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Abstract

Results of toluene and p-xylene containing model gases biofiltration are presented. Process was carried out on columns packed with two kinds of non-modified composts. Velocity and efficiency of biofiltration was determined and plotted vs. impurities concentration and linear gas velocity. Highest, average for the top section of the column, values of the decomposition velocity were found to be ca. 80 g/m3 /h, and average for the whole column ca. 40 g/m3/h respectively. Fluctuations of these values at similar, well controlled, measurement parameters were however encounter, most probable due to varying hardly adjustable humidity of the column bed.
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Authors and Affiliations

Andrzej Wieczorek
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Abstract

Results of study on biofiltration of waste gases arising during lacquer covering of coil wires are presented. Gases contained over 50 compounds, phenol, cresols, in between. Biofiltration was carried out on compost bed at 0.28 emfs average linear velocity of gases. Efficiency of the whole process reached over 99%. Significant decrease of concentration of several compounds already in humidifier has been encountered.
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Authors and Affiliations

Andrzej Wieczorek
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Abstract

Due to the lower energy consumption and waste production compared to traditional methods, the environmental bioremediation methods based on natural processes have been gradually becoming more prevalent in environmental engineering. Biological methods are used in waste management, wastewater treatment, gas treatment or soil remediation. For the low solubility of some pollutants and lower bioavailability, the use of biological methods may be hampered. This problem might be mitigated with the use of surfactants. This paper presents the results of studies regarding the eff ect of dosing a selected surfactant from the Tween group (Tween 20) on the efficiency of toluene elimination from the air by biofi ltration. The obtained maximum biofi ltration rate was 21.2 g/m3/h and 19.8 g/m3/h for the control bed and for the bed to which the Tween 20 solution was dosed, respectively. The eff ect of Tween was neutral (the effectiveness of toluene removal was insignificantly comparable to the effectiveness of the control series), it did not affect the effectiveness or limited the development of the biofilter microflora.

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Authors and Affiliations

Urszula Miller
1
Izabela Sówka
1
ORCID: ORCID
Waldemar Adamiak
1

  1. Faculty of Environmental Engineering, Wroclaw University of Science and Technology, Poland
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Abstract

This paper presents investigations on the removal of cyclohexane and ethanol from air in polyurethane- -packed biotrickling filters, inoculated with Candida albicans and Candida subhashii fungal species. Results on process performance together with flow cytometry analyses of the biofilm formed over packing elements are presented and discussed. The results indicate that the presence of ethanol enhances the removal efficiency of cyclohexane from air. This synergistic effect may be attributed to both co-metabolism of cyclohexane with ethanol as well as increased sorption efficiency of cyclohexane to mineral salt medium in the presence of ethanol. Maximum elimination capacities of 89 g m-3 h-1 and 36.7 g m-3 h-1 were noted for cyclohexane and ethanol, respectively, when a mixture of these compounds was treated in a biofilter inoculated with C. subhashii. Results of flow cytometry analyses after 100 days of biofiltration revealed that about 91% and 88% of cells in biofilm remained actively dividing, respectively for C. albicans and C. subhashii species, indicating their good condition and ability to utilize cyclohexane and ethanol as a carbon source.
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Bibliography

