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Abstract

This article presents a analysis of the impact of varying amounts of a specific additive in the core mixture and adjustments in shooting pressure on the elimination of surface defects in castings, particularly veinings. These defects, often located in inaccessible areas of the casting, cannot be effectively removed through conventional methods like punching, making the optimization of the core mixture composition crucial. Additives are frequently incorporated into the core mixture, as they have become an essential component in its production. For the core mixture to be effective, it is not only essential to identify the appropriate type of additive but also to precisely determine the optimal quantity of the additive and accurately set other critical production parameters, such as shooting pressure.This study investigates the influence of additive concentration and shooting pressure on the surface quality of cast iron castings, employing the cold box method for core production. The findings reveal that higher shooting pressure contributes positively to the reduction of veining defects. However, an increased additive content in the core mixture does not necessarily ensure vein-free castings. The additive also plays a role in reducing the gas content within the core, and increased core hardness is associated with a decrease in the occurrence of veining defects. The casting with the highest surface quality and the fewest veinings was produced using cores made from a mixture with 1% additive content, subjected to a shooting pressure of 4 bars.
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Bibliography


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[2] Svidró, J.T., Diószegi, A., Svidró, J. & Ferenczi, T. (2017). The effect of different binder levels on the heat absorption capacity of moulding mixtures made by the phenolic urethane cold-box process. Journal of thermal analysis and calorimetry. 13(3), 1769-1777. DOI: 10.1007/s10973-017-6611-y.

[3] Hrubovčáková, M., Vasková, I. & Conev, M. (2017). Influence the composition of the core mixture to the occurence of veinings on castings of cores produced by cold-box-amine technology. Manufacturing Technology. 17(1), 39-44.

[4] Neudert, A. (2019). Molding and core mixtures. Formovací a jádrové směsi. Slévárenství. 67, 217. (in Czech).

[5] Żymankowska-Kumon, S., Bobrowski, A., Drożyński,D., Grabowska, B. & Kaczmarska, K. (2018). Effect of silicate modifier on the emission of harmful compounds from phenolic resin used in cold-box technology. Archives of Foundry Enginnering. 18(1), 151-156. DOI: 10.24425/118829.

[6] Zanetti, M.Ch. & Fiore, S. (2002). Foundry processes: the recovery of green moulding sands for core operations. Resources Conservation and Recycling. 38(3), 243-254. https://doi.org/10.1016/S0921-3449(02)00154-4.

[7] ASK Chemicals (2020, September). Cold box PU Technology. Retrived September 4, 2020, from https://www.askchemicals.com/foundry-products/products/pu-cold-box-binder/cold-box-process.

[8] Jelínek, P. (1996). Slévarenské formovací směsi II část, Pojivové soustavy formovacích směsí (pp. 24-29). Ostrava.

[9] Udayan, N., Srinivasan, M.V., Vaira Vignesh, R. & Govindaraju, M. (2021). Elimination of casting defects induced by cold box cores. Materials Today: Proceedings. 46(10), 5022-5026. https://doi.org/10.1016/j.matpr.2020.10.398.

[10] Li, C., Ma, Z., Zhang, X., Fan, H., & Wan, J. (2016). Silicone-modified phenolic resin: Relashionships between molecular structure and curing behaviour. Thermochemical Acta. 639, 53-65. https://doi.org/10.1016/j.tca.2016.07.011.

[11] Kroker, J. & Wang, X. (2014). Advancement in cold box gassing processes. In 7st BILBAO 2014 World Foundry Congress, 19-21 May 2014. Palacio Euskalduna, BILBAO: Advanced Suistanable Foundry.

[12] Jelínek, P. (2000). Dispersion systems of foundry molding compounds: cutting edge. Ostrava. (in Czech).

[13] Beňo, J., Adamusová, K., Merta, V. & Bajer, T. (2019). Influence of silica sand on surface casting quality. Archives of Foundry Engineering. 19(2), 5-8. DOI: 10.24425/afe.2019.127107.

[14] Hlavsa, P. (2016). Core-melt interaction during casting of Al alloy cylinder heads into metal molds. Published doctoral dissertation, Vysoké učení technické v Brňe. Fakulta strojního inženýrství, Brno, Czech Republic. (in Czech).

[15] Svidró, J., Diószegi, A., Tóth, L. & Svidró, J.T. (2017). The influence of thermal expansion of unbonded foundry sands on the deformation of resin bonded cores. Archives of Metallurgy and Materials. 62(2), 795-798. DOI:10.1515/amm-2017-0118.

[16] Baker, S. G., & Werling, J. M. (2003). Expansion control method for sand cores. In Transactions of the American Foundry Society and the One Hundred Seventh Annual Castings Congress (pp. 457-462).

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[21] Hrubovčáková, M., Vasková, I., Conev, M. & Bartošová, M. (2017). Influence the compostition of the core mixture to the occurrence of veining on casting of cores produced by cold-box-amine technology. Manufacturing Technology. 17(1), 39-44. DOI: 10.21062/ujep/x.2017/a/1213-2489/MT/17/1/39.

[22] Hrubovčáková M. (2023). Analysis and action of additives in the nuclear mixture. Reasons for use and analysis of additives in molding compounds (41-56). Košice: Fakulta materiálov,metalurgie a recyklácie, Technická univerzita v Košiciach. (in Slovac).

[23] Abdulamer, D. (2023). Impact of the different moulding parameters on properties of the green sand mould. Archives of Foundry Engineering. 23(2), 5-9. DOI:10.24425/afe.2023.144288.

[24] Khandelwal, H. (2014). Effect of binder composition on the shrinkage of chemically bonded sand cores. Materials and Manufacturing Processes. 30(12), 1465-1470. https://doi.org/10.1080/10426914.2014.994779.

