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Abstract

The subject of the work are modern composite materials with increased wear resistance intended for elements of machines operating in difficult conditions in the construction and mining industries. The study determined the effect of zone reinforcement of GX120Mn13 cast steel with macroparticles (Al 2O 3+ZrO 2) on the corrosion resistance and abrasion wear of the composite thus obtained. SEM studies have shown that at interface between two phases, and more precisely on the surface of particles (Al 2O 3+ZrO 2) a durable diffusion layers are formed. During the corrosion tests, no significant differences were found between the obtained parameters defining the corrosion processes of GX120Mn13 cast steel and GX120Mn13 with particles (Al 2O 3+ZrO 2) composite. No intergranular corrosion was observed in the matrix of the composite material, nor traces of pitting corrosion at both phases interface. This is very important in terms of tested material’s service life. Reinforcement of cast steel with particles (Al 2O 3+ZrO 2) resulted in a very significant improvement in the abrasion resistance of the composite – by about 70%. After corrosion tests, both materials were subjected to further operational investigations. These examinations consisted in determining the impact of corrosion processes on the durability of the composite in terms of abrasion. The obtained results indicate that corrosion processes did not significantly deteriorate the wear resistance of both the cast steel and the composite.
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Bibliography

[1] Uetz, H. (1986). Abrasion and Erosion. Munich–Vienna: Carl Hanser Verlag Publ.
[2] Hebda, M., Wachal, A. (1980). Trybology. Warsaw: Scientific and Technical Publ (in Polish).
[3] Kalandyk, B., Zapała, R., Kasińska, J. & Madej, M. (2021). Evaluation of microstructure and tribological propertiesof GX120Mn13 and GX120MnCr18-2 cast steels. Archives of Foundry Engineering. 21(4), 67-76. DOI: 10.24425/afe.2021.138681.
[4] Marcus, P. (2017). Corrosion mechanisms in theory and practice. London–New York: CRC Press.
[5] Podrzucki, C. (1991). Cast iron. Structure, properties, application. vol. 2. Krakow: ZG STOP Publ (in Polish).
[6] Kaczmar, J., Janus, A., Samsonowicz, Z. (1998). Influence of technological parameters on the production of selected parts of machines reinforced with ceramic fibers. Report of Institute of Machine and Automation Technology, Wroclaw University of Science and Technology, Series SPR, 35 (in Polish). [7] Kurzawa, A., Kaczmar, J.W. & Janus, A. (2008). Selected mechanical properties of aluminum composite materials reinforced with SiC particles. Archives of Foundry Engineering. 8(2), 99-102.
[8] Kaczmar, J.W. & Kurzawa, A. (2012). The effect of α-alumina particles on the properties of EN AC-44200 Al alloy based composite materials. Journal of Achievements in Materials and Manufacturing Engineering. 55(1), 39-44.
[9] Jach, K., Pietrzak K., Wajler, A., Sidorowicz, A. & Brykała, U. (2013). Application of ceramic preforms to the manufacturing of ceramic – metal composites. Archives of Metallurgy and Materials, 58(4), 1425-1428. DOI: 10.2478/amm-2013-0188.
[10] Gawroński, J., Szajnar, J. & Wróbel, P. (2004). Study on theoretical bases of receiving composite alloy layers on surface of cast steel castings. Journal of Materials Processing Technology. 157, 679-682. DOI: 10.1016/j.jmatprotec.2004.07.153.
[11] Szajnar, J., Walasek, A., & Baron, C. (2013). Tribological and corrosive properties of the parts of machines with surface alloy layer. Archives of Metallurgy and Materials. 58(3), 931-936. DOI: 10.2478/amm-2013-0104.
[12] Hryniewicz, T., Rokosz, K. (2010). Theoretical basis and practical aspects of corrosion. Koszalin: Publ. House of Koszalin University of Technology (in Polish).
[13] Medyński, D. & Chęcmanowski, J. (2022). Corrosion resistance of L120G13 steel castings zone-Reinforced with Al2O3. Materials. 15(12), 4090, 1-14. https://doi.org/10.3390/ma15124090.
[14] Song, Y., Jiang, G., Chen, Y., Zhao, P. & Tian, Y. (2017). Effects of chloride ions on corrosion of ductile iron and carbon steel in soil environments. Scientific Reports. 7, 6865, 1-13. https://doi.org/10.1038/s41598-017-07245-1.

