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Abstract

Biogas production has a big potential to provide clean energy. To evaluate the future production and maturity of biogas technology the generalized Weng model was proved to be effective, due to it has the minimum error. The simple algorithms to determine its parameters have been proposed. The simulation results for China, USA, and EU have been presented. The quantity and quality analysis for biogas feedstock has been carried out. Energy Return on Energy Invested (EROEI) indicator for different biofuels was considered. According to analysis done biogas from maize residue and chicken manure has high EROEI. Shannon Index was suggested to evaluate the diversity of feedstock supply. Biomass energy cost indicator was grounded to be used for feedstock energy and cost assessment. Biogas utilization pathways have been shown. Biogas boilers and CHP have the highest thermal efficiency, but biogas (biomethane) has the highest potential to earn as a petrol substitute. Utilization of biogas upgrading by-product (carbon dioxide) enhances profitability of biogas projects. Methods to assess the optimal pathways have been described.

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Authors and Affiliations

Antonina Kalinichenko
Valerii Havrysh
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Abstract

Tests for combustion of hay and sunflower husk pellets mixed with wood pellets were performed in a horizontal-feed as well as under-feed (retort) wood pellet furnace installed in boilers with a nominal heat output of 15 and 20 kW, located in a heat station. During the combustion a slagging phenomenon was observed in the furnaces. In order to lower the temperature in the furnace, fuel feeding rate was reduced with unaltered air stream rate. The higher the proportion of wood pellets in the mixture the lower carbon monoxide concentration. The following results of carbon monoxide concentration (in mg/m3 presented for 10% O2 content in flue gas) for different furnaces and fuel mixtures (proportion in wt%) were obtained: horizontal-feed furnace supplied with hay/wood: 0/100 - 326; 30/70 - 157; 50/50 - 301; 100/0 - 3300; horizontal-feed furnace supplied with sunflower husk/wood: 50/50 - 1062; 67/33 - 1721; 100/0 - 3775; under-feed (retort) furnace supplied with hay/wood: 0/100 - 90; 15/85 - 157; 30/70 - 135; 50/50 - 5179; under-feed furnace supplied with sunflower husk/wood: 67/33 - 2498; 100/0 - 3128. Boiler heat output and heat efficiency was low: 7 to 13 kW and about 55%, respectively, for the boiler with horizontal-feed furnace and 9 to 14 kW and 64%, respectively, for the boiler with under-feed furnace.

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Authors and Affiliations

Marek Juszczak
Katarzyna Lossy
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Abstract

The experiment was carried out under laboratory conditions on sterile and nonsterile humus soil treated with 1'C-2,4-dichlorophenol (DCP). The disappearance dynamics of extractable residues, and formation of the bound ones, as well as diffusion of radioactive volatile substances to the air were observed during 112 days. The results showed that disappearance of extractable residues of 2,4-DCP and binding to the soil matter run much faster in the presence of soil microorganisms than under abiotic factors. It has been stated that soil microorganisms played an important role as the regulator of free residues level in soil solution, enhanced their mineralization process. Moreover, by participation in binding of 2,4-DCP to soil matrix microorganisms also limited the release of toxic substance into the air.
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Authors and Affiliations