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[27] Mahajan, N., Jadhav G. K. & Jadhav, R. (2018). Optimization of sand preparation to improve core strenght and casting quality. International Journal for Technological Research in Egineering. 6(2), 4808-4811.

[28] Bolibruchová, D. (2010). Foundry technology. (in Slovac). [29] HA Group. (2020). New Names – Proven Products. Retrieved June 20, 2024 from https://www.ha-group.com/fileadmin/redaktion_contentpool/3_Products_and_Services/Cold-Box/2020_Cold-Box_Brochure_e.pdf

[30] Shahria, S., Tariquzzaman, Md., Habibur Rahman, Md., Al Almi, Md. & Abdur Rahman, Md. (2017). Optimization of molding sand composition for casting al alloy. International Journal of Mechanical Engineering and Applications. 5(3), 155-161. DOI: 10.11648/j.ijmea.20170503.13.

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Authors and Affiliations

P. Delimanová
1
ORCID: ORCID
I. Vasková
1
ORCID: ORCID
O. Kožej
1
ORCID: ORCID

  1. Technical University of Košice Faculty of Materials, Metallurgy and Recycling, Slovak Republik
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Abstract

The results of tribological tests carried out on two novel high-entropy alloys (HEAs) from the AlCoCuFeNi group are described in this study. Research was carried out using a Miller machine (ASTM G75 standard) in an abrasive slurry environment, which contained SiC and water in a 1:1 ratio. The results obtained showed a higher rate of abrasive wear in the material designated as D3 (total weight loss in D3-1.6g compared to 1.1g in the D5 alloy), characterised by a homogeneous microstructure and hardness of 186 HV5. The second dual phase alloy, designated D5, was characterised by a lower rate of abrasive wear. In this alloy, the appearance of the second phase precipitates, evenly distributed throughout the entire volume, with higher hardness (760 HV0,01) and in a content of approximately 65% has led to a decrease in wear. The different wear resistances of the tested materials are due to differences in the hardness of the phases that constitute the microstructure of the tested alloys and the interaction of hard abrasive particles with the tested material. This has a direct impact on the plastic nature of the deformation in the upper layers of the samples. A characteristic system of linear grooves and protrusions, visible on surface profiles, was observed on the surfaces tested. Small local defects were also observed as a result of hammering and subsequent removal of hard SiC abrasive particles from the alloys tested or, in the case of the D5 alloy, additional removal of precipitates of the harder phase from the matrix.
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Bibliography


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[6] Cichocki, K., Bała, P., Kozieł, T., Cios, G., Schell N. & Muszka, K. (2022). Effect of mo on phase stability and properties in FeMnNiCo high-entropy alloys. Metallurgical and Materials Transactions A. 53, 1749-1760 https://doi.org/10.1007/s11661-022-06629-x.

[7] Zhao, D.Q., Pan, S.P., Zhang, Y., Liaw, P.K. & Qiao, J.W. (2021) Structure prediction in high-entropy alloys with machine learning. Applied Physics Letters. 118(23), 231904. https://doi.org/10.1063/5.0051307.

[8] Yeh, J.W. (2015). Physical Metallurgy of high-entropy alloys. JOM. 67, 2254-2261. https://doi.org/10.1007/s11837-015-1583-5.

[9] Wang, R., Tang, Y., Li, S., Ai, Y., Li, Y., Xiao, B., Zhu, L., Liu, X. & Bai, S. (2020). Effect of lattice distortion on the diffusion behavior of high-entropy alloys. Journal of Alloys and Compounds. 825, 154099, 1-8. https://doi.org/10.1016/j.jallcom.2020.154099.

[10] Mehta, A. & Sohn, Y.H. (2021). Effects in transition metal high-entropy alloys: ‘high-entropy’ and ‘sluggish diffusion’ effects. Diffusion Foundations. 29, 75-93. https://doi.org/10.4028/www.scientific.net/DF.29.75.

[11] Cao, B.X., Wang, C., Yang, T., Liu, C.T. (2020) Cocktail effects in understanding the stability and properties of face-centered-cubic high-entropy alloys at ambient and cryogenic temperatures. Scripta Materialia. 187. 250-255. https://doi.org/10.1016/j.scriptamat.2020.06.008.

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[14] Li, Z., Fu, L., Peng, J., Zheng, H., Ji, X., Sun, Y., Ma, S. & Shan, A. (2020). Improving mechanical properties of an FCC high-entropy alloy by γ′ and B2 precipitates strengthening, Materials Characterization, 159, 109989, 1-11. https://doi.org/10.1016/j.matchar.2019.109989.

[15] Chuang, M.H., Tsai, M.H., Wang, W.R., Lin, S.J. & Yeh, J.W. (2011). Microstructure and wear behavior of AlxCo1.5CrFeNi1.5Tiy high-entropy alloys. Acta Materialia. 59(16), 6308-6317. https://doi.org/10.1016/j.actamat.2011.06.041.

[16] Grudzień-Rakoczy, M., Rakoczy, Ł., Cygan, R., Chrzan, K., Milkovič, O. & Pirowski, Z. (2022). Influence of Al/Ti ratio and ta concentration on the As-cast microstructure, phase composition, and phase transformation temperatures of lost-wax Ni-based superalloy castings. Materials. 15(9), 3296, 1-26. https://doi.org/10.3390/ma15093296.

[17] Firstov, S.A., Gorban’, V.F., Krapivka, N.A. Karpets, M.V. & Kostenko, A.D. (2017). Wear resistance of high-entropy alloys. Powder Metallurgy and Metal Ceramics. 56, 158-164. https://doi.org/10.1007/s11106-017-9882-8.

