Review on thermoelectrical properties of selected imines in neat and multicomponent layers towards organic opto-electronics and photovoltaics

Journal title

Opto-Electronics Review








Bogdanowicz, Krzysztof. A. : Military Institute of Engineer Technology, 136 Obornicka St., 50-961 Wroclaw, Poland ; Iwan, Agnieszka : Military Institute of Engineer Technology, 136 Obornicka St., 50-961 Wroclaw, Poland



chronoamperometry ; CSA ; imines ; PC71BM ; PTB7 ; thermal imaging camera ; thermoelectrical properties

Divisions of PAS

Nauki Techniczne




Polish Academy of Sciences (under the auspices of the Committee on Electronics and Telecommunication) and Association of Polish Electrical Engineers in cooperation with Military University of Technology


  1. Wang, D. et al. Recent advances in molecular design of organic thermoelectric materials. CCS Chem. 3, 2212–2225 (2021).
  2. Dong, J. et al. Organic semiconductor nanostructures: Optoelectronic properties, Modification strategy, and photocatalytic applications. J Mater. Sci. Tech. (2021).
  3. Huang, D. et al. Conjugated-backbone effect of organic small molecules for n‑type thermoelectric materials with ZT over 0.2. J. Am. Chem. Soc. 139, 13013–13023 (2017).
  4. Mao, L. et al. Patching defects in the active layer of large-area organic solar cells. J. Mater.A 6, 5817–5824 (2018).
  5. Lindner, S. M. et al. Charge separation at self-assembled nano-structured bulk interface in block copolymers. Chem 45, 3364–3368 (2006).
  6. Han, Y. et al. Calibration and image processing of aerial thermal image for UAV application in crop water stress estimation. J. Sensors 2021, Article ID 5537795 (2021).
  7. Stumper, M., Kraus, J. & Capousek, L. Thermal imaging in aviation. Magazine of Aviation Development 3, 16 (2015).
  8. Thermal Imaging in the Automotive Industry. Thermascan Ltd (2021).
  9. Thermography in Chemical Industry. InfraTec GmbH (2021).
  10. Kasikowski, R. & Więcek, B. Fringing-effect losses in inductors by thermal modeling and thermographic measurements. IEEE Trans. Power Electron. 36, 9772–9786 (2021).
  11. Kucharska, M. & Jaskowska-Lemanska, J. Active thermography in diagnostics of timber elements covered with polychrome. Materials 14, 1134 (2021).
  12. Kowalski, M. Ł., Grudzień, A. & Ciurapiński, W. Detection of human faces in thermal infrared images. Meas. Syst. 28, 307–321 (2021).
  13. Teubner, J. et al. Comparison of drone-based ir-imaging with module resolved monitoring power data. Energy Procedia 124, 560–566 (2017).
  14. Irshad, Jaffery, Z. A. & Haque, A. Temperature measurement of solar module in outdoor operating conditions using thermal imaging. Infrared Phys. Technol. 92, 134–138 (2018).
  15. Gallardo-Saavedra, S. et al. Infrared thermography for the detection and characterization of photovoltaic defects: comparison between illumination and dark conditions. Sensors 20, 4395 (2020).
  16. Muttillo, M. et al. On field infrared thermography sensing for pv system efficiency assessment: results and comparison with electrical models. Sensors 20, 1055 (2020).
  17. Iwan, A. et al. Optical and electrical properties of graphene oxide and reduced graphene oxide films deposited onto glass and Ecoflex® substrates towards organic solar cells. Adv. Mater. Lett 9, 58– 65 (2018).
  18. Fryń, P. et al. Hybrid materials based on l,d-poly(lactic acid) and single-walled carbon nanotubes as flexible substrate for organic devices. Polymers 10, 1271 (2018).
  19. Fryń, P. et al. Dielectric, thermal and mechanical properties of L,D-Poly(Lactic Acid) modified by 4′-Pentyl-4-Biphenylcarbonitrile and single walled carbon nanotube. Polymers 11, 1867 (2019).
  20. Fryń, P. et al. Research of binary and ternary composites based on selected aliphatic or aliphatic–aromatic polymers, 5CB or SWCN toward biodegradable electrodes. Materials 13, 2480 (2020).