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Authors and Affiliations

Daniel Medyński
1
ORCID: ORCID

  1. Witelon Collegium State University, Poland
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Abstract

The mutual influence of fatigue processes, abrasive wear and corrosion of chain links on the functional properties of mining round link chains has been presented in this paper. Selected results of experimental investigations in the field of synergic impact of these destructive processes on the operational durability of mining chains have also been presented. The emphasis was given to the necessity of a comprehensive consideration of destructive processes that occur in various conditions of use of round link chains applied in mining machines.
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Bibliography

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[9] H . Kania, Kształtowanie struktury oraz odporność korozyjna powłoki Zn-Al otrzymanych metodą metalizacji zanurzeniowej. Wydawnictwo Politechniki Śląskiej, Gliwice (2017).
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[13] A .N. Wieczorek, Influence of Shot Peening on Abrasion Wear in Real Conditions of Ni-Cu-Ausferritic Ductile Iron. Arch Metall. Mater. 61 (4), (2016).
[14] A .N. Wieczorek, Comparative studies on the wear of ADI alloy cast irons as well as selected steels and surfacehardened alloy cast steels in the presence of abrasive. Arch. Metall. Mater. 62 (1), (2017).
[15] S. Mikuła, Ł. Gajda, Metody badań zużycia ściernego łańcuchów górniczych. Zeszyty Naukowe Politechniki Śląskiej, s. Górnictwo 93 (1978).
[16] E . Remiorz, S. Mikuła, Diagnosis of round link chains resistance to abrasive wear. Technicka Diagnostika 27 (1), (2018).
[17] B . Pawlukiewicz, J. Wiederman, Mechanizm niszczenia ogniw łańcuchów górniczych podczas eksploatacji. Inżynieria Materiałowa 19 (5), (1998).
[18] E . Remiorz, S. Mikuła, Eksploatacyjna diagnostyka ogniwowych łańcuchów górniczych stosowanych w pociągowych układach łańcuchowych maszyn ścianowych. Maszyny Górnicze 36 (1), (2018).
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Authors and Affiliations

Eryk Remiorz
1
ORCID: ORCID
Stanisław Mikuła
1
ORCID: ORCID

  1. Silesian University of Technology, Faculty of Mining, Safety Engineering and Industrial Automation, Department of Mining Mechanization and Robotisation, 2 Akademicka Str., 44-100 Gliwice, Poland
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Abstract

The paper presents results of research on steel castings GX120Mn13 (L120G13 by PN-89/H-83160), zone-reinforced by elektrocorundum particles (Al2O3), with a grain size from 2 to 3.5 mm. Studies revealed continuity at interface between composite components and formation of a diffusion zone in the surface layer of electrocorundum grains. In the area of this zone, simple manganese segregation and reverse iron and chromium segregation were found. The transfer of these elements from cast steel to electrocorundum grains resulted superficial depletion in aluminum and oxygen in this area. No porosity was observed at the interface between two components of the composite. We found it very beneficial from an exploitation point of view, as confirmed by the study of resistance to abrasive wear.
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Bibliography