Alicja Lewandowska
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Abstract

In literature as well as in the university debate, we can observe the increase of interest regarding converting agricultural residues into energy. Furthermore, the energy and climate policies have encouraged the development of biogas plants for energy production. One of the most significant reasons of this escalation is that this technology may be both convenient and beneficial. The produced biogas is not only supposed to cover the energy demand like heat and electricity, the resulting digestate has the prospect of a beneficial fertilizer and can thereby influence the energy management plans. This technology is widely introduced to countries, which have large income from agriculture. Not only does this reduce the use of industrial fertilizers, but also finds use for agricultural residues. One of the countries of this type is Vietnam, which is the fifth largest exporter of rice in the world. Over 55% of greenhouse gas emission in Vietnam comes from agriculture. Using innovative technologies such as biogas, may decrease this value in near future. It may also contribute to more sustainable agriculture by decreasing traditional fields burning after the harvesting period. The goal of this research paper is to estimate the possible production of biogas from rice straw to cover the energy demand of the rice mill. Four possible scenarios have been considered in this paper, the present situation and where electricity, energy or both were covered by biogas from agricultural residues. An attempt was made to answer the question whether the amount of biogas produced from agricultural residues is enough for both: electricity and energy supply, for the rice mill. If not, how much rice straw must be delivered from other sources, from which rice is not delivered to the rice mill. The base of the assumptions during the estimation of various values were statistics from FAO and other organizations, secondary sources and data from the existing rice mill in Hậu Mỹ Bắc B in Mekong delta in Vietnam.

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Authors and Affiliations

Berenika Lewicka
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Abstract

It has already been well established that long exposure to low doses of pesticidesis linked to consumer risks. So, this study purposed to investigate the amounts of pesticide residues and potential health risks associated with them. The risk assessment was determined by two methods: 1. Pesticide toxicity index (PTI) depending on the maximum residue limit (MRL) to calculate the hazard quotient (HQ); 2. Health risk assessment (HR) using acceptable daily intake (ADI) and estimated daily intake (EDI) to calculate the health index (HI). Pesticide residues were estimated in 176samples of the most popularly consumed vegetables collected from major retailers and markets in Dakahlia, Egypt (during 2018). There were 111 samples contaminated with pesticide residues (63.1%), of which 29 samples (16.48%) were higher than the maximum residue limits (MRL).Residues of 23 compounds were found in the analyzed samples, of which chlorpyrifos was the most frequentin 33 samples (18.75%);while cypermethrin was the lowest (detected in one sample). According to WHO toxicity classification, 12 of the detected pesticides were moderately hazardous (class II), seven pesticides belonged to class III (slightly hazardous), three compounds were found in class U (unlikely to pose an acute hazard with normal use), while carbofuran is a highly toxic compound (class Ib). Also, the obtained data revealed that, the HI’s for the individual pesticides ranged from 0.0018 to 64.0% of ADI indicates no risk of adverse effects following exposure to the individual pesticides. The cumulative exposure amounts (PTI values) ranged from 1.58 in snake cucumber to 128.44 in potato tubers, indicating that, the combined risk index of pesticide residues was a significant health risk for consumers according to the individual risk index.It can be concluded that there is a need for strict regulation and regular monitoring of pesticide residues in foodstuff for consumers’ health protection.
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Bibliography


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Authors and Affiliations

Shehata E.M. Shalaby
1
ORCID: ORCID
Gehan Y. Abdou
1
Ibrahim M. El-Metwally
2
Gomaa M.A. Abou-elella
1

  1. Pests and Plant Protection Department, National Research Centre, Dokki, Cairo, Egypt
  2. Botany Department, National Research Centre, Dokki, Cairo, Egypt
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Abstract

The residual stress analysis is discussed in the paper. However, the author has not intended to present, even partially, all aspects of this very broad problem. The aim of this work has been limited to a review of conternporarily used experimental, numerical and hybrid methods, and to outline the directions of possible developments.
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Authors and Affiliations

Marek Bijak-Żochowski
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Abstract

In 2001, a total of 2125 samples of plant origin were analysed for residues of the most commonly used pesticides in Poland. Detectable residues were found in 18% of the samples, while in about 0.9% of the samples the residues exceeded national or/and EU harmonised Maximum Residue Limits (MRLs). The long-term (chronic) dietary intake, based on monitoring data, was calculated for 7 pesticides in 9 commodities. The intake of 1 of the pesticide analysed (endosulfan/black currant combination) exceeded 1 % of Acceptable Daily Intake (ADI) indicating a sufficient margin of safety for the adult consumer. The short-term (acute) intake was estimated for 19 pesticides in 12 commodities according to the European Commission recommendations. The ADI level was exceeded for toddlers in 7 cases, carbendazim in mushroom, linuron in carrot, chlorothalonil in greenhouse tomato, tolylfluanid and EBDC in strawberry and flusilazole and diazinon in apple. In all cases, however, the safety factor of 2 for a toddler still existed.
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Authors and Affiliations

