Guo, E., Rometsch, P. & Wang, L. (2012). Effect of one-step and two-step homogenization treatments on distribution of Al3Zr dispersoids in commercial AA7150 aluminium alloy. Transactions of Nonferrous Metals Society of China. 22, 2645-2651. Science Direct.
[10] STN EN 1706. AC–42100. Aluminium alloy for general purpose castings.
[11] Liu, S., Zhang, X.M. & Chen, M.A. & You, J. H. (2008). Influence of aging on quench sensitivity effect of 7055 aluminium alloy. Materials Characterization, 59(1), 53-60.
[12] Pourkia, N., Emamy, M., Farhangi, H. & Seyed, E. (2010). The effect of Ti and Zr elements and cooling rate on the microstructure and tensile properties of a new developed super high-strength aluminium alloy. Materials Science and Engineering A. 527, 5318-5325.
[13] Tillova, E., Chalupova, M. (2009). Structural analysis of Al-Si alloys. Žilina: EDIS ŽU UNIZA.

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Authors and Affiliations

E. Kantoríková
1
ORCID: ORCID
M. Kuriš
1
R. Pastirčák
1
ORCID: ORCID

  1. Department of Technological Engineering, University of Žilina in Žilina, Univerzitná 8215/1, 010 26 Žilina, Slovakia
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Abstract

The article focused primarily on comparing the achieved mechanical results for AlSi7Mg0.3Cu0.5Zr and AlSi7Mg0.3Cu0.5Zr0.15Ti experimental alloys. Experimental variants with the addition of Zr ≥ 0.05 wt. % demonstrated the ability of Zr to precipitate in the form of Al3Zr or AlSiZr intermetallic phases. Zr precipitated in the form of long smooth needles with split ends. When evaluating the thermal analyses, the repeated peak was observed already with the initial addition of Zr in the range of approximately 630 °C. It was interesting to observe the increased interaction with other intermetallic phases. EDX analysis confirmed that the individual phases are based on Cu, Mg but also Fe. Similar phenomena were observed in experimental alloys with a constant addition of Zr and a gradual increase in Ti by 0.1 wt. %. A significant change occurred in the amount of precipitated Zr phases. A more significant increase in mechanical properties after heat treatment of AlSi7Mg0.3Cu0.5Zr experimental alloys was observed mainly above the Zr content ≥ 0.15 wt. % Zr. The improvement of yield and tensile strength over the AlSi7Mg0.3Cu0.5 reference alloy after heat treatment was minimal, not exceeding 1 %. A more significant improvement after heat treatment occurred in modulus of elongation with an increase by 6 %, and in hardness with an increase by 7 %. The most significant drop occurred in ductility where a decrease by 31 % was observed compared to the reference alloy. AlSi7Mg0.3Cu0.5Zr0.15Ti experimental alloys, characterized by varying Ti content, achieved a more significant improvement. The improvement in tensile strength over the AlSi7Mg0.3Cu0.5 reference alloy after heat treatment was minimal, not exceeding 1 %. A more significant improvement after heat treatment occurred in modulus of elongation with an increase by 12 %, in hardness with an increase by 12 % and the most significant improvement occurred in yield strengthwith a value of 18 %. The most significant decrease also occurred in ductility where, compared to the reference alloy, the ductility drop was by up to 67 %.
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Bibliography

[1] Vončina, M., Medved, J., Kores, S., Xie, P., Cziegler, A. & Schumacher, P. (2018). Effect of molybdenum an zirconium on aluminium casting alloys. Livarski Vestnik. 68-78.
[2] Medved, J. & Kores, M.V.S. (2018). Development of innovative Al-Si-Mn-Mg alloys with hight mechanical properties. The Minerals, Metals & Materials Society. 373-380. DOI 10.1007/978-3-319-72284-9_50.
[3] Pisarek, B.P., Rapiejko, C., Szymczak, T. & Payniak, T. (2017). Effect of Alloy Additions on the Structure and Mechanical Properties of the AlSi7Mg0.3 Alloy. Archives of Foundry Engineering. 17(1),137-142. ISSN: 1897-3310.
[4] Mahmudi, R., Sepehrband, P. & Ghasemi, H.M. (2006). Improve properties of A319 aluminium casting alloy modified with Zr. Materials Letters. 2606-2610. DOI: 10.1016/j.matlet.2006.01.046
[5] Sepehrband, P., Mahmudi, R., Khomamizadeh, F. (2004). Effect of Zr addition on the aging behavior of A319 aluminium cast alloy. Scripta Materialia. 253-257. DOI: 10.1016/j.scriptamat.2004.10.025
[6] Rakhmonov, J., Timelli, G. & Bonollo, F. (2017) Characterization of the solidification path and microstructure of secondary Al-7Si-3Cu-0,3Mg alloy with Zr, V and Ni additions. Material characterization. ISSN:1044-5803.
[7] Krajewski, W., Geer, A., Buraś, J., Piwowarski, G. & Krajewski, P. (2019). New developments of hight-zinc Al-Zn-Cu-Mn cast alloys. Materialstoday Proceedings. 306-311. DOI: 10.1016/j.matpr.2018.10.410.
[8] Hermandez-Sandoval, J., Samuel, A.M. & Vatierra, F.H. (2016). Thermal analysis for detection of Zr-rich phases in Al-Si-Cu-Mg 354-type alloys. Journal of metalcasting. ISSN 1939-5981.
[9] Bolibruchova, D., Kuriš, M., Matejka, M., Major Gabryś, K., Vicen, M., (2020) Effect of Ti on selected properties of AlSi7Mg0.3Cu0.5 alloy with constant addition of Zr. Archives of Metalurgy and Materials. 66(1), 65-72. DOI: 10.24425/amm.2021.134760.