[1] Matthews, F.L., Rawlings, R.D. (1999). Composite Materials. Engineering and Science. CRC Press: Boca Raton, FL, USA.
[2] Kocich, R., Kunčická, L., Král, P. & Strunz, P. (2018). Characterization of innovative rotary swaged Cu-Al clad composite wire conductors. Materials Design. 160, 828-835. Materials 2020. 13, 4161, p. 13 of 15.
[3] Kunčická, L., Kocich, R., Dvořák, K. & Macháčková, A. (2019). Rotary swaged laminated Cu-Al composites. Effect of structure on residual stress and mechanical and electric properties. Materials Science Engineering A. 742, 743-750.
[4] Kunčická, L., Kocich, R. (2018) Deformation behaviour of Cu-Al clad composites produced by rotary swaging. IOP Conf. Ser. Mater. Sci. Eng. 369, Kitakyushu City, Japan.
[5] Clyne, T.W., Withers, P.J. (1993) An Introduction to Metal Matrix Composites. Cambridge University Press: New York, NY, USA.
[6] Tjong, S. & Ma, Z. (2000). Microstructural and mechanical characteristics of in situ metal matrix composites. Materials Science Engineering R: Reports 29, 49-113.
[7] Górny, Z., Sobczak, J. (2005). Modern casting materials based on non-ferrous metals. Krakow. Ed. ZA-PIS.
[8] Sobczak, J. & Sobczak, N. (2001). Pressure infiltration of porous fibrous structures with aluminum and magnesium alloys. Composites. 1(2), 155-158.
[9] Klomp, J. (1987). Fundamentals of diffusion bonding. Amsterdam Ed. Ishida, Elsevier Science Publishers, 3-24.
[10] Kaczmar, J., Janus, A., Samsonowicz, Z. (1997). Influence of technological parameters on production of selected machine parts reinforced with ceramic fibers. Reports of Institute of Machine Technology and Automation of Wrocław University of Science and Technology. SPR No 5.
[11] Kaczmar, J., Janus, A., Kurzawa, A. (2002). Development of basics technology of manufacturing machine and device parts from aluminum composites reinforced with zones of ceramic particles. Reports of Institute of Machine Technology and Automation of Wrocław University of Science and Technology. SPR No 11.
[12] Dmitruk, A.G., Naplocha, K., Żak, A. M., Strojny-Nędza, A., Dieringa, H. & Kainer, K. (2019). Development of pore-free Ti-Si-C MAX/Al-Si composite materials manufactured by squeeze casting infiltration. Journal of Materials Engineering and Performance. 28(10), 6248-6257.
[13] Maj, J., Basista, M., Węglewski, W., Bochenek, K., Strojny-Nędza, A., Naplocha, K., Panzner, T., Tatarková, M., Fiori, F. (2018). Effect of microstructure on mechanical properties and residual stresses in interpenetrating aluminum-alumina composites fabricated by squeeze casting. Materials Science and Engineering. A, Structural Materials: Properties, Microstructure and Processing. 715,154-162.
[14] Szajnar, J., Wróbel, P., Wróbel, T. (2008). Model castings with composite surface layer - application. Archive of Foudry Enginnering. 8(3), 105-110.
[15] Gawroński, J., Szajnar, J., Wróbel, P. (2005). Surface composite layers of cast iron - ceramic particles. Archive of Foundry. 5(17), 107-114.
[16] Marcinkowska, J. (1986). Wear-resistant casting coatings on cast steel. Solidification of Metals and Alloys. 6, 37-42.
[17] Baron, Cz., Gawroński, J. (2006). Abrasive wear resistance of sandwich composites based on iron alloys. Composites. 6(3), 45-49.
[18] Operation and maintenance documentation of test stand T-07.
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Authors and Affiliations

Daniel Medyński
ORCID: ORCID
A.J. Janus
1

  1. Witelon State University of Applied Science in Legnica ul. Sejmowa 5A, 59 – 220 Legnica, Poland
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Abstract

In the present research, we used molecular dynamics simulation to determine the effect of cutting parameters on micro-grain boundary structures and Burgers vector distribution in single crystal iron and polycrystalline iron materials. The result showed that the destruction of the lattice in polycrystalline iron caused by the cutting tool was restricted to the contact surface area. In addition, in the precision machining process, a higher refining grain was observed on the iron surface. During the cutting process of single crystal iron, large-scale slip occurred along the <111> crystal direction on the {110} crystal plane. And the slip presented an annular shape.
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Authors and Affiliations

Zhiming Liu
1
Qiang Zhang
2
Fangying Liu
2
Hezhe Zhang
2

  1. China University of Mining and Technology (Beijing), Beijing 100083, China
  2. Shandong University of Science and Technology, Qingdao 266590, Shandong, China
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Abstract

Currently, due to the economic and ecological aspects, light alloys are increasingly important construction material, in particular in the transport industry. One of the popular foundry magnesium alloys is the alloy AZ91, which among others due to mechanical properties and technological features, is used, for example, for light structural parts.
The paper presents the results of research on modification of the AZ91 alloy surface layer in the plasma electrolytic oxidation process. The change of usable properties of the produced coatings was obtained by introducing additions of silicon carbide or boron nitride. The thickness and hardness of the protective layers produced, resistance to scratches and corrosion resistance were determined. Moreover, the friction coefficient of the coating-steel pair was investigated. The quality of the connections made between the coating and the substrate, i.e. the magnesium alloy, was also evaluated. The results obtained for coatings with silicon carbide or boron nitride additives were always compared to the results obtained for unmodified samples.
On the basis of the obtained results, it was shown that the introduction of boron nitride additive to the AZ91 alloy coating produced in the plasma electrolytic oxidation process significantly improves the resistance to: (i) corrosion and (ii) abrasive wear of the coating.
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Authors and Affiliations