  21. Różycka, A. et al. Influence of TiO2 nanoparticles on liquid crystalline, structural and electrochemical properties of (8Z)-N-(4-((Z)-(4-pentylphenylimino)methyl)benzylidene)-4- pentylbenzenamine. Materials 12, 1097 (2019).
  22. Gonciarz, A. et al. UV-Vis absorption properties of new aromatic imines and their compositions with poly({4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl}{3-fluoro-2-[(2- ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl}. Materials 12, 4191 (2019).
  23. Bogdanowicz, K. A. Selected electrochemical properties of 4,4'-((1E,1'E)-((1,2,4-thiadiazole-3,5- diyl)bis(azaneylylidene))bis-(methaneylylidene))bis(N,N-di-p-tolylaniline) towards perovskite solar cells with 14.4% efficiency. Materials 13, 2440 (2020).
  24. Przybył, W. et al. IR thermographic camera as useful and smart tool to analyse defects in organic solar Photonics Lett. Poland 12, 25–27 (2020).
  25. Jewloszewicz, B. et al. A comprehensive optical and electrical study of unsymmetrical imine with four thiophene rings and their binary and ternary compositions with PTB7 and PC70BM towards organic RSC Adv 10, 44958 (2020).
  26. Bogdanowicz, K. A. et al. Electrochemical and optical studies of new symmetrical and unsymmetrical imines with thiazole and thiophene moieties. Electrochim Acta 332, 135476 (2020).
  27. Dylong, A. et al. Crystal structure determination of 4‐[(Di‐p‐tolylamino)‐benzylidene]‐(5‐pyridin‐ 4‐yl‐[1,3,4]thiadiazol‐2‐yl)‐imine along with selected properties of imine in neutral and protonated form with camforosulphonic acid: Theoretical and experimental studies. Materials 14, 1952 (2021).
  28. Wang, J. et al. Stimulus responsive fluorescent hyperbranched polymers and their Sci. China Chem. 53, 2409–2428 (2010).
  29. Albota, A. et al. Design of organic molecules with large two-photon absorption cross Science 281, 1653 (1998).
  30. Reinhardt, B. A. et al. Highly active two-photon dyes:  design, synthesis, and characterization toward Chem. Mater. 10, 1863 (1998)., Y. et al. Synthesis and photophysical properties of new two-photon absorption chromophores containing a diacetylene moiety as the central π-bridge. J. Mater. Chem. 13, 1575 (2000).
  31. Kim, O. K. et al. New class of two-photon-absorbing chromophores based on Chem. Mater. 12, 284 (2000).
  32. Liu, Z. Q. et al. Trivalent boron as an acceptor in donor–π–acceptor-type compounds for single- and two-photon excited fluorescence. Chem. Eur. J. 9, 5074 (2003).
  33. Abbotto, A. et al. Novel heterocycle-based two-photon absorbing dyes. Org. Lett. 4, 1495 (2002).
  34. Sek, D. et al. Hole transport triphenylamine-azomethine conjugated system: Synthesis and optical, photoluminescence and electrochemical properties. Macromolecules 41, 6653–6663 (2008).
  35. Sek, D. et al. Characterization and optical properties of oligoazomethines with triphenylamine moieties exhibiting blue, blue-green and green light. Spectrochim Acta A Mol. Biomol. Spectrosc. 72, 1–10 (2009).
  36. Gawlinska, K. et al. Searching of new, cheap, air- and thermally stable hole transporting materials for perovskite solar cells. Opto-Electron. Rev. 25, 274–284, (2017).
  37. Costa, P. M. J. F. et al. Direct imaging of Joule heating dynamics and temperature profiling inside a carbon nanotube interconnect. Nat. Commun. 2, 421 (2011).
  38. McLaren, C. T. et al. Development of highly inhomogeneous temperature profile within electrically heated alkali silicate glasses. Sci. Rep. 9, 2805 (2019).
  39. Balakrishnan, V.  et al. A generalized analytical model for Joule heating of segmented wires. Heat Transfer 140, (7), 072001 (2018).
  40. Thangaraju, S. K. & Munisamy, K. M. Electrical and Joule Heating Relationship Investigation Using Finite Element Method. in 7th International Conference on Cooling & Heating Technologies. 88, 012036 (Selangor, Malaysia, 2015).
  41. Russ, B. et al. Organic thermoelectric materials for energy harvesting and temperature control. Nat. Rev. Mater. 1, 16050 (2016).






DOI: 10.24425/opelre.2021.139754