[18] Fan, Q., Chen, C., Fan, C., Liu, Z., Cai, X., Lin, S. & Yang, C. (2021). AlCoCrFeNi high-entropy alloy coatings prepared by gas tungsten arc cladding: Microstructure, mechanical and corrosion properties. Intermetallics. 138, 107337, 1-17. https://doi.org/10.1016/j.intermet.2021.107337.

[19] Yan, G., Zheng, M., Ye, Z., Gu, J., Li, C., Wu, C., Wang, B. (2021). In-situ Ti(C, N) reinforced AlCoCrFeNiSi-based high entropy alloy coating with functional gradient double-layer structure fabricated by laser cladding. Journal of Alloys and Compounds. 886, 161252, 1-8. https://doi.org/10.1016/j.jallcom.2021.161252.


[20] Standard- ISO 6507-1:2023- Metallic materials-Vickers hardness test. [21] Standard- ASTM G75-15(2021)- Standard Test Method for Determination of Slurry Abrasivity (Miller Number) and Slurry Abrasion Response of Materials (SAR Number).

[22] Ren, Y., Wu, H., Liu, B., Liu, Y., Guo, S., Jiao, Z.B. & Baker, I. (2022). A comparative study on microstructure, nanomechanical and corrosion behaviors of AlCoCuFeNi high entropy alloys fabricated by selective laser melting and laser metal deposition. Journal of Materials Science & Technology. 131, 221-230. https://doi.org/10.1016/j.jmst.2022.05.035.

[23] Cichocki, K., Bała, P., Kwiecień, M., Szymula, M., Chrzan, K., Hamilton, C. & Muszka, K. (2024). The influence of Mo addition on static recrystallization and grain growth behaviour in CoNiFeMn system subjected to prior deformation. Archives of Civil and Mechanical Engineering. 24. https://doi.org/10.1007/s43452-024-00888-8.

[24] Xiao, D.H., Zhou, P.F., Wu, W.Q., Diao, H.Y., Gao, M.C., Song, M. & Liwae, P.K. (2017). Microstructure, mechanical and corrosion behaviors of AlCoCuFeNi-(Cr,Ti) high entropy alloys. Materials & Design. 116, 438-447. https://doi.org/10.1016/j.matdes.2016.12.036.

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Authors and Affiliations

K. Chrzan
1 2
ORCID: ORCID
B. Kalandyk
2
M. Grudzień-Rakoczy
1
ORCID: ORCID
Ł. Rakoczy
3
K. Cichocki
3

  1. Łukasiewicz Research Network – Krakow Institute of Technology, Centre of Materials and Manufacturing Research, Poland
  2. AGH University of Krakow, Faculty of Foundry Engineering, Poland
  3. AGH University of Krakow, Faculty of Metals Engineering and Industrial Computer Science, Poland
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Abstract

The article concerns the technology of layered castings made with a system where the base part is made of gray cast iron with flake graphite and the working part is made of high-chromium steel X46Cr13. The castings were produced using mould cavity preparation method utilizing a molding sand based on SiC. The idea of the research was to perform heat treatment of X46Cr13 steel directly in the casting mould, with the success of this approach guaranteed by selecting molding sand with appropriate physicochemical parameters. During the pouring and cooling of the mould, the temperature on the outer surface of the steel insert was recorded to check if it reached the required austenitization temperature. The castings were then examined for the quality of the bond between the gray cast iron base part and the steel working part, microstructure studies were conducted using light and scanning microscopes, and hardness was measured on the surface of X46Cr13 steel. Based on the conducted research, it was found that the high thermal conductivity of the molding sand made with a silicon carbide base disqualifies it for use in the analyzed technology of integrating heat treatment of X46Cr13 steel with the process of producing a bimetal system with gray cast iron. In the microstructure of the steel, in addition to martensite, pearlite and ferrite were present. Therefore, a satisfactory increase in the hardness of the working surface compared to the annealed state of X46Cr13 steel was not achieved, which ultimately confirmed that the hardening of the steel insert was unsuccessful.
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Bibliography


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[8] Przyszlak, N., Wróbel, T. & Dulska A. (2021). Influence of molding materials on the self-hardening of X46Cr13 steel / grey cast iron bimetallic castings. Archives of Metallurgy and Materials, 66(1), 43-50. DOI:10.24425/amm.2021.134757.

[9] Przyszlak, N. & Wróbel, T. (2019). Self-hardening of X46Cr13 steel integrated with base from grey cast iron in bimetallic system. Archives of Foundry Engineering, 19(2), 29-34. DOI:10.24425/afe.2019.127112.

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[11] PN-EN 10088-1,2

[12] Przyszlak, N. & Piwowarski, G. (2023). Designing of X46Cr13 steel heat treatment in condition of casting mould. Archives of Foundry Engineering. 23(2), 119-126. DOI:10.24425/afe.2023.144304.

[13] PN-H-11077:1983

[14] PN-H-11001:1985

[15] Staub, F., Adamczyk, J., Cieślakowa, Ł., Gubała J , Maciejny, A. (1994). Metallography. Katowice, Śląskie Wydawnictwo Techniczne. (in Polish).