D. Pelczar
1
P. Długosz
2
ORCID: ORCID
P. Darłak
2
ORCID: ORCID
A. Szewczyk-Nykiel
1
ORCID: ORCID
M. Nykiel
1
ORCID: ORCID
M. Hebda
1
ORCID: ORCID

  1. Cracow University of Technology, Faculty of Materials Engineering and Physics, Department of Materials Engineering, 24 Warszawska St r., 31-155 Krakow, Poland
  2. Centre of Casting Technology, Research Network Lukasiewicz-Krakow Institute of Technology, Zakopiańska 73, 30-418 Krakow, Poland
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Abstract

The paper presents the results from a study on the impact of the cooling rate in the eutectoid transition on the abrasive wear of the as cast Zn-4Al alloy. The microstructure of the researched material consists of dendrites of the η solid solution and an (α+η) eutectic structure. During the eutectoid transformation at 275oC the distribution in the eutectic structure was transformed and fined. Heat treatment was carried out for this alloy, during which three cooling mediums were used, i.e. water, air and an furnace. For the research material obtained in this way, metallographic examinations were performed using the methods of light and scanning electron microscopy, as well as hardness measurements. It was found that faster cooling rate promoted the fragmentation of structural components, which translates into higher hardness of the material. This also had effects in the tribological wear of the tested alloy. As part of the tests, an abrasive wear test was carried out on a standard T-07 tester.

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Authors and Affiliations

M.M. Lachowicz
T. Leśniewski
M.B. Lachowicz
R. Jasionowski
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Abstract

Cast martensitic alloy steel is used for the production of parts and components of machines operating under conditions of abrasive wear. One of the most popular grades is cast steel GX70CrMnSiNiMo2 steel, which is used in many industries, but primarily in the mining and material processing sectors for rings and balls operating in the grinding sets of coal mills. To improve the abrasion resistance of cast alloy tool steel, primary titanium carbides were produced in the metallurgical process by increasing the carbon content to 1.78 wt.% and adding 5.00 wt.% of titanium to test castings. After alloy solidification, the result was the formation of a microstructure consisting of a martensitic matrix with areas of residual austenite and primary titanium carbides evenly distributed in this matrix.
The measured as-cast hardness of the samples was 660HV and it increased to as much as 800HV after heat treatment.
The abrasion resistance of the sample hardened in a 15% polymer solution increased at least three times compared to the reference sample after quenching and tempering.
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Bibliography