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  2. Cheng, Y., He, H., Yang, C., Zeng, G., Li, X., Chen, H. & Yu, G. (2016). Challenges and solutions for biofiltration of hydrophobic volatile organic compounds, Biotechnology Advances, 34, 1091–1102, https://doi.org/10.1016/j.biotechadv.2016.06.007
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  10. Miller, U., Sówka, I. & Adamiak, W. (2020). The use of surfactant from the Tween group in toluene biofi ltration, Archives of Environmental Protection, Vol. 46 no. 2 pp. 53–57, DOI: 10.24425/aep.2020.133474.
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  16. Rybarczyk, P., Szulczyński, B., Gospodarek, M. & Gębicki, J. (2019b). Effects of n-butanol presence, inlet loading, empty bed residence time and starvation periods on the performance of a biotrickling filter removing cyclohexane vapors from air, Chemical Papers 74, pp. 1039–1047,https://doi.org/10.1007/s11696-019-00943-2.
  17. Salamanca, D., Dobslaw, D. & Engesser, K.-H. (2017). Removal of cyclohexane gaseous emissions using a biotrickling filter system, Chemosphere 176, pp. 97–107, https://doi.org/10.1016/j.chemosphere.2017.02.078.
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  20. Yang, C., Chen, H., Zeng, G., Yu, G. & Luo, S. (2010). Biomass accumulation and control strategies in gas biofiltration, Biotechnology Advances 28, 4, pp. 531–540, https://doi.org/10.1016/j.biotechadv.2010.04.002.
  21. Yang, C., Qian, H., Li, X., Cheng, Y., He, H., Zeng, G. & Xi, J. (2018). Simultaneous Removal of Multicomponent VOCs in Biofilters, Trends in Biotechnology 36, 7, pp. 673–685, https://doi.org/10.1016/j.tibtech.2018.02.004.
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  24. Zhanga, Y., Denga, W., Qina, Y., Yanga, Z., Liua, J. & Lia, J. (2018) Research on Simultaneous Removal of Cyclohexane and Methyl Acetate in Biotrickling Filters, Proceedings of the 2nd International Conference of Recent Trends in Environmental Science and Engineering, Niagara Falls, Canada, https://doi.org/10.11159/rtese18.107.
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Authors and Affiliations

Piotr Rybarczyk
1
ORCID: ORCID
Milena Marycz
1
Bartosz Szulczyński
1
ORCID: ORCID
Anna Brillowska-Dąbrowska
2
Agnieszka Rybarczyk
3
Jacek Gębicki
1
ORCID: ORCID

  1. Department of Process Engineering and Chemical Technology, Faculty of Chemistry, Gdańsk University of Technology
  2. Department of Molecular Biotechnology and Microbiology, Faculty of Chemistry, Gdańsk University of Technology
  3. Department of Histology, Faculty of Medicine, Medical University of Gdańsk
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Abstract

This article presents the validity, advisability and purposefulness of using a gas sensor matrix to monitor air deodorization processes carried out in a peat-perlite-polyurethane foam-packed biotrickling filter. The aim of the conducted research was to control the effectiveness of air stream purification from vapors of hydrophobic compounds, i.e., n-hexane and cyclohexane. The effectiveness of hydrophobic n-hexane and cyclohexane removal from air was evaluated using gas chromatography as the reference method and a custom-built gas sensor matrix consisting of seven commercially available sensors. The influence of inlet loading (IL) of n-hexane and cyclohexane on the biotrickling filtration performance was investigated. The prepared sensor matrix was calibrated with use of two statistical techniques: Multiple Linear Regression (MLR) and Principal Component Regression (PCR). The developed mathematical models allowed us to correlate the multidimensional signal from the sensor array with the concentration of the removed substances. The results based on gas chromatography analyses indicated that the elimination efficiencies of n-hexane and cyclohexane reached about 40 and 30 g m-3 h-1, respectively. The results obtained using a gas sensor matrix revealed that it was possible not only to determine concentration reliably of investigated hydrophobic volatile organic compounds in the gas samples, but also to obtain results of a similar high level of quality as the chromatographic ones. A gas-sensor matrix proposed in this work can be used for on-line real-time monitoring of biofiltration process performance of air polluted with n-hexane and cyclohexane.
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Bibliography

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  45. Chen, Y., Wang, X., He, S., Zhu, S. & Shen, S. (2016). The performance of a two-layer biotrickling filter filled with new mixed packing materials for the removal of H_2 S from air. Journal of Environmental Management, 165, 1, pp. 11-16. DOI:10.1016/j.jenvman.2015.09.008
  46. Cheng, Y., He, H., Yang, C., Yan, Z., Zeng, G. & Qian, H. (2016a). Effects of anionic surfactant on n-hexane removal in biofilters. Chemosphere, 150, pp. 248-253. DOI:10.1016/j.chemosphere.2016.02.027
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Authors and Affiliations

Dominik Dobrzyniewski
1
ORCID: ORCID
Bartosz Szulczyński
1
ORCID: ORCID
Piotr Rybarczyk
1
ORCID: ORCID
Jacek Gębicki
1
ORCID: ORCID

  1. Department of Process Engineering and Chemical Technology, Faculty of Chemistry, Gdańsk University of Technology, Gdańsk, Poland

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