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Abstract

The effect of cobalt aluminate inoculant addition and melt-pouring temperature on the structure and mechanical properties of Ni-based superalloy was studied. The first major move to control the quality of investment cast blades and vanes was the control of grain size. Cobalt aluminate (CoAl2O4) is the most frequently utilized inoculant in the lost-wax casting process of Ni-based superalloys. The inoculant in the prime coat of moulds and pouring temperature play a significant role in grain size control. The finest surface grains were obtained when the internal surface of shell mould was coated with cobalt aluminate and subsequently pouring was at 1480°C. The influence of selected casting parameters and inoculant addition on mechanical properties was investigated on the basis of tensile, creep and hardness testing. The effect of grain refinement on mechanical properties were consistent with established theories. Tests conducted at ambient temperature indicated a beneficial effect of grain refinement both on tensile strength and hardness. In contrast at elevated temperature during creep, the reverse trend was observed.

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Authors and Affiliations

Ł. Rakoczy
M. Grudzień
R. Cygan
A. Zielińska-Lipiec
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Abstract

The paper presents a microscopic analysis of the surface and fracture of aluminium castings produced using the lost-wax method for patterns made of a composite material, i.e. polyethylene with the addition of bentonite. Castings are made of AlSi7 aluminium alloy (silumin) in a plaster mould. A new type of polymer waxes enriched with bentonite was used to obtain new composites, minimizing the defects caused by the casting production process. The castings were made in the centrifugal casting process. The prepared plaster moulds were removed from the furnace and poured with liquid aluminium alloy (AlSi7) at 750°C. The surface and fracture of the castings was analysed using an optical digital microscope type VHX-7000 manufactured by KEYENCE. It has been proven that the studied castings feature surface defects (raw surface defects) in the form of high roughness and the presence of bentonite inclusions classified as casting contamination. During the tests, shape defects related to mechanical damage were also detected.
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Bibliography

[1] Kozakowski, S. (2001). Study of castings. Warsaw: Biuro Gamma. (in Polish)
[2] Sozański, L. (2004). Visual examination of castings surface discontinuities according to European standards. Archives of Foundry. 4(11). 196-199. (in Polish)
[3] Sozański, L. (2006). Possibilities of assessment of surface discontinuities of castings. Archiwum Odlewnictwa. 6(2), 331-336. (in Polish)
[4] PN EN 1559-1 Founding – Technical delivery conditions – General provisions. (in Polish)
[5] PN EN 1371-2 Founding. Penetrant testing. Part 2: Castings made using the lost-wax method. (in Polish)
[6] PN EN 1370 Founding – Surface roughness testing using visual-tactile standards. (in Polish)
[7] Kuchariková, L., Tillová, E., Samardžiová, M. et al., (2019). Quality assessment of Al castings produced in sand molds using image and CT analyses. Journal of Materials Engineering and Performance. 28, 3966-3973. https://doi.org/10.1007/s11665-019-04040-z.
[8] Sika, R., Rogalewicz, M., Popielarski, P., Czarnecka-Komorowska, D., Przestacki, D., Gawdzińska, K. & Szymański, P. (2020). Decision support system in the field of defects assessment in the metal matrix composites castings. Materials. 13(16), 3552. https://doi.org/10.3390/ma13163552
[9] Tupaj, M., Orłowicz, A.W., Mróz, M., Trytek,. A., & Markowska, O. (2016). The effect of cooling rate on properties of intermetallic phase in a complex Al-Si alloy. Archives of Foundry Engineering. 16(3), 125-128. DOI: 10.1515/afe-2016-0063
[10] Gawdzińska, K., Chybowski, L., Bejger J.A. & Krile, S. (2016). Determination of technological parameters of saturated composites based on SiC by means of a model liquid. Metalurgija. 55(4) 659-662. https://hrcak.srce.hr/157391
[11] Aziz, M.N., Munyensanga, P. & Widyanto, S.A. (2018). Application of lost wax casting for manufacturing of orthopedic screw: A review. Procedia CIRP. 78, 149-154.
[12] Zych, J., Kolczyk, J., & Snopkiewicz, T. (2012). Investigations of properties of wax mixtures used in the investment casting technology, New investigation methods. Archives of Foundry Engineering. 12(spec.1), 199-204. ISSN (1897-3310)
[13] Wen, J., Xie, Z., Cao, W. & Yang, X. (2016). Effects of different backbone binders on the characteristics of zirconia parts using wax-based binder system via ceramic injection molding. Journal of Advanced Ceramics. 5(4), 321-328. https://doi.org/10.1007/s40145-016-0205-1
[14] Czarnecka-Komorowska, D., Grześkowiak, K., Popielarski, P., Barczewski, M., Gawdzińska, K. & Popławski, M. (2020). Polyethylene wax modified by organoclay bentonite used in the lost-wax casting process: processing−structure−property relationships. Materials. 13(2255), 1-22. https://doi.org/10.3390/ma13102255.
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[16] Olszówka-Myalska, A., Godzierz, M., Myalski, J. & Wrześniowski, P. (2019). Magnesium matrix composites with open-celled glassy carbon foam obtained using the infiltration method. Metals. 9(622), 1-14. DOI: 10.3390/met9060622
[17] Grzeskowiak, K., Czarnecka-Komorowska, D., Sytek K. & Wojciechowski, M. (2015). Influence of waxes remelting used in investment casting on their thermal properties and linear shrinkage. Metalurgija. 54(2), 350-352. https://hrcak.srce.hr/128959
[18] Trytek, A., Orłowicz, A.W., Tupaj, M., Mróz, M., Markowska, O., Bąk, G. & Abram, T. (2016). The effect of a thin459 wall casting mould cavity filling conditions on the casting surface quality. Archives of Foundry Engineering. 16(4), 222-226. DOI: 10.1515/afe-2016-0113
[19] Dolata, A.J., Dyzia, M., Putyra, P. & Jaworska, L. (2016). Cast hybrid composites designated for air compressor 549 pistons. Archives of Metallurgy and Materials. 61(2), 705-708. DOI: 10.1515/amm-2016-0120
[20] Staude, M. (2021). Porosity assessment of suspension and saturated composite castings with the use of microscopic examinations. Scientific Journals of the Maritime University of Szczecin. 67(139), 53-57.
[21] Skołek, E., Giętka, T., Świątnicki, W. & Myszka, D. (2017). The comparative study of the microstructure and phase composition of nanoausferritic ductile iron alloy using SEM, TEM, magnetometer, and X-ray diffraction methods. Acta Physica Polonica A. 5(131), 1319-1323, DOI: 10.12693/APhysPolA.131.1319
[22] Polish Standard PN-85/H-83105. Castings. Division and terminology of defects. (in Polish)