[1] Głownia, J. (2002). Alloy steel castings-applications. Kraków: Fotobit. (in Polish).
[2] Dobrzański, L.A. (2006). Engineering materials and material design. Warszawa: WNT. (in Polish).
[3] Metals Handbook, (1990). 10-th Ed., vol. 1. ASM International.
[4] Głownia, J., Tęcza, G., Sobula, S., Kalandyk, B., Dzieja, A. (2007). Determination of the content and effect of residual austenite on the properties of cast L70H2GNM steel. Research done for Metalodlew S.A., unpublished. (in Polish).
[5] Głownia, J. (2017). Metallurgy and technology of steel castings. Sharjah: Bentham Science Publishers, cop.
[6] Mirzaee, M., Momeni, A., Keshmiri, H. & Razavinejad, R. (2014). Effect of titanium and niobium on modifying the microstructure of cast K100 tool steel. Metallurgical and Materials Transactions B. 45, 2304-2314. https://doi.org/10.1007/s11663-014-0150-8.
[7] Grabnar, K., Burja, J., Balaško, T., Nagode, A. & Medved, J. (2022). The influence of Nb, Ta and Ti modification on hot-work tool-steel grain growth during austenitization. Materiali in tehnologije. 56(3), 331-338. https://doi.org/10.17222/mit.2022.486.
[8] Srivastava, A.K. & Das, K. (2009). Microstructural and Mechanical Characterization of in Situ TiC and (Ti,W)C-Reinforced High Manganese Austenitic Steel Matrix Composites. Materials Science & Engineering A. 516, 1–6.
[9] Das, K., Bandyopadhyay, T.K. & Das, S. (2002). A review on the various synthesis routes of TiC reinforced ferrous based composites. Jurnal of Materials Science. 516(1-2), 1-6. https://doi.org/10.1016/j.msea.2009.04.041.
[10] Olejnik, E., Janas, A., Kolbus, A. & Sikora, G. (2011). The composition of reaction substrates for TiC carbides synthesis and its influence on the thickness of iron casting composite layer. Archives of Foundry Engineering. 11(spec.2), 165-168. ISSN (1897-3310).
[11] Olejnik, E., Tokarski, T., Sikora, G., Sobula, S., Maziarz, W., Szymański, Ł. & Grabowska, B. (2019). The effect of Fe addition on fragmentation phenomena, macrostructure, microstructure, and hardness of TiC-Fe local reinforcements fabricated in situ in steel casting. Metallurgical and Materials Transactions A. 50, 975-986. https://doi.org/10.1007/s11661-018-4992-6.
[12] Sobula, S., Olejnik, E. & Tokarski, T. (2017). Wear resistance of TiC reinforced cast steel matrix composite. Archives of foundry engineering. 17(1), 143-146. DOI: 10.1515/afe-2017-0026.
[13] Montealegre, M., Castro, G., Arias, J., Fernández-Vicente, A., Vázquez, J. (2008). Tool steel laser surface modification with TiC. In 3rd Pacific International Conference on Application of Lasers and Optics 2008, (pp. 890-894). Torneiros, Spain.
[14] Balanou, M., Karmiris-Obratański, P.P., Emmanouil-Lazaros., G.N., Markopoulos, A. (2021). Surface modification of tool steel by using EDM green powder metallurgy electrodes. In IOP Conference Series Materials Science and Engineering, 14-15 December 2021 (pp. 012014). Athens, Greece.
[15] Szymański, Ł., Olejnik, E., Tokarski, T., Kurtyka, P., Drożyński, D. & Żymankowska-Kumon, S. (2018). Reactive casting coatings for obtaining in situ composite layers based on Fe alloys. Surface and Coatings Technology. 350, 346-358. https://doi.org/10.1016/j.surfcoat.2018.06.085.
[16] Szymański, Ł., Olejnik, E., Sobczak, J.J., Szala, M., Kurtyka, P., Tokarski, T. & Janas, A. (2022). Dry sliding, slurry abrasion and cavitation erosion of composite layers reinforced by TiC fabricated in situ in cast steel and gray cast iron. Journal of Materials Processing Technology. 308, 117688. https://doi.org/10.1016/j.jmatprotec.2022.117688.
[17] Valdes, V.H., Guerra, F.V., Bedolla Jacuinde, A. & Pacheco-Cedeño, J. (2023). Development and characterization of a cast steel reinforced with primary carbides for high strength and severe wear applications. MRS Advances. 8, 1139-1143. DOI: 10.1557/s43580-023-00699-8.
[18] Tęcza, G. & Zapała, R. (2018). Changes in impact strength and abrasive wear resistance of cast high manganese steel due to the formation of primary titanium carbides. Archives of Foundry Engineering. 18(1), 119-122. DOI: 10.24425/118823.
[19] Tęcza, G. & Garbacz-Klempka A. (2016). Microstructure of cast high-manganese steel containing titanium. Archives of Foundry Engineering. 16(4), 163-168. ISSN (1897-3310).
[20] Tęcza, G. (2021). Changes in abrasive wear resistance during Miller test of Cr-Ni cast steel with Ti carbides formed in the alloy matrix. Archives of Foundry Engineering. 21(4), 110-115. DOI: 10.24425/afe.2021.139758.,
[21] Kalandyk, B. & Zapała, R. (2013). Effect of high-manganese cast steel strain hardening on the abrasion wear resistance in a mixture of SiC and water. Archives of Foundry Engineering. 13(4), 63-66. ISSN (1897-3310).
[22] Kasinska, J. & Kalandyk, B.(2017). Effects of rare earth metal addition on wear resistance of chromium-molybdenum cast steel. Archives of Foundry Engineering. 17(3), 63-68. DOI: 10.1515/afe-2017-0092.
[23] Sobula, S. & Kraiński, S. (2021). Effect of SiZr modification on the microstructure and properties of high manganese cast steel. Archives of Foundry Engineering. 21(4), 82-86. Doi: 10.24425/afe.2021.138683.
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Authors and Affiliations