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Authors and Affiliations

N. Przyszlak
1
T. Wrobel
1

  1. Department of Foundry Engineering, Silesian University of Technology, Towarowa 7 St., 44-100 Gliwice, Poland
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Abstract

The paper presents the results of damping coefficient tests on the ZnAl27Cu2 alloy (ZL27). The tested alloy was cast into five types of molds made of different materials (a steel mold with an ambient temperature of 20°C, a steel mold with a temperature of 100°C, a humid green sand mold, a dried green sand mold and a mold made of foundry gypsum mass). The thermophysical properties of these materials are different, and that's affecting the rate of heat absorption from the cast. Different mold materials affect obtaining different cooling rates. The cooling rate significantly affects the microstructure of the tested alloy. The specimens of investigate alloy were subjected to ultrasound and microscopic tests to assess the alloy structure. The damping coefficient has been calculated on the basis of specimen measurements obtained with the use of the signal echo method. Research shows that high structural fragmentation adversely affects the damping properties of alloys is confirmed. On the other hand, very low cooling rate, resulting in the formation of large, overgrown dendrites, does not guarantee the highest vibration damping capacity for this particular alloy. It turns out in this case a humid green sand mold, (cooling rate of 5.1 K/s) guarantees the best damping properties for the ZL27 alloy.
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Bibliography


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[15] Djurdjevič, M. & Grzinčič, M. (2012) The effect of major alloying elements on the size of the secondary dendrite arm spacing in the as-cast Al-Si-Cu alloys. Archives of Foundry Engineering. 12(1), 19-24. DOI: 10.2478/v10266-012-0004-2

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Authors and Affiliations

G. Piwowarski
1
J. Cepielik
1

  1. AGH University of Krakow, Poland
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Abstract

High pressure die casting (HPDC) is one of the most productive casting methods to produce a wide range of aluminum components with high dimensional accuracy and complex geometries. The process parameters of high-pressure casting generally directly affect the resulting quality of the castings, such as the presence of pores in the casting or the microstructure. In addition to air entrapment, porosity can also be caused by the dissolution of hydrogen. Hydrogen is released by the reaction of water vapor and melt at high temperatures and is released during solidification. These defects can lead to a significant reduction in mechanical properties such as strength and ductility and especially fatigue properties. The aim of the presented article is to describe the effect of the temperature of the core of the high-pressure mold on the presence and distribution of porosity and the microstructure of the aluminum casting in two geometric variants. The temperature of the core was changed due to the use of two flowing media in the thermoregulation circuit of the core, i.e. demineralized water and heat transfer oil and worked with a core temperature of 130 ± 5 and 165 ± 5 °C. With both geometric variants, a higher porosity was achieved when using water (core temperature 130 ± 5 °C) than when using oil (core temperature 165 ± 5 °C). The opposite results were observed for microporosity, where higher microporosity was observed for tempering oil. The microstructure of the casting with water-cooled cores was more characterized by finer grains of phase α (Al) and eutectic Si. In tempering oil, the microstructure was characterized by coarse grains of the α phase (Al) and the Si lamellae were in the form of sharp-edged formations.
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Authors and Affiliations

M. Matejka
1
ORCID: ORCID
D. Bolibruchová
1
ORCID: ORCID
R. Podprocká
2
P. Oslanec
3
ORCID: ORCID

  1. University of Zilina, Faculty of Mechanical Engineering, Department of Technological Engineering, Slovakia
  2. Rosenberg-Slovakia s.r.o., Slovakia
  3. Slovak Academy of Sciences, Institute of Materials and Machine Mechanics, Slovakia
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Abstract

In this work, a new method of near-infrared curing 3D printing sodium silicate sands (NIRC3DPSSS) driven by photovoltaic cells was proposed, and the Span-80 moisture resistance modifier was studied. NIRC3DPSSS had the advantages of high strength, rapid curing and low residual strength. However, the 24h storage strength would reduce because Na+ in the bonding bridges could absorb moisture. The experimental results showed that the strength of Span-80 modified sands molds reached 0.95MPa after 4 hours in a humidistat with 99%RH (relative humidity) containing 2.2% sodium silicate, an increase of 97.9% comparing to common sands molds. In air(80%RH), the strength reached 1.25MPa, an increase of 40.4%. The optimal effect of modification was achieved when Span-80 was 0.066% of the raw sands. Additionally, the bonding film and bridges in sodium silicate sands modified with Span-80 were more stable, smoother and free of cracks when observed using scanning electron microscopy (SEM) and energy dispersive spectroscopy(EDS).
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Authors and Affiliations

Ao Xue
1
Yuhan Tang
1
Yao Li
2
Weihong Dai
1
Jijun Lu
1
ORCID: ORCID
Huafang Wang
1
ORCID: ORCID

  1. School of Mechanical Engineering and Automation, Wuhan Textile University, China
  2. Dongfeng Motor Corporation Research & Development Institute, China
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Abstract

The article presents the results of studies of the process of accelerated drying performed by means of microwave radiation of ceramic moulds deposited on patterns made of foamed plastics used in the Ceramic Shell technology. The studies aimed at determining the microwave radiation parameters (power, downtime, and uninterrupted operation time) in order to obtain the maximally short drying times which do not cause pattern destruction. The analysis of results confirmed that an increase of the microwave radiation power shortens the drying time of the particular layers of the ceramic mould, however, at the same time, it excessively raises the temperature of the mould. With the microwave power over 1200 W, we can obtain the drying time of one layer at the level of about 30 min, and the temperature of the mould reaches the value of 70oC, which does not cause deformation or partial melting of the polystyrene pattern. From the point of view of production effectiveness, as a result of the application of microwave drying, the time of production of ceramic moulds was shortened from 7 days to 1 working day.
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Authors and Affiliations

P. Just
1
R. Kaczorowski
1
M. Topola
1
T. Pacyniak
1
ORCID: ORCID
C. Rapiejko
1
ORCID: ORCID

  1. Department of Materials Engineering and Production Systems, Lodz University of Technology, ul. Stefanowskiego 1/15, 90-537 Łódź, Poland
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Abstract

