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Abstract

The results of investigations of plasticity of moulding sands with binders obtained by measuring deflection angles in the single point bend test in dependence on their hardening degree are presented in the hereby paper. Shaped samples made of moulding sands obtained in the technology with urea-furfuryl resin Furanol FR75A and in the technology with water glass, were subjected to various tests. Shaped samples were made on the quartz matrix of a medium grains size ����=0,29 ����. Investigations were performed for the resin content being 1% and 2%, at a constant proportion of a hardener versus resin -- equal 60%. In the case of sands from the technology with water glass, investigations were performed for 3.5% of water glass versus sand matrix and 0.35% of Flodur. Plasticity tests were carried out with using the strength machine with a continuous recording of a sample deflection value. Measurements of deflection angles values in the bend test were performed on a series of simultaneously made samples at constant time intervals from the moment of their making. To determine the sand hardening degree the ultrasound technique was applied, according to the previously developed methodology [1]. Every time from the obtained results the characteristic of the growing stress as a function of deflection was prepared (��). In addition, for the tested group of moulding sands, empirical relationships between the maximum deflection angle (αmax) in the bend test and the hardening degree were determined (Sx): α = f(Sx).
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Bibliography

[1] Zych, J. (2002). New, nondestructive method of quality inspection of mould’s elements made of moulding sands with chemical binders. Archives of Foundry. 2(5), 132-139.
[2] Fredrickson, A.G. (1964). Principles and applications of rheology. New York: Prentice Hall, Englewood Cliffs.
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[7] Gröning, P. (2014). Properties and use of the modern PUR cold-box system. 4th Conference: Molding and core materials - theory and practice. 28 -30 August. Iława – Poland: Hüttenes-Albertus Poland. (in Polish).
[8] Gröning, P., Schreckenberg, S. & Jenrich, K. (2015). Herstellung von hoch-komplexen Zylinderkurbel-gehäusen. Giesserei. 102(01), 42-47.
[9] Grabarczyk, A., Dobosz, M.St., Kusiński, J., & Major-Gabryś, K. (2018). The tendency of moulding sands to generate core cracs. Archives of Foundry Engineering. 18(1), 157-161.
[10] Dobosz, M.St., Grabarczyk, A. & Major-Gabryś, K. (2017). Elasticity of moulding sands – a method of reducing core cracking. Archives of Foundry Engineering. 17(1), 31-36.
[11] Grabarczyk, A. (2018). Analysis and evaluation of mechanical and thermal deformation of molding sands with selected binders. Unpublished doctoral dissertation, AGH University of Science and Technology, Kraków. (in Polish).
[12] Zych, J. (2007). Synthesis of ultrasonic technique applications in the analysis of the kinetics of selected processes in molding materials. Kraków: AGH Uczelniane Wydawnictwa Naukowo-Dydaktyczne. Seria: Rozprawy i Monografie nr 163. (in Polish).

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Authors and Affiliations

Natalia Matonis
ORCID: ORCID
J. Zych
1
ORCID: ORCID

  1. AGH University of Science and Technology, Faculty of Foundry Engineering, ul. Reymonta 23, 30-059 Cracow, Poland
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Abstract

The aim of the research was to determine the effect of the primary quality of reclaim from dry mechanical reclamation on the strength properties and service life of moulding sands based on this reclaim. Another aim was to establish the effect of the quality of reclaim, sulphur content - in particular, on the surface quality and thickness of the deformed surface layer in ductile iron castings. The research has revealed differences in the strength parameters and service life (mouldability) of sands based on the tested reclaims, depending on the type of the furfuryl resin used, including resins whose synthesis was done as part of the Żywfur project. Examinations of the structure of the surface layer of test castings poured in moulds made of loose self-hardening sands containing the addition of reclaim have confirmed the occurrence of degenerated spheroidal graphite in this part of the casting. It should be noted here that when massive castings with a long solidification time are made, the graphite degeneration effect can be more visible and the layer with the changed structure can increase in thickness. The research has clearly shown that it is necessary to control the parameters of the reclaim, including sulphur content which is transferred from the hardener and accumulates on the grains. This phenomenon has a negative impact not only on the sand strength and technological properties but also on the surface layer of castings.
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Bibliography