Grzegorz Tęcza
1
ORCID: ORCID

  1. AGH University of Krakow, Poland
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Abstract

In the work was presented the results of studies concerns on the destructive mechanisms for forging tools used in the wheel forging process as well the laboratory results obtained on a specially constructed test items for testing abrasive wear and thermal fatigue. The research results of the forging tools shown that the dominant destructive mechanisms are thermal fatigue occurring in the initial the exploitation stage and abrasive wear, which occurs later, and is intensified effects of thermo-mechanical fatigue and oxidation process. In order to better analysis of phenomena associated with destructive mechanisms, the authors built a special test stands allow for a more complete analysis of each of the mechanisms separately under laboratory conditions, which correspond to the industrial forging processes. A comprehensive analysis of the forging tools confirmed by laboratory tests, showed the interaction between the thermal fatigue and abrasive wear, combined with the oxidation process. The obtained results showed that the process of oxidation and thermal fatigue, very often occur together with the mechanism of abrasive wear, creating a synergy effect. This causing the acceleration, the most visible and easily measurable process of abrasive wear.
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Authors and Affiliations

M. Hawryluk
M. Zwierzchowski
M. Marciniak
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Abstract

In this study T6 heat treated 6063 aluminum alloys were used as substrate material. In order to form a bond between the substrate and the

main coating, all samples were coated with Ni-Cr-Al powders. 8 wt% Yttria Stabilized Zirconia powders (YSZ) were coated with plasma

spray technique. Thickness of YSZ was 150 m and bond coating was 36 m. XRD and SEM-EDS analyses were performed to characterize

the coating layers. These YSZ coated and uncoated samples were subjected to wear testing under different spindle speed, loading and

working distance. Wear test results were compared with the kinetic friction coefficients and weight loss values. Wear marks on YSZ

coated and uncoated samples were investigated by SEM analysis. By coating with plasma spray technique, the wear resistance of Al alloys

was increased without changing the friction coefficient. It was found that spindle speed had significant effect over the wear properties than

the load applied. By YSZ coating, wear properties were increased 10 times.

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Authors and Affiliations

E. Erzi
D. Dispinar
S. Yilmaz
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Abstract

The presented work deals with the influence of the addition of soft graphite particles on the abrasive wear of composite reinforced with

hard SiC particles. The discussed hybrid composites were produced by stirring the liquid alloy and simultaneous adding the mixture of

particles. The adequately prepared suspension was gravity cast into a metal die. Both the composite castings obtained in this way and the

comparative castings produced of the pure matrix alloy were examined for the abrasive wear behaviour. Photomacrographs of the sliding

surfaces of the examined composites were taken, and also the hardness measurements were carried out. It was found that even a small

addition of Cgr particles influences positively the tribological properties of the examined composite materials, protecting the abraded

surface from the destructive action of silicon carbide particles. The work presents also the results of hardness measurements which confirm

that the composite material hardness increases with an increase in the volume fraction of hard reinforcing particles.

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Authors and Affiliations

Z. Konopka
M. Łągiewka
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Abstract

The results of the modification of austenitic matrix in cast high-manganese steel containing 11÷19% Mn with additions of Cr, Ni and Ti

were discussed. The introduction of carbide-forming alloying elements to this cast steel leads to the formation in matrix of stable complex

carbide phases, which effectively increase the abrasive wear resistance in a mixture of SiC and water. The starting material used in tests

was a cast Hadfield steel containing 11% Mn and 1.34% C. The results presented in the article show significant improvement in abrasive

wear resistance and hardness owing to the structure modification with additions of Cr and Ti.

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Authors and Affiliations

B. Kalandyk
R. Zapała
G. Tęcza
S. Sobula
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Abstract

In the paper the results and analysis of abrasive wear studies were shown for two grades of cast steels: low-alloyed cast steel applied for

heavy machinery parts such as housing, covers etc. and chromium cast steels applied for kinetic nodes of pin-sleeve type. Studies were

performed using the modified in Department of Foundry pin-on-disc method.

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Authors and Affiliations

A. Studnicki
M. Kondracki
J. Szajnar
T. Wróbel
J. Suchoń
D. Bartocha
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Abstract

Cast Hadfield steel is characterised by high abrasion resistance, provided, however, that it is exposed to the effect of dynamic loads.