The present study evaluates the microstructural features, mechanical properties, and wear characteristics of the newly developed hybrid composite of A356/ZrO2/Al2O3/SiC produced by compo-casting at 605±5 °C, 600 rpm for 15 minutes with less than 30% solid fraction in which Bi and Sn were added separately to the matrix before introducing reinforcements. FESEM micrographs and corresponding EDS illustrated the successful incorporation of particles in the matrix. Fine particles of ZrO2 were observed close to the coarse Al2O3, and SiC particles, along with Bi and Sn elements, were detected at the eutectic evolution region. The A356+Bi/Al2O3+ZrO2+SiC hybrid composite exhibited the lowest specific wear rate (1.642 ×10-7cm3/Nm) and friction coefficient (0.31) under applied loads of 5, 10, and 20 N, in line with the highest hardness (73.4 HBN). Analysis of the worn surfaces revealed that the wear mechanism is mostly adhesive in all synthesized composites, which changed to the combination of adhesive and abrasive mode in the case containing Bi and SiC. Inserting Bi not only leads to the refinement of eutectic Si but also enhances the adhesion between the matrix/particles and improves lubricity. This, in turn, reduces the wear rate and coefficient of friction, ultimately improving the performance of the hybrid composite.
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Authors and Affiliations

S. Farahany
1
M.K. Hamdani
2
M.R. Salehloo
2
M. Krol
2
E. Cheraghali
3

  1. Buein Zahra Technical University, Iran
  2. Iran University of Science and Technology, Iran
  3. Silesian University of Technology
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Abstract

This research investigates the microstructural evolution and mechanical properties of LM25 (Al-Si-Mg) alloy and Cr-modified LM25-Cr (Al-Si-Mg-Cr) alloy. Microstructural analysis reveals distinctive ε-Si phase morphologies, with Cr addition refining dendritic structures and reducing secondary dendrite arm spacing in the as-cast condition. Cr modification results in smaller-sized grains and a modified ε-Si phase, enhancing nucleation sites and reducing ε-Si size. Microhardness studies demonstrate significant increases in hardness for both alloys after solutionising and aging treatments. Cr-enriched alloy exhibits superior hardness due to solid solution strengthening, and prolonged aging further influences ε-Si particle size and distribution. The concurrent rise in microhardness, attributed to refined dendritic structures and unique ε-Si morphology, underscores the crucial role of Cr modification in tailoring the mechanical properties of aluminium alloys for specific applications.
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Authors and Affiliations

V.V. Ramalingam
1
K.V. Shankar
2
B. Shankar
2
R. Abhinandan
3
A. Dineshkumar
3
P.A. Adhithyan
3
K. Velusamy
3
A. Kapilan
3
N. Sudheer
3

  1. Department of Mechanical Engineering, Amrita School of Engineering, Amrita Vishwa Vidyapeetham, Coimbatore, 64112, India
  2. Department of Mechanical Engineering, Amrita Vishwa Vidyapeetham, Amritapuri, India; Centre for Flexible Electronics and Advanced Marerials, Amrita Vishwa Vidyapeetham, Amritapuri, India
  3. Department of Mechanical Engineering, Amrita Vishwa Vidyapeetham, Amritapuri, India
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Abstract

A method for fabrication of a composite layer on the surface of a steel casting using coating containing TiC substrates was presented. The reaction of the synthesis of the ceramic phase was based on the SHS method (Self-propagating High-temperature Synthesis) and was triggered by the heat of molten steel. High hardness titanium carbide ceramic phases were obtained, which strengthened the base material improving its performance properties presented in this article. Microstructural examinations carried out by light microscopy (LM) on the in-situ produced composite layers showed that the layers were the products of reaction of the TiC synthesis – the phenomenon called “fragmentation” by the authors of study. The examinations carried out by scanning electron microscopy (SEM) have revealed the presence of spheroidal precipitated and free of impurities. The presence of titanium carbide was twofold increase in hardness in the area of the composite layer as compared to the base alloy which was carbon cast steel.
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Authors and Affiliations

J. Marosz
ORCID: ORCID
S. Sobula
1
ORCID: ORCID

  1. AGH University of Krakow, Poland
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Abstract

The paper presents the results of the analysis of cooling curves of cast iron with approximately eutectic composition rasterized at different rates of cooling and ingot crystallization. The test samples were in the form of rods with a diameter of 30,0.mm and a coagulation modulus M = 0.75 cm. They were cast in a sand mould made of furan mass placed on a chill in the form of a cast-iron plate, with which one of the front surfaces of the rod casting was in contact. In this way, a differentiated cooling rate along the rod was achieved. At selected distances from the chiller (5, 15, 25, 25 and 45 mm) thermocouple moulds were placed in the cavity to record the cooling curves used in thermal (AT) and derivation (ATD) analysis. The solidification time of the ingot in the part farthest from the chiller was about 200s, which corresponds to the solidification time in the test cup AT. An analysis of the recorded cooling curves was performed in order to determine the values of characteristic points on the AT curve (Tsol. Tliq, ΔTrecal., τclot, etc.). Relationships between cooling time and rate and characteristic points on AT and ATD curves were developed. For example, Tsol min changes in the range of 1115 - 1145 for the range of cast iron solidification times in the selected ingot zone from ~ 70 to ~ 200 s, which corresponds to the process speed from 0.0047 to 0.014 [1/s]. The work also includes an analysis of other characteristic points on the AT and ATD curves as functions of the solidification rate of cast iron of the same composition.
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Authors and Affiliations

J.S. Zych
1

  1. AGH University of Krakow, Faculty of Foundry Engineering, Reymonta 23. 30-059 Kracow, Poland,
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Abstract

Sodium silicate, known for its low cost and non-toxicity, has been considered as a promising option for green foundry in terms of mould sands. However, the utilization of used sodium silicate sands has posed significant challenges. To address the issues of high energy consumption and secondary pollution associated with wet and dry regeneration of sodium silicate used sands, this paper proposes a novel unattended biological regeneration system. The system involves culturing diatoms in an incubator with a solution of sodium silicate used sands. The incubator is equipped with built-in sensors that continuously monitor temperature, illuminance, pH, and water level. The monitoring data is transmitted in real-time to the Yeelink Internet of Things platform via the controller using the TCP/IP protocol. By logging onto the corresponding web page, the experimenter can remotely observe the monitoring data. The results of the experiment indicate that diatoms bloomed five times, and the water pH decreased from 10.2 to 8.2 after 40 days of cultivation. Additionally, the film removal rate of the used sands reached 90.26%.
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Authors and Affiliations

