Szargut proposed the algorithm for determination of the influence of irreversibility of components of thermal process on the emission of CO2 [6]. In the presented paper, basing on Szargut's proposal, the example of analysis of influence of operational parameters of coal fired power plant on the local increase of CO2 emission is presented. The influence of operational parameters on the local exergy losses appearing in components of investigated power plant are simulating making use of the semi-empirical model of power plant.