Among the elements that compose steel slags and blast furnace slags, metallic precipitates occur alongside the dominant glass and crystalline phases. Their main component is metallic iron, the content of which varies from about 90% to 99% in steel slags, while in blast furnace slags the presence of precipitates was identified with the proportion of metallic iron amounting to 100%. During observations using scanning electron microscopy and X-ray spectral microanalysis it has been found that the form of occurrence of metallic precipitates is varied. There were fine drops of metal among them, surrounded by glass, larger, single precipitates in a regular, spherical shape, and metallic aggregates filling the open spaces between the crystalline phases. Tests carried out for: slags resulting from the open-hearth process, slags that are a by-product of smelting in electric arc furnaces, blast furnace slags and waste resulting from the production of ductile cast iron showed that depending on the type of slag, the proportion and form of metallic precipitates is variable and the amount of Fe in the precipitates is also varied. Research shows that in terms of quality, steel and blast furnace slag can be a potential source of iron recovery. However, further quantitative analyses are required regarding the percentage of precipitates in the composition of slags in order to determine the viability of iron recovery. This paper is the first part of a series of publications aimed at understanding the functional properties of steel and blast furnace slags in the aspect of their destructive impact on the components of devices involved in the process of their processing, which is a significant operational problem.
The results presented in this article are part of the research on fatigue life of various foundry alloys carried out in recent years in the Lukasiewicz Research Network – Institute of Precision Mechanics and AGH University of Science and Technology, Faculty of Foundry Engineering. The article discusses the test results obtained for the EN-GJS-600-3 cast iron in an original modified low-cycle fatigue test (MLCF), which seems to be a beneficial research tool allowing its users to evaluate the mechanical properties of materials with microstructural heterogeneities under both static and dynamic loads. For a comprehensive analysis of the mechanical behaviour with a focus on fatigue life of alloys, an original modified low cycle fatigue method (MLCF) adapted to the actually available test machine was used. The results of metallographic examinations carried out by light microscopy were also presented. From the analysis of the results of the conducted mechanical tests and structural examinations it follows that the MLCF method is fully applicable in a quick and economically justified assessment of the quality of ductile iron after normalizing treatment.
An analysis has been carried out of the influence of annealing time at the preheating temperature of 650 °C on the change in hardness and alloy structure of lamellar graphite cast iron in the working as well as in the laboratory conditions. This preheat temperature is common during reclaiming welding of castings with complex shapes. The changes in unalloyed cast iron EN-GJL 200 to EN-GJL 300 according to ISO 1690 standard and cast iron with low amount of elements such as Sn, Cu, Cr, and Mo and their combinations were assessed. It was found that the cast iron of higher strength grades has better hardness and structural stability. Cast iron alloyed with chromium or its combinations has the highest stability. In unalloyed cast iron, a partial degradation of pearlite occurs; in alloyed cast iron the structural changes are not conclusive.
The paper presents the initial results of investigation concerning the abrasion resistance of cast iron with nodular, vermicular, or flake graphite. The nodular and vermicular cast iron specimens were cut out of test coupons of the IIb type with the wall thickness equal to 25 mm, while the specimens made of grey cast iron containing flake graphite were cut out either of special casts with 20 mm thick walls or of the original brake disk. The abrasion tests were carried out by means of the T-01M tribological unit working in the pin-on-disk configuration. The counterface specimens (i.e. the disks) were made of the JT6500 brand name friction material. Each specimen was abraded over a distance of 4000 m. The mass losses, both of the specimens and of the counterface disks, were determined by weighting. It was found that the least wear among the examined materials was exhibited by the nodular cast iron. In turn, the smallest abrasion resistance was found in vermicular cast iron and in cast iron containing flake graphite coming from the brake disk. However, while the three types of specimens (those taken from the nodular cast iron and from grey cast iron coming either from the special casts or from the brake disk) have almost purely pearlitic matrix (P95/Fe05), the vermicular cast iron matrix was composed of pearlite and ferrite occurring in the amounts of about 50% each (P50/Fe50). Additionally, it was found that the highest temperature at the cast iron/counterface disk contact point was reached during the tests held for the nodular cast iron, while the lowest one occurred for the case of specially cast grey iron.