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Authors and Affiliations

D. Czarnecka-Komorowska
1
ORCID: ORCID
K. Gawdzińska
2
ORCID: ORCID
P. Popielarski
1
ORCID: ORCID

  1. Poznań University of Technology, Poland
  2. Maritime University of Szczecin, Poland
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Abstract

The casting workshop was discovered with numerous artifacts, confirming the existence of the manufacturing process of metal ornaments using ceramic molds and investment casting technology in Lower Silesia (Poland) in 7-6 BC. The research has yielded significant technological information about the bronze casting field, especially the alloys that were used and the artifacts that were made from them. Based on the analyses, the model alloys were experimentally reconstructed. Taking advantage of the computer-modeling method, a geometric visualization of the bronze bracelets was performed; subsequently, we simulated pouring liquid metal in the ceramic molds and observed the alloy solidification. These steps made it possible to better understand the casting processes from the perspective of the mold technology as well as the melting and casting of alloys.

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Authors and Affiliations

A. Garbacz-Klempka
J.S. Suchy
Z. Kwak
P. Długosz
T. Stolarczyk
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Abstract

In lost wax technology, self-supporting ceramic moulds are made, which must have adequate strength after being filled with liquid metal. The final structural strength is determined by such factors as the thickness of the individual layers applied to the wax model resulting from the viscosity of the liquid mass, the specific strength of the layers formed, and the heat treatment of the moulds. The development of technology and materials is moving in the direction of increasing the specific strength of self-supporting ceramic moulds. The consequence of this is that the final strength of these moulds is too high, making it difficult to knock castings out of the moulds. Removing mould remnants from holes, closed spaces of the casting, corners, sharp edges, variable cross sections and etc. is cumbersome. In order to remove mould remnants from the casting, a method is used to dissolve them in heated solutions of suitable chemical composition and reaction. The paper presents the results of research on a new solution, the essence of which is the production of layers in a ceramic mould, in the middle zone of the mould, characterized by a significantly reduced final strength, achieved after firing. These layers are produced using a different liquid ceramic mass than the base one, based on an organic binder. As a result, thanks to the embedded layer, very good knock-out of castings is achieved and separation of residual ceramic mass. Special layers can be incorporated over the entire surface or only in those places where the bonding of the casting surface and ceramic mass occurs.
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Bibliography