Huafang Wang
1
ORCID: ORCID
Zhaoxian Jing
1
Ao Xue
1
Yuhan Tang
1
Lei Yang
1
ORCID: ORCID
Jijun Lu
1
ORCID: ORCID

  1. School of Mechanical Engineering and Automation, Wuhan Textile University, China
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Abstract

As an alloying element in steel, manganese can considerably enhance the mechanical properties of structural steel. However, the Mn volatilisation loss in vacuum melting is severe because of the high saturated vapour pressure, resulting in an unstable Mn yield and Mn content fluctuation. Therefore, a systematic study of the volatilisation behaviour of Mn in vacuum melting is required to obtain a suitable Mn control process to achieve precise control of Mn composition, thereby providing a theoretical basis for industrial melting of high-Mn steel. In order to explore the Mn volatilization behavior, the volatilization thermodynamics and volatilisation rate of Mn, as well as the influence factors are discussed in this study. The results shows that Mn is extremely volatilised into the vapour phase under vacuum, the equilibrium partial pressure is closely related to Mn content and temperature. With an increase in the Mn content, a higher C content has a more obvious inhibitory effect on the equilibrium partial pressure of Mn. The maximum theoretical volatilisation rate of Mn shows a linear upward trend with an increase in Mn content. However, a higher C content has a more obvious effect on the reduction of the maximum theoretical volatilisation rate with the increase of Mn content. This study provides an improved understanding of Mn volatilisation behaviour as well as a theoretical foundation for consistent Mn yield control during the vacuum melting process of high-Mn steel.
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Authors and Affiliations

Jialiu Lei
1
Yongjun Fu
1
Li Xiong
2

  1. Hubei Polytechnic University, China
  2. Hubei Guoan Special Steel Inspection and Testing Co., Ltd.
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Abstract

The article discusses the growing importance of decarbonization of production systems in the foundry industry as a response to climate challenges and increasing requirements for sustainable development. The process of reducing greenhouse gas emissions in foundry production is caused by a number of reasons. Decarbonization of the foundry industry refers to actions aimed at reducing greenhouse gas emissions, especially carbon dioxide (CO2). Reducing carbon dioxide emissions is increasingly being considered as a key element of the strategy of both small and large foundries around the world. Foundry is one of the industries that generates significant amounts of carbon dioxide emissions due to the energy consumption in the process of melting and forming metals. There is virtually no manufacturing industry that does not use elements cast from iron, steel or non-ferrous metals, ranging from elements made of aluminum to zinc. The article presents various decarbonization strategies available to foundries, such as: the use of renewable energy, the use of more efficient melting technologies, or the implementation of low-energy technologies throughout the production process. Application examples from different parts of the world illustrate how these strategies are already being put into practice, as well as the potential obstacles and challenges to full decarbonization.
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Authors and Affiliations

C. Kolmasiak
1

  1. Czestochowa University of Technology, Faculty of Production Engineering and Materials Technology, Department of Production Management, Poland
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Abstract

The publication presents a new shooting technique with reduced pressure in venting system for manufacturing foundry cores using inorganic sand mixture with Cordis binder. Traditional technologies for producing casting cores using blowing methods, despite their undeniable advantages, including the ability to produce cores in series, also come with some disadvantages. The primary drawbacks of the process involve uneven compaction structure of the cores, with denser areas primarily located under the blow holes, and under-shooting defects, which often occur in regions away from the blow hole or in increased core cross-sectional areas. In an effort to improve core quality, a concept was developed that involves incorporating a reduced pressure in the core box venting system to support the basic overpressure process. The solutions proposed in the publication with a vacuum method of filling the cavities of multi-chamber core boxes solve a number of technical problems occurring in conventional blowing technologies. It eliminates difficulties associated with evacuating the sand from the chamber to the shooting head and into technological cavity and increases the uniform distribution and initial degree of compacting of grains in the cavity. The additive role of this “underpressure” support is to enhance corebox venting by eliminating 'air cushions' in crevices and structural elements that obstruct the flow of evacuated air. The publication presents the results of studies on core manufacturing using blowing methods conducted in three variants: classic overpressure, utilizing the core box filling phenomenon by reducing pressure, and an integrated approach combining both these methods.
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Authors and Affiliations

M. Skrzyński
1
R. Dańko
1
ORCID: ORCID
G. Dajczer
2

  1. AGH University of Krakow, Poland
  2. KPR PRODLEW-KRAKÓW Spółka z o.o., Alfreda Dauna 78, 30-629 Krakow, Poland
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Abstract

In the paper, the results of a numerical analysis of KCl and KF particles present in liquid aluminium assimilation to the slag are presented. The authors analysed particle movement in the slag model, which is based on buoyant, capillary, viscosity, Newton and repulsion forces, interfacial tensions at the interface of phases and surface energy during the particle movement through phases boundary. On the basis of the mathematical model, a computer programme was written to make simulations under different conditions. The results of particle position in the slag are presented for different particle radiuses: 1, 5, 10, 20 μm, and constant viscosity of the slag including velocity evolution of the velocity. Another approach was used to indicate the influence of slag viscosity on particle and slag penetration depth. During computations, selected viscosities of slag of 0.0012, 0.0015, 0.0018 [kg/m·s] were taken into account. Different comparisons were made for the chosen particle sizes. Each examination takes into account the impact of the particle type. The results clearly show that for larger particles the penetration depth is greater and viscosity of the slag has an impact on the velocity evolution during assimilation process.
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Authors and Affiliations