Acid mine drainage (AMD) is widespread environmental problem associated with both working and abandoned mining operation, resulting from the microbial oxidation of pyrite in presence of water and air, to form an acidic solution containing metal ions. The present study aims to adjust low pH, remove iron, manganese and sulphate from AMD generated at open pit Jiří and depth Jiří, Sokolovská uhelná, Czech Republic. The local AMD is very problematic due to its composition and process taking place in the Water Preparing Plant Svatava (WPPS), where only pH value is adjusted and mainly high concentration of iron and suspended solids are removed.
The influence of the hold time of the austempering heat treatment at 280°C on the microstructure and corrosion resistance in NaCl-based media of austempered ductile iron was investigated using X-ray diffraction, micro-hardness measurements, corrosion tests and surface observations. Martensite was only found in the sample which was heat treated for a short period (10 minutes). Corrosion tests revealed that this phase does not play any role in the anodic processes. Numerous small pits were observed in the α-phase which is the precursor sites in all samples (whatever the value of the hold time of the austempering heat treatment).
In the present work, different Cu-alloyed model ductile irons with ferritic (0%Cu-0.09%Mn), mixed ferritic-pearlitic (0.38%Cu-0.40%Mn) and pearlitic (0.69%Cu-0.63%Mn) microstructure were produced and analyzed in terms of their electrochemical corrosion behavior in a 3.5wt.%NaCl aqueous solution containing naturally dissolved oxygen at room temperature (25°C). The remaining elements such as Si and Mg were kept at balanced levels in an attempt to minimize variations in graphite size and distribution among different samples. The corrosion resistance was evaluated by electrochemical impedance spectroscopy and potentiodynamic polarization. Microstructure analysis of the cast alloys confirmed similarity in the graphite morphology among the different cast samples and the expected variations in the metallic matrix. In the absence of passivation, it was found that the addition of copper led to an increase in corrosion resistance, which could be attested by higher values polarization resistance and corrosion potential.
The objective of the study reported in this paper was to determine the effect of structure on thermal power of cast-iron heat exchangers which in this case were furnace chambers constituting the main component of household fireplace-based heating systems and known commonly as fireplace inserts. For the purpose of relevant tests, plate-shaped castings were prepared of gray iron with flake graphite in pearlitic matrix (the material used to date typically for fireplace inserts) as well as similar castings of gray cast iron with vermicular graphite in pearlitic, ferritic-pearlitic, and ferritic matrix. For all the cast iron variants of different structures (graphite precipitate shapes and matrix type), calorimetric measurements were carried out consisting in determining the heat power which is quantity representing the rate of heat transfer to the ambient environment. It has been found that the value of the observed heat power was affected by both the shape of graphite precipitates and the type of alloy matrix. Higher thermal power values characterize plate castings of gray iron with vermicular graphite compared to plates cast of the flake graphite gray iron. In case of plates made of gray cast iron with vermicular graphite, the highest values of thermal power were observed for castings made of iron with ferritic matrix.
This paper presents a new stand for studying the linear shrinkage kinetics of foundry alloys. The stand is equipped with a laser displacement sensor. Thanks to this arrangement, the measurement is of a contactless nature. This solution allows for the elimination of errors which occur in measurements made using intermediary elements (steel rods). The supposition of the expansion (shrinkage) of the sample and the expansion of the heated rod lead to the distortion of the image of the actual dimensional changes of the studied sample. A series of studies of foundry alloys conducted using the new stand allowed a new image of shrinkage kinetics to be obtained, in particular regarding cast iron. The authors introduce in the study methodology a real-time measurement of two linked quantities; shrinkage (the displacement of the free end of the sample) and temperature in the surface layer of the sample casting. This generates not only a classic image of shrinkage (S) understood as S = f (t), but also the view S = f (T). The latter correlation, developed based on results obtained using the contactless method, provide a new, so far poorly known image of the course of shrinkage in foundry alloys, especially cast iron with graphite in the structure. The study made use of hypo- and hypereutectic cast iron in order to generate an image of the differences which occur in the kinetics of shrinkage (as well as in pre-shrinkage expansion - expansion occurs during solidification).