Ambient concentrations of CO, as well as NOx and O3, were measured as a part of the PARADE campaign conducted at the Taunus Observatory on the summit of the Kleiner Feldberg between the 8th of August and 9th of September 2011. These measurements were made in an effort to provide insight into the characteristics of the effects of both biogenic and anthropogenic emissions on atmospheric chemistry in the rural south-western German environment. The overall average CO concentration was found to be 100.3±18.1 ppbv (within the range of 71 to 180 ppbv), determined from 10-min averages during the summer season. The background CO concentration was estimated to be ~90 ppbv. CO and NOx showed bimodal diurnal variations with peaks in the late morning (10:00-12:00 UTC) and in the late afternoon (17:00-20:00 UTC). Strong correlations between CO and NOx indicated that vehicular emission was the major contributor to the notable CO plumes observed at the sampling site. Both local meteorology and backward trajectory analyses suggest that CO plumes were associated with anthropogenically polluted air masses transferred by an advection to the site from densely populated city sites. Furthermore, a good linear correlation of R2 = 0.54 between CO and O3 (∆O3/∆CO=0.560±0.016 ppbv/ppbv) was observed, in good agreement with previous observations

The aim of the statistical analyses carried out was to identify similarities and to point out differences between the various tributaries of the Narew River, to identify the factors and processes responsible for the transformations occurring in the aquatic environment and finally, to identify the main sources of pollution in the river catchment. For the purposes of statistical analysis, the results of studies conducted as part of diagnostic monitoring by the General Inspectorate for Environmental Protection in 2017–2018 were used. The studies included 8 measurement points located directly on the Narew River and 17 points located on its selected left and right tributaries. Analysis of the collected results indicates that the chemical condition of the water in the Narew catchment is assessed as being poor. This observation may be due to the fact that the Narew catchment is mainly used for agricultural purposes and, in addition, there is a relatively large number of potential anthropogenic sources. As part of the analysis, two potential sources of pollution affecting water quality in the Narew catchment were identified, which include surface run-off and treated wastewater inflow.