P.L. Żak
1
K. Kuglin
2
M. Szucki
3
ORCID: ORCID
D. Kalisz
1
ORCID: ORCID
N. Mrówka
E. Dand

  1. AGH University of Krakow, Krakow, Poland
  2. NPA Skawina Sp. z o. o., Poland
  3. Technische Universität Bergakademie Freiberg, Germany
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Abstract

Austenitic Fe-Ni-Cr alloys are commonly used for the production of castings intended for high-temperature applications. One area where Fe-Ni-Cr castings are widely used is the equipment for heat treatment furnaces. Despite the good heat resistance properties of the materials used for the castings, they tend to develop cracks and deformations over time due to cyclic temperature changes experienced under high temperature operating conditions. In the case of carburizing furnace equipment, thermal stresses induced by the temperature gradient in each operating cycle on rapidly cooled elements have a significant influence on the progressive fatigue changes. In the carburized subsurface zone, also the different thermal expansion of the matrix and non-metallic precipitates plays a significant role in stress distribution. This article presents the results of analyses of thermal stresses in the surface and subsurface layer of carburized alloy during cooling, taking into account the simultaneous effect of both mentioned stress sources. The basis for the stress analyzes were the temperature distribution in the cross-section of the cooled element as a function cooling time, determined numerically using FEM. These distributions were taken as the thermal load of the element. The study presents the results of analyses on the influence of carbide concentration increase on stress distribution changes caused by the temperature gradient. The simultaneous consideration of both thermal stress sources, i.e. temperature gradient and different thermal expansions of phases, allowed for obtaining qualitatively closer results than analyzing the stress sources independently
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Authors and Affiliations

A. Bajwoluk
1
ORCID: ORCID
P. Gutowski
1
ORCID: ORCID

  1. Mechanical Engineering Faculty, West Pomeranian University of Technology, Szczecin Al. Piastów 19, 70-310 Szczecin, Poland
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Abstract

Microwave Assisted Self-propagating High-temperature Synthesis (MASHS) was used to prepare open-porous MAX phase preforms in Ti-Al-C and Ti-Si-C systems, which were further used as reinforcements for Al-Si matrix composite materials. The pretreatment of substrates was investigated to obtain open-porous cellular structures. Squeeze casting infiltration was chosen to be implemented as a method of composites manufacturing. Process parameters were adjusted in order to avoid oxidation during infiltration and to ensure the proper filling. Obtained materials were reproducible, well saturated and dense, without significant residual porosity or undesired interactions between the constituents. Based on this and the previous work of the authors, the reinforcement effect was characterized and compared for both systems. For the Al-Si+Ti-Al-C composite, an approx. 4-fold increase in hardness and instrumental Young's modulus was observed in relation to the matrix material. Compared to the matrix, Al-Si+Ti-Si-C composite improved more than 5-fold in hardness and almost 6-fold in Young's modulus. Wear resistance (established for different loads: 0.1, 0.2 and 0.5 MPa) for Al-Si+Ti-Al-C was two times higher than for the sole matrix, while for Al-Si+Ti-Si-C the improvement was up to 32%. Both composite materials exhibited approximately two times lower thermal expansion coefficients than the matrix, resulting in enhanced dimensional stability.
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Authors and Affiliations

A. Dmitruk
1
ORCID: ORCID
K. Naplocha
1
ORCID: ORCID
A. Żak
2
A. Strojny-Nędza
3

  1. Wrocław University of Science and Technology, Faculty of Mechanical Engineering, Department of Lightweight Elements Engineering, Foundry and Automation, Poland
  2. Wrocław University of Science and Technology, Faculty of Chemistry, Institute of Advanced Materials, Poland
  3. Łukasiewicz Institute of Microelectronics and Photonics, Poland
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Abstract

This paper presents the results of a study on the use of infrared thermography to assess the quality of liquid metal, a basic semi-finished product used in foundry production. EN AC-46000 alloy with the designation AlSi9Cu3(Fe) was used for the study. The crystallization process of the alloy was investigated using the TDA method with a Crystaldigraph device and Optris PI thermal imaging camera. The research describes how to use a thermal imaging camera to assess the quality of aluminium alloys. These alloys, due to their propensity in the liquid state to oxidise and absorb hydrogen, a refining procedure in the melting process. The effects of alloy refining are evaluated during technological tests of hydrogen solubility, density and casting shrinkage. The results presented in this paper showed that there is a statistical correlation between the density of the metal and the temperature values from the thermogram of the sample, obtained during its solidification. The existing correlation makes it possible to develop a thermographic inspection algorithm that allows a fast and non-contact assessment of aluminium alloy quality.
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Authors and Affiliations

Ryszard Władysiak
1
ORCID: ORCID

  1. Lodz University of Technology, Department of Materials Engineering and Production Systems, Łódź, Poland
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Abstract

An as-cast aluminum billet with a diameter of 100 mm has been successfully prepared from aluminum scrap by using direct chill (DC) casting method. This study aims to investigate the microstructure and mechanical properties of such as-cast billets. Four locations along a cross-section of the as-cast billet radius were evaluated. The results show that the structures of the as-cast billet are a thin layer of coarse columnar grains at the solidified shell, feathery grains at the half radius of the billet, and coarse equiaxed grains at the billet center. The grain size tends to decrease from the center to the surface of the as-cast billet. The ultimate tensile strength (UTS) and the hardness values obtained from this research slightly increase from the center to the surface of the as-cast billet. The distribution of Mg, Fe, and Si elements over the cross-section of the as-cast billet is inhomogeneous. The segregation analysis shows that Si has negative segregation towards the surface, positive segregation at the middle, and negative segregation at the center of the as-cast billet. On the other hand, the Mg element is distributed uniformly in small quantities in the cross-section of the as-cast billet.
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Authors and Affiliations