During abrasion without loading, e.g. under the impact of loose sand jet, its wear resistance drops very drastically. To increase the abrasion

resistance of this alloy under the conditions where no pressure is acting, primary vanadium carbides are formed in the metallurgical

process, to obtain a composite structure after the melt solidification. The primary, very hard, carbides uniformly distributed in the

austenitic matrix are reported to double the wear resistance of samples subjected to the effect of a silicon carbide-water mixture.

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Authors and Affiliations

G. Tęcza
J. Głownia
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Abstract

The paper presents the results of abrasive wear resistance tests carried out on high-vanadium cast iron with spheroidal VC carbides. The cast iron of eutectic composition was subjected to spheroidising treatment using magnesium master alloy. The tribological properties were examined for the base cast iron (W), for the cast iron subjected to spheroidising treatment (S) and for the abrasion-resistant steel (SH). Studies have shown that high-vanadium cast iron with both eutectic carbides and spheroidal carbides has the abrasion resistance twice as high as the abrasion-resistant cast steel. The spheroidisation of VC carbides did not change the abrasion resistance compared to the base high-vanadium grade.

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Authors and Affiliations

M. Kawalec
E. Olejnik
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Abstract

A research of wear resistance of an austenitic cast iron with higher resistance to abrasive-wear and maintained corrosion resistance characteristic for Ni-Resist cast iron is presented. For the examination, structure of raw castings was first formed by proper selection of chemical composition (to make machining possible). Next, a heat treatment was applied (annealing at 550 °C for 4 hours followed by air cooling) in order to increase abrasive-wear resistance. One of the factors deciding intensity of wear appeared to be the chilling degree of castings. However, with respect to unfavourable influence of chilling on machining properties, an important factor increasing abrasivewear resistance is transformation of austenite to acicular ferrite as a result of annealing non-chilled castings. Heat treatment of non-chilled austenitic cast iron (EquNi > 16%) resulted in much higher abrasive-wear resistance in comparison to the alloy having pearlitic matrix at ambient temperature (EquNi 5.4÷6.8%).
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Authors and Affiliations

D. Medyński
A. Janus
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Abstract

The paper presents the results of tests on the spheroidising treatment of vanadium carbides VC done with magnesium master alloy and mischmetal. It has been proved that the introduction of magnesium master alloy to an Fe-C-V system of eutectic composition made 34% of carbides crystallise in the form of spheroids. Adding mischmetal to the base alloy melt caused 28% of the vanadium carbides crystallise as dendrites. In base alloy without the microstructure-modifying additives, vanadium carbides crystallised in the form of a branched fibrous eutectic skeleton. Testing of mechanical properties has proved that the spheroidising treatment of VC carbides in high-vanadium cast iron increases the tensile strength by about 60% and elongation 14 - 21 times, depending on the type of the spheroidising agent used. Tribological studies have shown that high-vanadium cast iron with eutectic, dendritic and spheroidal carbides has the abrasive wear resistance more than twice as high as the abrasion-resistant cast steel.

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Authors and Affiliations

M. Górny
M. Kawalec
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Abstract

An influence of a decreased Cr content on the microstructure of the highly alloyed Cr-Ni cast steel, duplex type, melted under laboratory conditions, was characterized in the paper. The microstructure investigations were performed in the initial state and after the heat treatment (solution annealing) at 1060°C as well as the phase transformation kinetics at continuous cooling was measured. The wear resistance of the investigated cast steel was tested and compared with the 24%Cr-5%Ni-2.5%Mo cast steel. The Cr content decrease, in ferritic-austenitic cast steels (duplex), from 24-26%Cr to 18% leads to the changes of the castings microstructure and eliminating of a brittle σ phase. In dependence of the casting cooling rate, apart from ferrite and austenite, also fine martensite precipitates occur in the casting structure. It was shown that the investigated cast steel is characterised by a slightly lower wear resistance than the typical cast steel duplex grades.
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Authors and Affiliations