Stanisław Sadło
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Abstract

Disappearance of iprodione deposits on peppers, eggplants and tomatoes grown in commercial greenhouses and in a foil tunnel were studied. It was found that iprodione residues on ripening fruits decreased according to simple regression lines. Their initial values dropped by half and reached zero levels within 2.5-2.8 and about 5 weeks after Rovral FLO 255 SC application, respectively. Iprodione deposits on pepper leaves dropped within four weeks only by 30% while on eggplant leaves in practice stayed at the same level. The chemical may be suitable for the comparative study of real disappearance of pesticides after their applications for the control of pests and diseases.
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Authors and Affiliations

Stanisław Sadło
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Abstract

The aim of this study was to monitor pesticide residues in the blood of agricultural workers (farmers, pesticide dealers, and spraying workers) living in the Dakahlia Governorate, Egypt. Residue analysis revealed that 48, 76, and 84% of the farmers, pesticide dealers, and spraying workers had pesticide residues in their bloods, respectively. Eleven compounds were detected in the blood of examined individuals. According to the World Health Organization (WHO) classification, most of these pesticides (nine pesticides) were in moderately hazardous compounds. Carbofuran, a highlyhazardous compound was the most toxic. The compound with the lowest toxicity was hexytiazox, which is unlikely to pose an acute hazard in normal use. Chlorpyrifos was found in the blood of 38.3% of the study subjects, followed by acetamiprid (11.7%) and profenofos (10.7%), while fenvalerate was the lowest occurring compound (1.3%). Of the collected samples 41.3% was free of pesticide residues, while 58.7% of the samples was contaminated. Furthermore, the amounts of all detected pesticides were below the no observable adverse effect levels (NOAEL). Also, 38.7% of the samples had only one pesticide, while 8% of them contained residues of two pesticides, and 5.3% contained more than two compounds. The worker’s age did not affect the accumulations of pesticide residues in their bodies. However, there was a strong correlation between pesticide residues accumulation and an individual’s exposure time. Therefore, from these results it can be seen that encouraging greater awareness among pesticide users of the need to improve safe usage and handling of pesticides by education, advice, and warning them of the risks involved in the misuse of these poisonous materials is highly recommended.

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Authors and Affiliations

Shehata E.M. Shalaby
ORCID: ORCID
Gehan Y. Abdou
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Abstract

The normal formulation of etofenprox was developed to nanoformulation and used against the adults of silver whitefly, Bemisia tabaci in eggplant fields. Three concentrations of both the normal and nanoformulations were used. The concentrations of etofenprox nanoformulation were one-fifth of the normal formulation. The nanosize of etofenprox ranged from 225 to 489 nm. The loading capacity of etofenprox was 60.7 ± 5.7%. The obtained results showed that the LC 50 of the normal formulation was four times more than the nanoformulation. The LC 50 for the nanoformulation was 0.9 and 3.5 ppm for the normal formulation of etofenprox. This means that the nanoformulation of etofenprox was more effective than the normal. The residues of both nano and normal formulations were determined in eggplant fruits after three applications. The obtained results showed that the residue of nanoformulation after 1 hour of treatment was 0.51 ± 0.03 compared with 0.62 ± 0.03 mg · kg –1 ± SD in normal formulation. After 1 hour of treatment the residue of etofenprox was reduced to 0.11 ± 0.1 and 0.22 ± 0.02 mg · kg –1 ± SD in nano and normal formulations, respectively. The dissipation rates of both nano and normal formulations after 1 hour were 78.3 and 64.5%, respectively. The degradation rate (K) in nanoformulation and normal etofenprox was 1.33 and 0.73 mg · kg –1 ± SD, respectively. The residue half-life (LR 50) was 0.52 and 1 day, respectively. The preharvest interval (PHI) was 6 days for both nano and normal etofenprox formulations. The results confirmed that nanoetofenprox was more effective against B. tabaci adults, with lower persistence and lower residue than the normal formulation of etofenprox.
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Authors and Affiliations