[1] Lewandowski, J.L. (1997). Materials for foundry moulds. Kraków: WN Akapit. ISBN: 83-7108-21-2 (in Polish).
[2] Kamińska, J., Puzio, S., Angrecki, M., Stachowicz, M. & Łoś, A. (2019). Preliminary tests of innovative eco-friendly furfuryl resins and foundry sand mixtures based on these resins. Journal of Ecological Engineering. 20(9), 285-292, DOI: 10.12911/22998993/112510.
[3] Acharya, S.G., Vadher, J.A. & Kanjariya, P.V. (2016). Identification and quantification of gases releasing from furan no bake binder. Archives of Foundry Engineering. 16(3), 5-10. DOI: 10.1515/afe-2016-0039.
[4] Chate, G.R., Patel, GC M., Deshpande, A.S. & Parappagoudar, M.B. (2018). Modeling and optimization of furan moulding sand system using design of experiments and particle swarm optimization. Journal of Process Mechanical Engineering. 232(5), 1-20. DOI: 10.1177/0954408917728636.
[5] Sappinen, T., Orkas, J. & Konqvist, T. (2018). Thermal Reclamation of Foundry Sands Using Repurposed Sand Dryer Equipment. Archives of Foundry Engineering. 18(4), 99-102. DOI: 10.24425/afe.2018.125176.
[6] Kamińska, J., Puzio, S., Angrecki, M. & Łoś, A. (2020). Effect of reclaim addition on the mechanical and technological properties of moulding sands based on pro-ecological furfuryl resin. Archives of Metallurgy and Materials. 65(4), 1425-1429. DOI: 10.24425/amm.2020.133709.
[7] Yan-lei, L., Guo-hua, W., Wen-cai, L., An-tao, C., Liang, Z. & Ying-xin Wang, W. (2017). Effect of reclaimed sand additions on mechanical properties and fracture behavior of furan no-bake resin sand. China Foundry. 14(2), 128-137. DOI: 10.1007/s41230-017-6024-3.
[8] Holtzer, M., Dańko, R., Kmita, A., Drożyński, D., Kubecki, M., Skrzyński, M. & Roczniak, A. (2020). Environmental impact of the reclaimed sand addition to moulding sand with furan and phenol-formaldehyde resin—A comparison, Materials. 13(19), 4395; DOI: https://doi.org/10.3390/ma13194395.
[9] Holtzer, M., Dańko, R. & Kmita, A. (2016). Influence of a reclaimed sand addition to moulding sand with furan resin on its impact on the environment. Water Air and Soil Pollution. 227(16), 1-12. DOI: 10.1007/s11270-015-2707-9.
[10] Hosadyna, M. (2012). The effect of sulphur contained in self-hardening moulding sands on the structure of surface layer in ductile iron castings. Doctoral dissertation, Kraków. (in Polish).
[11] Holtzer, M., Zych, J. & Retel, K. (1996). The effect of mould-liquid cast iron interaction on the surface quality of castings. Przegląd Odlewnictwa. 6(1996), 129-134. (in Polish).
[12] Riposan, I., Chisamera, M., Stan, S., Skaland, T. (2008). Surface graphite degeneration in ductile iron castings for resin molds. Tsinghua Science and Technology. 13(2), 157-163.
[13] Linke, T., Sluis, J.R. (1993). The influence of coatings on the graphite structure in the rim-zone of ductile iron castings. 60th World Foundry Congress, The Netherlands
[14] Hosadyna, M., Dobosz, St.M. & Jelinek, P. (2009). The diffusion of sulphur from moulding sand to cast and methods of its elimination. Archives of Foundry Engineering. 9(4), 73-76.
[15] Sheladiya, M.V., Acharya, S.G., Mehta, K., Acharya, G.D. (2019). Evaluate sulphur diffusion at mould-metal interface in no-bake mould system. Archives of Foundry Engineering. 19(1), 63-70. DOI: 10.24425/afe.2018.125193.
[16] Anca, D., Stan, I., Chisamera, M., Riposan, I. & Stan, S. (2021). Experimental study regarding the possibility of blocking the diffusion of sulfur at casting-mold interface in ductile iron castings. Coatings. 11(673), 1-10. DOI: https://doi.org/10.3390/coatings11060673.
[17] Dańko, J., Dańko, R. & Łucarz, M. (2007). Processes and devices for the matrix regeneration of spent molding sands. Kraków: WN Akapit. ISBN: 978-83-89541-88-8 (in Polish).
[18] Holtzer, M., Bobrowski, A., Drożyński, D., Isendorf, B., Mazur, (2012). Influence of the reclaim on the properties of moulding sands with furfuryl resin applied for moulds for manganese steel castings. Archives of Foundry Engineering. 12(1), 57-62.
[19] Dańko, R., Górny, M., Holtzer, M., Żymankowska-Kumon, S. (2014). Effect of the quality of furan moulding sand on the skin layer of ductile iron castings. ISIJ International. 54(6), 1288-1293. DOI: https://doi.org/10.2355/isijinternational.54.1288.
[20] Pałyga, Ł., Stachowicz, M., Granat, K. (2015). Evaluation of 2D and 3D surface roughness of die castings from alloy AlSi9Cu3. Archives of Foundry Engineering. 15(1), 75-80.