B. Kalandyk
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Abstract

The paper presents an innovative method of creating the layered castings. The innovation relies on application the 3D printing insert obtaining in SLM (selective laser melting) method. This type of scaffold insert made from pure Ti powder, was placed into mould cavity directly before pouring by grey cast iron. In result of used method was obtained grey cast iron casting with surface layer reinforced by titanium carbides. In range of studies were carried out metallographic researches using light microscope and scanning electron microscope, microhardness measurements and abrasive wear resistance. On the basis of obtaining results was stated that there is a possibility of reinforcing surface layer of the grey cast iron casting by using 3D printing scaffold insert in the method of mould cavity preparation. Moreover there was a local increase in hardness and abrasive wear resistance in spite of the precipitation of titanium carbides in surface layer of grey cast iron. While the usable properties of composite surface layer obtained in result of use of the method presented in the paper, strongly depend of dimensions of scaffold insert, mainly parameters Re and Ri.

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Authors and Affiliations

A. Dulska
J. Szajnar
N. Przyszlak
T. Wróbel
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Abstract

The paper concerns evaluation of the coefficient of friction characterising a friction couple comprising a commercial brake disc cast of

flake graphite grey iron and a typical brake pad for passenger motor car. For the applied interaction conditions, the brake pressure of

0.53 MPa and the linear velocity measured on the pad-disc trace axis equalling 15 km/h, evolution of the friction coefficient μ values were

observed. It turned out that after a period of 50 minutes, temperature reached the value 270°C and got stabilised. After this time interval,

the friction coefficient value also got stabilised on the level of μ = 0.38. In case of a block in its original state, stabilisation of the friction

coefficient value occurred after a stage in the course of which a continuous growth of its value was observed up to the level μ = 0.41 and

then a decrease to the value μ = 0.38. It can be assumed that occurrence of this stage was an effect of an initial running-in of the friction

couple. In consecutive abrasion tests on the same friction couple, the friction coefficient value stabilisation occurred after the stage of

a steady increase of its value. It can be stated that the stage corresponded to a secondary running-in of the friction couple. The observed

stages lasted for similar periods of time and ended with reaching the stabile level of temperature of the disc-pad contact surface.

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Authors and Affiliations

M. Mróz
A.W. Orłowicz
G. Wnuk
O. Markowska
W. Homik
B. Kolbusz
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Abstract

Within the presented work, the effect of austenite transformation on abrasive wear as well as on rate and nature of corrosive destruction

of spheroidal Ni-Mn-Cu cast iron was determined. Cast iron contained: 3.1÷3.4 %C, 2.1÷2.3 %Si, 2.3÷3.3 %Mn, 2.3÷2.5 %Cu and

4.8÷9.3 %Ni. At a higher degree of austenite transformation in the alloys with nickel equivalent below 16.0%, abrasive wear resistance

was significantly higher. Examinations of the corrosion resistance were carried out with the use of gravimetric and potentiodynamic

method. It was shown that higher degree of austenite transformation results in significantly higher abrasive wear resistance and slightly

higher corrosion rate, as determined by the gravimetric method. However, results of potentiodynamic examinations showed creation

of a smaller number of deep pinholes, which is a favourable phenomenon from the viewpoint of corrosion resistance.

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Authors and Affiliations

A. Janus
D. Medyński
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Abstract

The resistance of cast iron to abrasive wear depends on the metal abrasive hardness ratio. For example, hardness of the structural

constituents of the cast iron metal matrix is lower than the hardness of ordinary silica sand. Also cementite, the basic component of

unalloyed white cast iron, has hardness lower than the hardness of silica. Some resistance to the abrasive effect of the aforementioned

silica sand can provide the chromium white cast iron containing in its structure a large amount of (Cr, Fe)7C3 carbides characterised by

hardness higher than the hardness of the silica sand in question. In the present study, it has been anticipated that the white cast iron

structure will be changed by changing the type of metal matrix and the type of carbides present in this matrix, which will greatly expand

the application area of castings under the harsh operating conditions of abrasive wear. Moreover, the study compares the results of

abrasive wear resistance tests performed on the examined types of cast iron. Tests of abrasive wear resistance were carried out on a Miller

machine. Samples of standard dimensions were exposed to abrasion in a double to-and-fro movement, sliding against the bottom of

a trough filled with an aqueous abrasive mixture containing SiC + distilled water. The obtained results of changes in the sample weight

were approximated with a power curve and shown further in the study.

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Authors and Affiliations

D. Kopyciński
M. Kawalec
S. Piasny
A. Madizhanova

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