The paper presents results of a study concerning an AlSi7Mg alloy and the effect of subjecting the liquid metal to four different processes: conventional refining with hexachloroethane; the same refining followed by modification with titanium, boron, and sodium; refining by purging with argon carried out in parallel with modification with titanium and boron salts and strontium; and parallel refining with argon and modification with titanium, boron, and sodium salts. The effect of these four processes on compactness of the material, parameters of microstructure, and fatigue strength of AlSi7Mg alloy after heat treatment. It has been found that the highest compactness (the lowest porosity ratio value) and the most favorable values of the examined parameters of microstructure were demonstrated by the alloy obtained with the use of the process including parallel purging with argon and modification with salts of titanium, boron, and sodium. It has been found that in the fatigue cracking process observed in all the four variants of the liquid metal treatment, the crucial role in initiation of fatigue cracks was played by porosity. Application of the process consisting in refining by purging with argon parallel to modification with Ti, B, and Na salts allowed to refine the microstructure and reduce significantly porosity of the alloy extending thus the time of initiation and propagation of fatigue cracks. The ultimate effect consisted in a distinct increase of the fatigue limit value.
With the aid of eutectic modification treatment, the precipitation of coarse lamellar eutectic silicon can be suspended during the solidification of aluminum-silicon alloys, thereby the formation of fine-grained, fibrous eutectic Si can be promoted by the addition of small amounts of modifying elements, such as Sr, to the liquid alloy. The effectiveness of this technique is, however, highly dependent on many technological factors, and the degree of modification can be lowered during the various stages of melt preparation due to the oxidation of the Sr-content of the melt. During our research, we investigated the effect of rotary degassing melt treatments coupled with the addition of three different fluxes on the degree of modification of an Al-Si-Mg-Cu casting alloy. It was also studied, that whether additional Sr alloying made before and during the melt treatments can compensate the Sr fading with time. The degree of eutectic modification was characterized by thermal analysis (TA) and the microscopic investigation of TA specimens. It was found, that by using one of the three fluxes, and by adding Sr master alloy rods before the melt treatments, better modification levels could be achieved. It was also found that the measurement of Sr-concentration by optical emission spectroscopy alone cannot be used for controlling the level of eutectic modification.
The morphology of G20Mn5 specimens made of non-modified and rare earth metals (REM) modified cast steel was investigated. Molten metal was treated with a cerium-rich mischmetal contain 49.8% Ce, 21.8% La, 17.1% Nd, 5.5% Pr and 5.35% other rare earth metals making up the balance. The melting, quenching (920°C/water) and tempering (720°C/air) were performed under industrial conditions. Analysis included G20Mn5 cast steel fracture specimens subjected to Charpy V-notch impact testing at 20°C, -30°C and -40°C. The purpose of the analysis was to determine the influence of REM on the microstructure and mechanical properties of G20Mn5 cast steel and the REM effect on the morphology, impact strength and character of the fracture surfaces. In addition, a description of the mechanism by which fracture occurred in the two materials was proposed. The author demonstrated the beneficial effects of adding REM to molten steel, manifested by a 20 - 40% increase in impact toughness, depending on test temperature, as compared to the non-modified cast steel. Important findings included more than 100% increase in impact strength in comparison with the required impact toughness of 27J at -40C for heat treated steels (EN 10213).
The paper presents the results of investigations concerning the influence of gray cast iron modification on free vibration frequency of the disc casting. Three different chemical composition melts of gray cast iron were prepared in induction furnace. During gravity casting 0.05% and 0.3% mass of the Inolate modifier was added on stream of metal for changing graphite flakes in castings. Sound signal vibration of cast iron sample was registered by means on microphone for free vibration frequency measurements. Decreasing of free vibration frequency of modified cast iron in comparison with non modified castings was observed. Higher contents of modifier causes more decreasing of free vibration frequency. Cast iron with smaller contents of carbon and silicon have higher free vibration frequency in comparison with eutectic composition cast iron. Hardness of examined cast iron is lower when the more modifier is added during modification process. Free frequency is smaller with smaller Brinell hardness of disc casting. It was concluded that control of free vibration frequency of disc castings by means of chemical composition and modification process can improved comfort and safety of working parts.
Cells of a multicellular organism are genetically identical but differ in structure and function. This heterogeneity is created by several epigenetic mechanisms during the development of the organism. The epigenetic changes- including DNA methylation, histone post-translational modifications, chromatin remodeling and RNA interference have all been shown to control chromatin structure and regulate a plethora of cellular and organismal processes. There is a strong evidence that epigenetics play a crucial role in the development of diseases such as cancer, schizophrenia or metabolic disorders. The epigenetic regulation underlie memory formation or adaptation to external stimuli. The extent to which environmental effects can provoke epigenetic responses represents an exciting area of future research. Here we review the current knowledge about the epigenetic mechanisms and their relation to the human health and disease.
According to the results of digitization of the experimental studies carried out in the past concerning Fe-C alloys solidification in cylindrical molds of castings with a carbon content of 0.04%, 0.1%, 0.4%, 0.93%, 1.42%; 2.44%, 3.28%, 4.45%, 4.83% and their subsequent interpolation in the range of 0.04 ÷4.83% С there were obtained the curves of the advancement of the pour point, liquidus and solidus in the coordinates of the relative thickness of the solidified metal layer x/R and the parametric criterion τ/R2. Their usage is proposed for the development of modes of physical and chemical influence on the liquid metal in the axial zone of the casting after solidification of its calculated layer. Calculation of the mass of modifiers or deoxidizers for introduction into the axial zone was performed in relation to the total mass of metal in the liquid and liquid-solid zones of the casting. The technique for calculating the mass and time of introduction a graphitizing modifier into the axial zone of rolling rolls made of hypereutectoid steel with 1.7% C is proposed to reduce the negative impact of cementite, chromium and molybdenum carbides on the structure of the axial zone of the rolls. The obtained curves can also be used to assess the accuracy of computer modeling of the processes of Fe-C alloys solidification and further adaptation of mathematical models by the correction of thermophysical coefficients, the values of which are not always known in the liquidus-solidus temperature range.
The effect of laser processing on the structure, microstructure and hardness of high-speed steel produced by powder metallurgy was investigated. The samples were surfaces remelted with impulse CO2 laser radiation under different operation conditions. In the remelted layer, the presence of full remelting, partial remelting and heat affected zones was detected. As a result of concentrated laser beam treatment, microstructures characteristic of the rapid crystallization process were observed. The microstructure in the full remelting zone was characterized by a fine microdendritic structure with the average distance between the secondary axes of dendrites below 1 µm and the dissolution of primary carbides. Retained austenite was found in the remelted samples, the amounts of which depended on the treatment parameters and grew with an increase in the speed of the laser beam movement. There was no unequivocal effect of the distance of the irradiated surface from the focus of the beam focusing system on the content of retained austenite. Due to the presence of retained austenite in the remelted part, the hardness decreased by about 23% compared to the hardness of the material before the treatment. On the other hand, laser processing leads to strong refinement of the microstructure and eliminates the residual porosity of powder steels, which can increase the toughness and cutting performance of steel. The research also showed the possibility of shaping the geometry of the remelting zone by the appropriate selection of machining parameters
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