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Number of results: 3
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Abstract

The goals of this work are to design and develop a technology for fabrication and study of multifunctional properties of core/shell nanoparticles (NPs) as magnetic/luminescent markers. The new hybrid core/shell Fe3O4/Gd2O3:1% Er3+, 18% Yb3+, 2.5% Mg2+, x% Nd3+ NPs doped with different concentrations of neodymium ions, where x = 0%, 0.5%, 0.75%, 1%, 2%, 4%, were synthesized by the co-precipitation method. The NPs were characterised using XRD, TEM, SEM, EDX, confocal microscopy and photoluminescence. Fe3O4 (core) consists of several 13 nm NPs. The core/shell NPs have sizes from 220 nm to 641 nm. In this latter case, the shell thicknesses were 72, 80, and 121 nm. The upconversion efficiency properties and magnetic properties of the hybrid NPs were investigated. In the core/shell NPs, the addition of Nd3+ quenches the luminescence. The magnetic response of core/shell samples is rather paramagnetic and does not differ significantly from that registered for the shell material alone. For Gd2O3:1% Er3+, 18% Yb3+ and Fe3O4/Gd2O3:1% Er3+, 18% Yb3+, 2.5% Mg2+, 0.5% Nd3+, at 300 K, the values of the magnetization registered at ~ 40 kOe are similar and equal to ~ 5.3 emu·g−1. The survivability of the HeLa tumor cells with the presence of the core/shell NPs was investigated for 24 h. The NPs are non-toxic up to a concentration of 1000 µg·ml−1 and penetrate cells in the process of endocytosis which has been confirmed by confocal microscope studies.
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Authors and Affiliations

Izabela Kamińska
1
ORCID: ORCID
Kamil Sobczak
2
Yaroslav Zhydachevskyy
1
ORCID: ORCID
Tomasz Wojciechowski
1 3
ORCID: ORCID
Roman Minikayev 
1
ORCID: ORCID
Bożena Sikora-Dobrowolska
1
ORCID: ORCID
Sabina Lewińska
1
ORCID: ORCID
Michał Chojnacki
1 3
ORCID: ORCID
Krzysztof Fronc
1 3
ORCID: ORCID

  1. Institute of Physics, Polish Academy of Sciences, al. Lotników 32/46, Warsaw 02-668, Poland
  2. Faculty of Chemistry, Biological and Chemical Research Centre, University of Warsaw, ul. Żwirki i Wigury 101, Warsaw 02-089, Poland
  3. International Research Centre MagTop, al. Lotników 32/46, Warsaw 02-668, Poland
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Abstract

The aquifers in the M’léta Plain are crucial for supplying drinking water and supporting industrial and agricultural water needs. However, they are facing a pollution risk and environmental degradation. The present study aims to assess the groundwater quality in the M’léta Plain, focusing on its physicochemical properties, statistics of the aquifer, pollution risks, and factors influencing the water mineralisation process. The analysis of 16 samples reveals that the water contains high levels of sulphates and chlorides, often accompanied by sodium, calcium, or magnesium. This suggests two distinct water types or facies: one characterised by sodium chloride or calcium chloride, and the other with calcic or sodic sulphate waters, sometimes including magnesium sulphate. These facies may be attributed to the influence of different formations at the outcrop. Statistical analyses reveal a strong correlation between electrical conductivity and the majority of chemical elements, indicating the impact of freshwater interacting with the underlying rock formations on mineralisation. Some results also show undersaturation of certain minerals. Furthermore, the study evaluates the water's suitability for irrigation in the M’léta Plain in accordance with Richards’ classification.
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Authors and Affiliations

Mohammed Khelifa
1
ORCID: ORCID
Abdelhamid Khedidja
1
ORCID: ORCID
Hamidi Mansour
2
Reghais Azzeddine
3

  1. University of Batna 2, Laboratory of Mobilization and Resources Management, 53, Road to Constantine, Fésdis, Batna, Algeria
  2. University of Oran 2, Laboratory of Georesources, Environment and Natural Hazards, BP 1524, Campus Pole Belgaid, Oran, Algeria
  3. University of Jijel, Laboratory of Geological Engineering, BP 98, Ouled Aissa, Jijel, Algeria
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Abstract

Strengthening the functioning of existing rural piped water supply systems is a critical strategy for ensuring household water security, particularly in water-scarce contexts. Improving operation and maintenance (O&M) of the systems is an important area of focus, commonly plagued by poor reliability and functionality over time. From an economic perspective, there is an opportunity to optimise O&M input efficiencies as a foundation for improved management. This paper presented challenges and opportunities to optimise O&M input efficiencies based on an analysis of water supply systems in Vietnam’s highland areas characterised by mountainous terrain and water scarcity. The analysis focused on state-based agencies for O&M given their mandate for restoring the inefficient systems and identified input norms for guidance on how to optimise O&M activities. We applied an input-oriented data envelopment analysis (DEA) model under constant returns to scale assumption to estimate technical, economic and allocative efficiencies. The results identified efficiency levels of 90%, 30% and 33% respectively. The study suggests a 10% reduction in general input amounts and identified efficient input target values reveal potential reduction rates for technical labour (12%), electricity (12%), as well as the technical and economic norms of technical labour (0.86 person- day∙(100 m3)–1 water sold) and electricity (0.53 kWh∙m–3 water sold). The policy implications for O&M state-based agencies include the adoption of input-based contracting mechanisms, while the government is encouraged to approve water tariffs and provide compensation based on input items to promote water service supply as a public good in water- scarce and challenging areas.
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Authors and Affiliations

Dao Van Dinh
1
ORCID: ORCID
Phong Tung Nguyen
2
ORCID: ORCID
Tan Tiep Nguyen
3
ORCID: ORCID
Naomi Carrard
4
ORCID: ORCID
Ngoc Minh Nguyen
5
ORCID: ORCID
Ton Nu Hai Au
6
ORCID: ORCID

  1. Institute for Water Resources Economics and Management, No 131, Chua Boc, 10000, Dong Da, Hanoi, Vietnam
  2. Ministry of Agriculture and Rural Development, Department of Water Resources, No 2, Ngoc Ha, 10000, Ba Dinh, Hanoi, Vietnam
  3. Vietnam Academy of Water Resources, No 17, Tay Son, Dong Da, 10000, Hanoi, Vietnam
  4. University of Technology Sydney-Institute for Sustainable Futures, Broadway 15-73, Ultimo, 2007, Sydney, Australia
  5. Hanoi Architectural University, km 10, Nguyen Trai, Thanh Xuan, 10000, Hanoi, Vietnam
  6. University of Economics, Hue University, 99 Ho Dac Di, 49000, Hue City, Vietnam

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