Kardo Rajagukguk
1 2 4
ORCID: ORCID
Suyitno Suyitno
3 4
Harwin Saptoadi
1
I. K. Indraswari Kusumaningtyas
1
Budi Arifvianto
1 4
Muslim Mahardika
1 4

  1. Department of Mechanical and Industrial Engineering, Faculty of Engineering, Universitas Gadjah Mada, Jl. Grafika 2, Yogyakarta 55281, Indonesia
  2. Department of Mechanical Engineering, Institut Teknologi Sumatera (ITERA), Jl. Terusan Ryacudu, South Lampung, Lampung 35365, Indonesia
  3. Department of Mechanical Engineering, Faculty of Engineering, Universitas Tidar, Jl. Kapten Suparman 39, North Magelang, 56116, Indonesia
  4. Center for Innovation of Medical Equipment and Devices (CIMEDs), Universitas Gadjah Mada, Jl. Teknika Utara Yogyakarta 55281, Indonesia
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Abstract

As a part of this work, an analysis of the current state of knowledge regarding the use of additive technology - binder jetting in the production of castings was made. The binder jetting (so-called 3D printing) has become the leading method of sand mold and core production. Within this paper types of molding and core sands with organic and inorganic binders that are and can be used in technology were analyzed. The need to carry out works aimed at developing pro-ecological molding / core sands with inorganic binders and organic binders with reduced harmfulness to the environment dedicated to binder jetting technology was noticed. The influence of technology parameters on the properties of molding / core sands and the properties of cast components was analyzed. It was shown that thanks to the unlimited shapes of the systems obtained with the use of additive technologies, it is possible to influence the rate of heat dissipation through the mold, which positively effects the process of solidification and crystallization of the castings.
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Authors and Affiliations

Dawid Halejcio
1
ORCID: ORCID
Katarzyna Major-Gabryś
1
ORCID: ORCID

  1. AGH University of Krakow, Faculty of Foundry Engineering Department of Moulding Materials, Mould Technology and Non-ferrous Metals al. A. Mickiewicza 30, 30-059 Krakow
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Abstract

Convection caused by gravity and forced flow are present during casting. The effect of forced convection generated by a rotating magnetic field on the microstructure and precipitating phases in eutectic and hypoeutectic AlSiMn alloys was studied in solidification by a low cooling rate and low temperature gradient. The chemical composition of alloys was selected to allow joint growth or independent growth of occurring α-Al, α-Al15Si2Mn4 phases and Al-Si eutectics. Electromagnetic stirring caused instead of equiaxed dendrites mainly rosettes, changed the AlSi eutectic spacing, decreased the specific surface Sv and increased secondary dendrite arm spacing λ2 of α-Al, and modified the solidification time. Forced flow caused complex modification of pre-eutectic and inter-eutectic Mn-phases (Al15Si2Mn4) depending on the alloy composition. By high Mn content, in eutectic and hypoeutectic alloys, stirring caused reduction in the number density and a decrease in the overall dimension of pre-eutectic Mn-phases. Also across cylindrical sample, specific location of occurring phases by stirring was observed. No separation effect of Mn-phases by melt flow was observed. The study provided an understanding of the forced convection effect on individual precipitates and gave insight of what modifications can occur in the microstructure of castings made of technical alloys with complex composition.
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Authors and Affiliations

P. Mikolajczak
1
ORCID: ORCID

  1. Poznan University of Technology, Poland
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Abstract

A statistical approach was conducted to investigate effect of independent factors of the mixing time compactability and bentonite percentage on dependent variables of permeability, compression and tensile strength of sand mould properties. Using statistical method save time in estimating the dependent variables that affect the moulding properties of green sand and the optimal levels of each factor that produce the desired results.
The results yielded indicate that there are variations in the effects of these factors and their interactions on different properties of green sand. The outcomes obtained a range of permeability values, with the highest and lowest numbers being 125 and 84. The sand exhibited high values of tensile and compressive strength measuring at 0.33N/cm2 and 17.67N/cm2. Conversely it demonstrated low levels of tensile and compressive strength reaching 0.14N/cm2 and 9.32N/cm2.
These results suggest that the moulding factors and their interactions have an important role in determining properties of the green sand. ANOVA was used to assess effect of various factors on different properties of the green sand. The results obtained suggest that compactability factor play a significant effect on permeability, the mixing time or bentonite factor has a significant effect on the compressive strength and mixing time or compactability factor has a significant impact on the tensile strength with a significance level lower than 5%. It is found that neither the mixing time nor the amount of bentonite used in the green sand mix has a significant impact on its permeability. Compactability of the green sand does not has a significant effect on the compressive strength. Bentonite used in green sand mix does not have a significant impact on its tensile strength.
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Authors and Affiliations

Dheya Abdulamer
1
ORCID: ORCID

  1. University of Technology, Iraq
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Abstract

Dokra casting is famous for its Artistic value to the world but it is also sophisticated engineering. The technique is almost 4500 years old. It is practiced by the tribal artisans of India. It is a clay moulded wax-based thin-walled investment casting technique where liquid metal was poured into the red hot mould. Dimensional accuracy is always preferable for consumers of any product. Distortion is one of the barriers to achieving the accurate dimension for this type of casting especially for the bending parts. The cause and nature of the distortion for this type of casting must be analyzed to design a product with nominal tolerance and dimensional accuracy.
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Authors and Affiliations

R. Mandal
1
S. Roy
2
ORCID: ORCID
S. Sarkar
1
T. Mandal
3
A.K. Pramanick
2
G. Majumdar
1

  1. Mechanical Engineering Department, Jadavpur University, India
  2. Metallurgical and Material Engineering Department, Jadavpur University, India
  3. Metallurgy and Materials Engineering, IIEST Shibpur, India

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