Al-kazafy Hassan Sabry
1
Aziza H. Mohamady
2
Rasha A. Sleem
2
Shaker M. Abolmaaty
3
Rania M.A. Helmy
4

  1. Pests and Plant Protection Department, National Research Centre, Giza, Egypt
  2. Bioassay Research Department, Central Agricultural Pesticides Laboratory, Agricultural Research Center, Dokki, Giza, Egypt
  3. Central Laboratory for Agriculture Climate, Agricultural Research Center, Dokki, Giza, Egypt
  4. Pesticide Residue and Environmental Pollution Department, Central Agricultural Pesticides Laboratory, Agricultural Research Center, Dokki, Giza, Egypt
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Abstract

Vibrational stress relief (VSR) treatment as a method of stress relief is currently performed on different alloys and sizes as an appropriate alternative for thermal stress relief (TSR) method. Although many studies have been performed to extend the knowledge about this process, analytical studies in the field of VSR process seems to require wider efforts to introduce the concept more clearly and extensively. In this study, a theoretical model is proposed based on an analytical equation. The proposed equation was modified in terms of required variables including frequency, amplitude, and vibration duration to encompass more practical parameters compared to the previous models. Thus, essential VSR parameters including the number of cycles as a representative of treatment duration, strain rate as a representative of frequency, and the amplitude were embedded in the model to make it comprehensively practical. Experimental tests were also performed and residual stress distribution was measured by X-ray diffractometry (XRD) method for certain points to compare the experimental results with the theoretical output. An acceptable range of conformation was observed between theoretical and experimental results.
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Authors and Affiliations

Mehdi Jafari Vardanjani
1
Jacek Senkara
2
ORCID: ORCID

  1. Department of Mechanical Engineering, Technical and Vocational University (TVU), Tehran, Iran.
  2. Department of Welding Engineering,Warsaw University of Technology,Warsaw, Poland.
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Abstract

The aim of investigations was to understand the effect of herbicides application on soil environment and residues in sugar beet. Field experiments were carried out during 1997-2001 on arable field near Wroclaw. Herbicides to weed control in sugar beet were applied at recommended dose alone and in mixture with adjuvants. Samples of soil, leaves and roots of sugar beet were taken on the day of harvest. Additional, soil samples were taken six weeks (in autumn 2000) and five months (in spring 2001) after harvest. All samples were analysed (herbicide residues) using the high-performance liquid chromatography (HPLC) with UV-detection and gas liquid chromatography (GLC) with ECD. Residues of active ingredient of herbicides determined in roots and leaves of sugar beet did not exceed acceptable values included in EU standards and herbicides use in normal agricultural practice should not present problems for following crops. Moreover, the addition of adjuvants caused an increase of the herbicide active ingredient residue in soil, leaves and roots of sugar beet samples in comparison with the treatments, where herbicides alone were used.
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Authors and Affiliations

Mariusz Kucharski
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Abstract

Method for determination of carbendazim residues in fruits, vegetables and cereals was described. The compound was extracted with methanol-hydrochloric acid mixture, and after liquid-liquid partition step with dichlorornethane, was determined by high performance liquid chromatography (HPLC) with column switching and ultraviolet (UV) detection. The average recoveries of carbendazim from fortified sample were from 68.7% ± 4.3% to 92.6% ± 4.5%, the coefficients of variation were from 2.9% to 6.3%, and the limits of quantification at "A = 279 nm were from 0.02 mg/kg to 0.2 mg/kg.
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Authors and Affiliations

Monika Michel
Bogusław Buszewski
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Abstract