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Authors and Affiliations

J. Kamińska
1
ORCID: ORCID
M. Angrecki
1
ORCID: ORCID
S. Puzio
1
ORCID: ORCID
M. Stachowicz
2
ORCID: ORCID

  1. Łukasiewicz Research Network – Krakow Institute of Technology, Poland
  2. Wroclaw University of Technology, Faculty of Mechanical Engineering, Poland
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Abstract

Iron aluminides are iron-aluminum alloys that have excellent resistance to oxidation at high temperatures with low density, high resistance/weight ratio and a low manufacturing cost. Due to its characteristics, these alloys are presented as an option to replace stainless steels in certain applications. This works intends report the casting process and subsequent analyses involving microstructure, mechanical properties, and corrosion resistance of two Fe-Al-C alloys (Fe-11wt%Al and Fe-25wt%Al, containing 0.31-0.37%C), which were prepared in an induction furnace and poured in a permanent mold. Samples of these alloys were characterized and presented elevated hardness values of 37 HRC (alloy Fe-11wt%Al) and 49.6HRC (alloy Fe-25wt%Al) and microstructure with aluminides type Fe3Al and FeAl and also carbides type K. The Fe-11wt%Al alloy exhibited superior resistance to uniform corrosion, although both Fe-Al-C alloys exhibited significantly higher corrosion rates compared to a binary iron aluminide in 0.5M H2SO4 containing naturally dissolved oxygen.
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Bibliography