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Authors and Affiliations

M. Kuriš
1
D. Bolibruchova
1
M. Matejka
1
ORCID: ORCID
E. Kantoríková
1
ORCID: ORCID

  1. University of Zilina, Faculty of Mechanical Engineering, Department of Technological Engineering, Univerzitna 1, 010 26 Zilina, Slovak Republic
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Abstract

The current trend of continuous improvement of various components constantly pushes the development of new materials forward. The basic goal of research into new and better materials is to improve their properties compared to the original material. One of the essential properties of the newly developed aluminum alloys is their resistance to the formation of tearing. Tears appear during the solidification of the casting and break the integrity due to tension arising while cooling. Several factors influence the susceptibility to tearing, but they can be minimized and reduce the chance of their occurrence. As part of the experiment, the AlSi5Cu2Mg alloy was evaluated in four material variants, without additives (in the reference state), with the addition of transition elements Zr, Ti and their combination Zr + Ti. Susceptibility to the formation of teras was assessed using a qualitative method supplemented by microscopic analysis of the tear profile and determination of the dendritic coherence temperature. The evaluation shows that the addition of Zr increased the susceptibility to tear formation. On the contrary, the addition of Ti had a positive effect and reduced the susceptibility to the formation of tears. The effect of the addition of Zr and Ti in the AlSi5Cu2Mg alloy showed a similar values as without the addition of alloys (reference condition). Microstructural analysis of the tear profile pointed to the negative influence of phases rich in Zr. The subsequent evaluation of the dendritic coherence temperature of individual AlSi5Cu2Mg alloys did not show a correlation with the results of a quantitative evaluation of susceptibility to tears.
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Bibliography

[1] Bolibruchová, D. (2010). Foundry technology. Žilina: vydavateľstvo GEORG, ISBN 978-80-89401-14-7.
[2] Pastirčák, R., Bolibruchová, D., Sládek, A. (2015). Foundry theory. Žilina: EDIS-vydavateľské centrum ŽU, ISBN 978-80-554-1096-8.
[3] Wu, Q., (2012). Study of Hot Tearing in Cast and Wrought Aluminum Alloys. Dissertation thesis. Worchester: Faculty of the Worcester polytechnic institute, UK.
[4] Bruna, M. & Galčík, M. (2021). Casting Quality Improvement by Gating System Optimization. Archives of Foundry Engineering. 21(1). 132-136. DOI:10.24425/afe.2021.136089.
[5] Huang, H., Fu, P, Wang, Y., Peng, L. & Jiang, H. (2014). Effect of pouring and mold temperatures on hot tearing susceptibility of AZ91D and Mg–3Nd–0.2Zn–Zr Mg alloys. Transactions of Nonferrous Metals Society of China. 24(4), 922-929. DOI:10.1016/S1003-6326(14)63144-7.
[6] Campbell, J. (2015). Complete casting handbook: metal casting processes, metallurgy, techniques and design. Elsevier Science.
[7] Oh, S.H., A.H., Munkhdelger, Ch. & Kim, H.J. (2021). Effect of Cu content on hot tearing susceptibility in al-si-cu aluminum casting alloy. Journal of Korea Foundry Society. 41(5), 419-433.
[8] Bichler, L., Elsayed, A., Lee, K. & Ravindran, C. (2008). Influence of mold and pouring temperatures on hot tearing susceptibility of AZ91D magnesium alloy. International Journal of Metalcasting. 2, 43-54. DOI:10.1007/BF03355421.
[9] Hasan, A. & Suyitno, A. (2014). Effect pouring temperature on casting defect susceptibility of hot tearing in metal alloy Al-Si. Applied Mechanics and Materials. 758, 95-99. https://doi.org/10.4028/www.scientific.net/AMM.758.95.
[10] Djurdjevic, M.B. Sokolowski, J.H. & Odanovic Z. (2012). Determination of dendrite coherency point characteristics using first derivative curve versus temperature. Journal of Thermal Analysis and Calorimetry volume. 109(2), 875-882. https://doi.org/10.1007/s10973-012-2490-4.
[11] Gómez, I. V., Viteri, E. V. Montero, J., Djurdjevic, M. & Huber, G. (2018). The determination of dendrite coherency point characteristics using three new methods for aluminum alloys. Applied Sciences. 8(8), 1236, 1-14. https://doi.org/10.3390/app8081236.
[12] Bolibruchová, D., Širanec, L. & Matejka, M. (2022). Selected properties of a Zr-containing AlSi5Cu2Mg alloy intended for cylinder head castings. Materials. 15(14), 4798, 1-16. https://doi.org/10.3390/ma15144798
[13] Bolibruchová, D., Kuriš, M., Matejka, M. & Kasińska, J. (2022). Study of the influence of zirconium, titanium and strontium on the properties and microstructure of AlSi7Mg0.3Cu0.5 alloy. Materials. 15(10), 3709, 1-20. https://doi.org/10.3390/ma15103709.
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Authors and Affiliations

M. Matejka
1
ORCID: ORCID
D. Bolibruchová
1
ORCID: ORCID
E. Kantoríková
1
ORCID: ORCID

  1. University of Zilina, Faculty of Mechanical Engineering, Department of Technological Engineering, Slovak Republic

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