The results of studies on residues of dithiocarbamate fungicides in 13 different crops during 1999-2000 are presented. According ro monitoring programme 2,226 samples of fruits and vegetables were collected from the productions sites in the whole country. The samples were analyzed for residue content by a spectrophotometric method. In 11.3% of samples the residues were detected. Residues exceeding Polish MRLs were found in 10 samples (0.5 %).
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Authors and Affiliations

Bożena Morzycka
Anna Nowacka
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Abstract

The objective of this work was to estimate the disappearance of pyrimethanil the active ingredient of Myth os 300 SC. At present, Myt hos 300 SC is commonly used for the protection of greenhouse vegetables against diseases of fungal origin. The behaviour ofpyrimethanil deposits was studied on tomato plants grown in commercial greenhouses sprayed with homogenous 0.15% aqueous solution of this plant protection product. It was found that the value of pyrimethanil residues on ripening fruits decreased by half and reached zero levels in 5. 7 and 13.7 days after Mythos 300 SC application, respectively. Pyrimethanil residues on tomato leaves decreased by half within 4.0 days and reached zero level in the first I 0.5 days. Therefore, in conditions of high infection pressure, there is a need to repeat the fungicide application as early as after 3 or 4 days after previous application of Mythos 300 SC.
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Authors and Affiliations

Stanisław Sadło
Ewa Szpytka
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Abstract

In the period of 1993-1998 six wells known as being contaminated were monitored 3-6 times per year (a total of 143 samples) for the presence of atrazine, simazine and respective chloro-dealkyl metabolites. Samples were prepared for analysis by solid phase extraction (SPE) and determination was by HPLC/UV or GC/NPD techniques, GC/MSD and HPLC/DAD were employed as secondary (confirmatory) techniques. Residues of analysed compounds were present in more than 90% of samples with exception for DeDiA that was found in 81.6% of samples. The highest concentrations of atrazine, simazine, DeA, DiA, and DeDiA were 16.80; 18.60; 7.49; 2.98 and 3.43 μgil respectively. New inputs of atrazine and simazine were observed in ground water of three wells occasionally, probably resulting from fresh herbicide treatments. In the other wells contamination was rather stagnant at lower levels (0.X mg/I).
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Authors and Affiliations

Jerzy Dąbrowski
Dariusz Drożdżyński
Stanisław Walorczyk
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Abstract

Contamination by pesticides is known to be one of the major issues that are enormously degrading the quality of food and fodder crops together with increased agricultural, environmental and aquatic pollution. Many analytical and laboratory methods are available for detection of these pesticides in products in order to maintain food security but these methods are not readily accessible to most people including farmers for on-site and onfield detection in the crops. The development of more convenient, fast, and cost-effective methods that can be easily accessed by laymen based on simple paper strips or mobile analyzers etc. are need of the time. This review includes a brief discussion about novel devices which have been introduced in the field for pesticide detection viz. easy to use colorimetric and non-colorimetric detection methods based on various electrochemical and optical sensing strategies. These techniques exhibited promising results in field of on-site pesticide detection owing to their easy production, high sensitivity and readily accessible results obtained with these portable devices. This review further describes emerging prospects, deficits and challenges associated with the application of the aforementioned sensing devices.
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Authors and Affiliations