[1] Zamanzade, M., Barnoush, A. & Motz, C. (2016). A review on the properties of iron aluminide intermetallics. Crystals. 6(10), 1-29. DOI: 10.3390/cryst6010010.
[2] Stoloff, N.S. (1998). Iron aluminides: present status and future prospects. Materials Science and Engineering: A. 258(1-2), 1-14. DOI: 10.1016/S0921-5093(98)00909-5.
[3] Cinca, N., Lima, C.R.C. & Guilemany, J.M. (2013). An overview of intermetallics research and application: Status of thermal spray coatings. Journal of Materials Research and Technology. 2(1), 75-86. DOI: 10.1016/j.jmrt.2013.03.013.
[4] Palm, M., Stein, F. & Dehm, G. (2019). Iron Aluminides. Annual Review of Materials Research. 49, 297-326. DOI: 10.1146/annurev-matsci-070218-125911.
[5] Deevi, S.C. & Sikka, V.K. (1996). Nickel and iron aluminides: an overview on properties, processing, and applications. Intermetallics. 4(5) 357-375. DOI: 10.1016/0966-9795(95)00056-9.
[6] Shankar Rao, V., Baligidad, R. G. & Raja, V. S. (2002). Effect of carbon on corrosion behaviour of Fe3Al intermetallics in 0.5N sulphuric acid. Corrosion Science. 44, 521-533. DOI: 10.1016/S0010-938X(01)00084-1.
[7] Shankar Rao, V. (2005). Repassivation behaviour and surface analysis of Fe3Al based iron aluminide in 0.25M H2SO4. Corrosion Science. 47, 183-194. DOI: 10.1016/j.corsci.2004.05.014.
[8] Nigam, A.K., Balasubramaniam, R., Bhargava, S. & Baligidad, R.G. (2006). Electrochemical impedance spectroscopy and cyclic voltammetry study of carbon-alloyed iron aluminides in sulfuric acid. Corrosion Science. 48(7), 1666-1678. DOI: 10.1016/j.corsci.2010.05.006.
[9] Schneider, A., Falat, L., Sauthoff, G. & Frommeyer, G. (2005). Microstructures and mechanical properties of Fe3Al-based Fe-Al-C alloys. Intermetallics. 13(12), 1322-1331. DOI: 10.1016/j.intermet.2005.01.0.
[10] Brito, P., Pinto, H., Klaus, M., Genzel, C. & Kaysser-Pyzalla, A. (2010). Internal stresses and textures of nanostructured alumina scales growing on polycrystalline Fe3Al alloy. Powder Diffraction. 25(2), 114-118. DOI: 10.1154/1.3402764
[11] Brito, P., Schuller, E., Silva, J., Campos, T.R., Araújo, C.R. & Carneiro, J.R. (2017). Electrochemical corrosion behaviour of (100), (110) and (111) Fe3Al single crystals in sulphuric acid. Corrosion Science. 126, 366-373. DOI: 10.1016/j.corsci.2017.05.029.
[12] Brito, P.P., Carvalho Filho, C.T. & Oliveira, G.A. (2020). Electrochemical corrosion behavior of iron aluminides in sulfuric acid. Materials Science Forum. 1012, 395-400. DOI: 10.4028/www.scientific.net/MSF.1012.395.
[13] Hernández-Hernández, M., Liu, H. B., Alvarez-Ramirez, J. & Espinosa-Medina, M. A. (2017). Corrosion behavior of Fe-40at.%Al-Based intermetallic in 0.25M H2SO4 solution. Journal of Materials Engineering and Performance. 26, 5983-5996. DOI: 10.1007/s11665-017-3036-5.

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Authors and Affiliations

A.P. Silva
1
ORCID: ORCID
P.P. Brito
1
N. Martins
1

  1. PUC Minas, Brazil
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Abstract

The European Commission's ambitious plan to reduce CO2 emissions has a significant impact on the global automotive industry. Recent development of new diesel and petrol engines with direct injection is aimed at improving fuel efficiency while maintaining (or enhancing) engine performance. This naturally also increases the demands on the properties of the most stressed engine components (e.g., cylinder heads, engine blocks, pistons), which leads to the development of new materials. Presented work analysed the effect of different mold temperatures (60; 120; 180 °C) on mechanical, physical properties and microstructure of AlSi5Cu2Mg aluminium alloy. This alloy is currently being used for the production of cylinder head castings. The results showed that the changing mold temperature had an effect on mechanical properties (ultimate tensile strength and Young modulus values). SEM with EDX analysis of intermetallic phases revealed there were no size and morphology changes of Cu, Mg and Fe intermetallic phases when the mold temperature changed. No significant effect of different mold temperature on physical properties (thermal and electrical conductivity) and fracture mechanism occurred during experiment. Optimal combination of mechanical and physical properties of AlSi5Cu2Mg alloy was achieved using a permanent mold with temperature ranging from 120 to 180 °C.
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Bibliography

