The sodium expansion and creep strain of semi-graphitic cathodes are investigated using a modified Rapoport apparatus. To further understanding of the sodium and bath penetration damage processes, the impact of external stress fluence on the carbon cathode microstructure has been defined with XRD analysis, Raman spectroscopy and scanning electron microscope (SEM). Graphite atoms fracture into smaller fragments that are less directional than the pristine platelets, which allows for a possible filling of the cracks that thus develop by the sodium and bath during aluminum electrolysis. The average microcrystalline size (calculated by Raman spectroscopy) is reduced by the deformation. The decreased intensity and widened āGā and āDā peaks in the analysis indicate the poor order of the sheets along the stacking direction while the consistent layered graphite structure is sustained.
In this paper, the different mechanical behaviors of layered rocks with different bedding angles during uniaxial compression tests are studied. Numerical simulation models of layered rock are validated based on laboratory tests, and uniaxial compression tests are conducted by using Particle Flow Code (PFC). Using these simulations, the uniaxial compressive strength, failure patterns, development of micro-cracks, and displacement of meso particles are analyzed. When the bedding angle is similar to the failure angle, the macro failure planes develop directly along the beddings, the bedding behavior dictates the behavior of the layered rock, reducing the compressive strength.
Room temperature vulcanized (RTV) silicone rubber is widely used to prevent pollution flashover with its excellent hydrophobicity and hydrophobicity transfer. However, RTV coatings are at the risk of deterioration and failure in heavily polluted operating environment. In this paper, RTV coated insulators with different suspension heights operating in coal ash polluted areaswere sampled. Pollution degree, pollution composition and aging degree of coatings were tested. The result shows that the insoluble pollution contains Al(OH)3 filler precipitated from RTV coating, which indicates the aging of the RTV coating. The top surface coating is more affected by ultraviolet and rainwater than the bottom surface resulting in more serious degradation. As the pollution degree of the lower phase insulator is heavier than that of the upper phase insulator, the erosion effect of pollution on the RTV coating is more intense. The fillers and rubber molecules of RTV continuously precipitate into the pollution layer, leading to further aging. Therefore, the overall aging degree of the lower insulator coating is more serious than that of the upper insulator coating.