Khushbu Gumber
1

  1. Chandigarh University, Gharuan, Mohali, Punjab, India
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Abstract

Human health risk assessment of pesticide residues in agricultural commodities is a key element of food safety strategy. The present study focused on potential risks resulting from selected fruit, vegetable and cereal samples with pesticide residues exceeding maximum residue levels (MRLs) from a 5-year survey of official control in Poland (2017–2021). A novel, common tool, the EFSA Pesticide Residue Intake Model PRIMo was used for short-term exposure calculation with embedded consumption data from EU Member States. The challenge of the research was to determine whether the International Estimated Short Time Intakes (IESTI) of toxic pesticides in the diet are acceptable or not. For the first time with long-term investigation which involved many legislative changes, we prepared a picture of the most dangerous pesticides present in fruits, vegetables and cereals for the most critical sub-populations of adults and children. We examined whether these substances have the potential to cause harm to humans. From the full spectrum of 545 analyzed pesticides, we considered 13 pesticides above safety limits in the concentration range of 0.03 to 2.5 mg · kg –1. The most frequently detected compound was the non-authorized, organophospate insecticide chlorpyrifos, which poses toxicological risks to humans. The results of acute exposure were up to 93% ARfD for adults and up to 130% for children. The Hazard Quotient (HQ) showed that consumption of agricultural plants with potential risk can be safe for adults and children, with some exceptions. Samples containing flonicamid/Brussel sprouts (HQ = 1.3) and chlorpyrifos/rucola (HQ = 1.1) could have negative health effects on humans. However, an approach which overestimates the exposure due to a worst-case scenario ensures the widest possible safety margin for the consumers.
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Authors and Affiliations

Magdalena Jankowska
1
ORCID: ORCID
Izabela Hrynko
1
ORCID: ORCID
Bożena Łozowicka
1
ORCID: ORCID

  1. Laboratory of Food and Feed Safety, Institute of Plant Protection – NRI, Bialystok, Poland
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Abstract

The fumigation toxicity of Melaleuca alternifolia (Maid. & Betche) Cheel. (Myrtales: Myrtaceae) essential oil and its major fractions was studied under laboratory conditions against adults of Sitophilus oryzae L. (Coleoptera: Curculionidae) to protect wheat grains ( Triticum aestivum L.) (Poales: Poaceae) from this global pest that destroys the host plant during storage. By analyzing M. alternifolia essential oil (EO) using GC/MS terpinen-4-ol and γ-terpinene were detected as major components. In the fumigation toxicity, M. alternifolia EO showed the highest toxicity (LC50 = 0.31 μl · l–1 air), followed by terpinen-4-ol (LC 50 = 23.65 μl · l–1 air) and γ-terpinene was the least toxic (LC 50 = 43.55 μl · l–1 air). When tested for their insecticidal activities against S. oryzae in stored wheat, no progeny emerged after 3 months of treatment with M. alternifolia EO at 10 mg · g–1 or with terpinen-4-ol and γ-terpinene for 2 months. However, none of these compounds could protect wheat grain from damage throughout the entire study period (4 months). Interestingly, all tested compounds at the highest application rate did not show any phytotoxic effects after 4 months of storage.
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Authors and Affiliations

Seham Mansour Ismail
1

  1. Department Insect Population Toxicology, Central Agricultural Pesticides Laboratory, Agriculture Research Center, 12618, Giza, Egypt
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Abstract

Contamination of water bodies by heavy metals is a continuously growing environmental issue. High concentrations of mercury (Hg) in river waters are a recognized environmental problem, because it is one of the most toxic heavy metal ions as it causes damage to the central nervous system. Its negative impact has led to the development of different methods for the treatment of effluents contaminated with Hg(II). The aim of this article is to evaluate the use of coffee ( Coffea arabica) residues as adsorbent of Mercury in an aqueous solution. Four kinetic models, including intraparticle diffusion, pseudo-first-order, pseudo-second-order, and Elovich kinetic models were applied to explore the internal mechanism of mercury adsorption. Results indicate that the pseudo-first-order and pseudo-second-order models could accurately describe the adsorption process. It means that chemical adsorption play an important role in the adsorption of mercury by activated carbon. Meanwhile, the external mass transfer process is more effective in controlling the activated carbon mercury adsorption according to the fitting result of the pseudo-first-order model. The fitting to Langmuir’s model suggested that the material surface is energetically homogeneous. The technique of contaminated biomass encapsulation proved to be safe for short-term disposal when metal recovery is not desired.
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Authors and Affiliations

Candelaria N. Tejada-Tovar
1
ORCID: ORCID
María M. Rocha-Caicedo
2
Isabel C. Paz-Astudillo
2
ORCID: ORCID