[1] Skrabulakova, E.F, Ivanova, M., Rosova, A., Gresova, E., Sofranko, M. & Ferencz, V. (2021). On electromobility development and the calculation of the infrastructural country electromobility coefficient. Processes. 9(2), 1-28. DOI: 10.3390/pr9020222.
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[7] Kores, S., Zak, H. & Tonn, B. (2008). Aluminium alloys for cylinder heads. Materials and Geoenvironment. 55, 307-317.
[8] Podprocká, R. & Bolibruchová, D. (2017). Iron intermetallic phases in the alloy based on Al-Si-Mg by applying manganese. Archives of Foundry Engineering. 17(3), 217-221. DOI: 10.1515/afe-2017-0118.
[9] Vincze, F., Tokár, M., Gegyverneki, G. & Gyarmati, G. (2020). Examination of the eutectic modifying effect of Sr on an Al-Si-Mg-Cu alloy using various technological parameters. Archives of Foundry Engineering. 20(3), 79-84. 10.24425/afe.2020.133334
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[12] Tillová, E., Chalupová, M. (2009). Structural analysis of Al-Si alloys. Žilina: EDIS – vydavateľstvo ŽU.

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Authors and Affiliations

L. Širanec
1
ORCID: ORCID
D. Bolibruchová
1
ORCID: ORCID
M. Chalupová
1
ORCID: ORCID

  1. Department of Technological Engineering, Faculty of Mechanical Engineering, University of Žilina, Slovakia
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Abstract

The article presents the results of research on the abrasion resistance of cast iron with vermicular graphite in the as-cast state and after austempering (the latter material is referred to as AVGI – Austempered Vermicular Graphite Iron). Austenitization was carried out at the temperature values of either 900°C or 960°C, and austempering at the temperature values of either 290°C and or 390°C. Both the austenitization and the austempering time was equal to 90 minutes. The change of the pearlitic-ferritic matrix to the ausferritic one resulted in an increase in mechanical properties. Abrasion tests were conducted by means of the T-01M pin-on-disc tribometer. The counter-sample (i.e. the disc) was made of the JT6500 friction material. Each sample was subject to abrasion over a sliding distance of 4000 m. The weight losses of both samples and counter-samples were determined by the gravimetric method. It was found that the vermicular cast iron austenitized at 900°C and austempered at 290°C was characterized by the lowest wear among the evaluated cast iron types. The geometric structure of the surface layer after the dry friction test exhibited irregular noticeable grooves, distinct oriented abrasion traces, plastic flow of the material, microcracks, and pits generated by tearing out the abraded material. The largest surface roughness was found for the AVGI cast iron heat-treated according to the variant 3 (Tγ =900 ºC; Tpi = 390°C), while the smallest one occurred in AVGI cast iron subject to either the variant 2 (Tγ =960 ºC; Tpi = 290°C) or the variant 4 (Tγ =900 ºC; Tpi = 290°C) of heat treatment and was equal to either 2.5 μm or 2.66 μm, respectively. It can be seen that the surface roughness decreases with the decrease in the austempering temperature.
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Bibliography

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Authors and Affiliations

A. Jakubus
1
ORCID: ORCID

  1. The Jacob of Paradies University in Gorzów Wielkopolski, ul. Teatralna 25, 66-400 Gorzów Wielkopolski, Poland
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Abstract

The method of the ongoing assessment of the reclaim quality originating from the mechanical reclamation is described in this paper. In the process, the triboelectric system of measuring amounts of dust in the dedusting part of a reclamation device was applied. Based on the online measurements of the amounts of dust generated in the spent sand-reclamation process and the post-process determinations of the ignition losses and granular structures of the removed dust, the proper work parameters of the experimental reclaimer were selected. The allowable value of the ignition losses as well as the main fraction of the reclaimed matrix being similar to fresh sand was assumed as the main criteria of the positive assessment of the process. Within the presented investigations, a periodically operating device for rotor-mechanical reclamation was developed. The possibility of changing the intensity and time of the reclamation treatment as well as the triboelectric system of the dust-amount measuring were applied in this device. Tests were performed for the spent moulding sand with phenol-resol resin Carbophen 5692 hardened by CO2. This sand represents the moulding sand group with a less harmful influence on the surroundings for which the recovery of the quartz matrix utilising the reclamation requires stricter control of the parameters of the reclamation process and reclaim quality.
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Bibliography

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Authors and Affiliations

R. Dańko
1
ORCID: ORCID
A. Pietrzak
1
D. Gruszka
1

  1. AGH University of Science and Technology, Department of Foundry, ul. Reymonta 23, 30-059 Kraków, Poland

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