[1] Małek, M. Wiśniewski, P., Matysiak, H., Ziwlinska, M. & Kurzydkowski, K. J. (2013). Yttrium (III) oxide application for manufacturing prime coat of ceramic shell moulds used in investment casting. Glass Ceram. 6, 8-11. DOI: 10.13140/RG.2.1.1594.6002.
[2] Matysiak, H., Ferenc, J., Lipiński, Z., Grabarz, K., Michalski J., & Kurzydłowski, K.J. (2009). Characterization and monitoring of technological parameters of ceramic slurries used in the investment casting process of aircraft turbine elements using the Bridgman technique. Inżynieria Materiałowa. 30(4), 239-244.
[3] Wei-hua Liu, Xin Jia, Lai Song, & Ying-min Li. (2023). Effects of binder components and PVA modifier on bonding performance of phosphate binder for sand core-making. China Foundry. 20, 134-138. https://doi.org/10.1007/s41230-023-1021-1
[4] Pattnaik, S.R. (2017). An investigation on enhancing ceramic shell properties using naturally available additives. The International Jouranl of Advanced Manufacturing Technology. 91, 3061-3078. https://doi.org/10.1007/s00170-016-9975-4.
[5] Soroczyński, A., Haratym, R. & Biernacki, R. (2019). The role of recycled ceramic material obtained from the ceramic layered moulds used in the Investment Casting. Archives of Foundry Engineering. 19(1), 71-74. DOI: 10.24425/afe.2018.125194.
[6] Karwiński, A. (2014). Technological parameters of the process of making molds of ceramic with the participation of water silicate binder. In Swiatkowski. K. (Eds.)., Polish Metallurgy in 2011-2014, (pp. 529–541), AKAPIT, Cracow. (in Polish).
[7] Karwiński, A. & Żółkiewicz, Z. (2014). The research of properties of experimental ceramic layers. Archives of Metallurgy and Materials. 59(2), 703-705. DOI:https://doi.org/10.2478/amm-2014-0115.
[8] Lu K, Liu X, Duan Z (2019). Effect of firing temperature and time on hybrid fiber-reinforced Shell for investment casting. International Journal of MetalCasting. 13, 666-673. https://doi.org/10.1007/s40962-018-0280-x.
[9] Kolczyk, J., Zych, J. & Jamrozowicz, Ł. (2017). Influence of the Al2O3 solid phase on the kinetics of binding ceramic moulds. Archives of Foundry Engineering. 17(4), 91-96. DOI: 10.1515/afe-2017-0136.
[10] Kolczyk, J., Zych, J. (2013). Kinetics of hardening and drying of ceramic moulds with the new generation binder – colloidal silica. Archives of Foundry Engineering. 13(4), 112-116. DOI: 10.2478/afe-2013-0093.
[11] Tabor, A., Rączka, J.S. (1998). Casting design and mold technology. Kraków: Fotobit. (in Polish).
[12] Skarbiński, M. (1957). Casting construction. Warszawa: Państwowe Wydawnictwo Techniczne. (in Polish).
[13] Pająk, J., Ziemski, M. & Nowak, B. (2010). Poly(vinyl alcohol) – biodegradable vinyl material. CHEMIK. 64(7-8), 523-530. (in Polish).
[14] Rohini, Kumar, D.B., Rami, Reddy, M., Mulay, V.N., & Krishnamurti, N. (2000). Acrylic co-polymer emulsion binders for green machining of ceramics. European Polymer Journal. 36(7), 1503-1510. DOI:10.1016/S0014-3057(99)00199-8.

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Authors and Affiliations

Joanna Kolczyk-Tylka
1
ORCID: ORCID
Jerzy Zych
1
ORCID: ORCID

  1. AGH University of Science and Technology, Faculty of Foundry Engineering, Krakow, Poland
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Abstract

The results of testing the strength properties of experimental ceramic materials containing spending moulding sand after initial mechanical reclamation as a material for subsequent layers of the stucco composition were presented. Tests were carried out on spent moulding sands from various foundry technologies, i.e. sand with furfuryl resin and sand with hydrated sodium silicate. The spent, agglomerated moulding sand has undergone a crushing process. Next, the required granular fractions used for individual layers of the stucco material were separated. Ceramic samples, in which the spent moulding sand was a substitute for fresh silica sand in successive layers of the stucco composition, were prepared. As a reference material, identical ceramic samples were used but with all layers made from the fresh silica sand. Samples prepared in this way were used to determine the bending strength of ceramic materials in the temperature range from 20 to 900ºC. The obtained values of the bending strength have demonstrated that spent moulding sand can be used in investment casting with no adverse effect on the strength of ceramic materials.

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Authors and Affiliations

M. Angrecki
ORCID: ORCID
J. Kamińska
ORCID: ORCID
J. Jakubski
ORCID: ORCID
P. Wieliczko
ORCID: ORCID
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Abstract

Investment casting technology that utilizes lost-wax casting is one of the most-important achievements of ancient society. In Lower Silesia, Poland (Grzybiany, Legnica county), a 7-6 BC casting workshop was discovered with numerous artifacts, confirming the existence of the manufacturing process of metal ornaments using ceramic molds. The paper presents the research of molds and casts from the Bronze and Early Iron Ages. Microscopic analyses of the casting molds were performed, along with radiographic and chemical composition tests of the artifacts (the latter employing the use of the X-ray fluorescence spectroscopy method). The clustering method was used for alloy classification. The microstructure was analyzed by means of Scanning Electron Microscopy with Energy Dispersive Spectroscopy. Conclusions from the research were utilized in further experiments
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Authors and Affiliations

A. Garbacz-Klempka
J.S. Suchy
Z. Kwak
T. Tokarski
R. Klempka
T. Stolarczyk

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