  1. Universidad de Cartagena, Faculty of Engineering, Department of Chemical Engineering, Avenida Del Consulado 48-152, Cartagena 130014, Colombia
  2. Universidad del Tolima, Faculty of Agronomic Engineering, Ibagué, Colombia
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Abstract

The aim of the study was to compare two grouping methods for regionalisation of watersheds, which are similar in respect of low flow and chosen catchments parameters (physiographic and meteorological). In the study, a residual pattern approach and cluster analysis, i.e. Ward’s method, were used. The analysis was conducted for specific low flow discharge q95 (dm3∙s–1∙km–2). In the analysis, 50 catchments, located in the area of the upper and central Vistula River basin, were taken. Daily flows used in the study were monitored from 1976 to 2016. Based on the residual pattern approach (RPA) method, the analysed catchments were classified into two groups, while using the cluster analysis method (Ward’s method) – into five. The predictive performance of the complete regional regression model checked by cross-validation R2cv was 47% and RMSEcv = 0.69 dm3∙s–1∙km–2. The cross validation procedure for the cluster analysis gives a predictive performance equal to 33% and RMSEcv = 0.81 dm3∙s–1∙km–2. Comparing both methods, based on the cross-validated coefficient of determination (R2cv), it was found that the residual pattern approach had a better fit between predicted and observed values. The analysis also showed, that in case of both methods, an overestimation of specific low flow discharge q95 was observed. For the cross-validation method and the RPA method, the PBIAS was –10%. A slightly higher value was obtained for the cross-validation method and models obtained using cluster analysis for which the PBIAS was –13.8%.
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Authors and Affiliations

Agnieszka Cupak
1
ORCID: ORCID
Bogusław Michalec
1
ORCID: ORCID

  1. University of Agriculture in Krakow, Faculty of Environmental Engineering and Land Surveying, al. Mickiewicza 21, 31-120 Kraków, Poland
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Abstract

The biodiversity of aqueous environments has been affected due to the disposal of wastewater highly contaminated with heavy metal ions, causing much damage to ecosystems. These pollutants are very toxic and bioaccumulate in living organisms. This work attempts to evaluate the adsorption of nickel ad cadmium ions using three biomasses from agricultur-al residues (corn cob – CC, orange peel – OP, and oil palm bagasse – PB) modified with alumina nanoparticles. The bio-masses were characterized via compositional analysis and a point of zero charges to quantify the presence of lignin, cellu-lose, hemicellulose, and the feasible pH, taking advantage of the biomass charge. After modification with Al2O3 nanoparti-cles. The resulting adsorbents were characterized via FT-IR analysis to identify the functional groups that most contributed to the adsorption performance. Furthermore, the influence of Al2O3 nanoparticles was analysed on the adsorption capacities of the evaluated biomasses using batch systems at a temperature of 25°C and pH 6. All biomasses displayed a high content of cellulose, estimating a weight percentage of about 19.9%, 14.3%, and 13.1% for PB, OP, and CC samples, respectively. The FT-IR spectrum confirmed hydroxyl and carboxyl functional groups, which contribute to enhancing the adsorption capacities of the modified biomasses. Functional adsorption capacity was observed for all biomasses after modification with Al2O3 nanoparticles, achieving at pH 6.0 a cadmium removal from 92% (CC-Al2O3 and PB-Al2O3) up to 95.8±0.3% (OP-Al2O3). In nickel ions, it was estimated a broader adsorption capacity at pH 6.0 of about 86±0.4% after using the CC-Al2O3 sample, 88±0.1% for the PB-Al2O3 adsorbent, and 98±0.2% for the OP-Al2O3 sample, confirming the suitability of these Al2O3-modified biomasses for the removal of heavy metal ions.
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Authors and Affiliations

Adriana Herrera-Barros
1
ORCID: ORCID
Candelaria Tejada-Tovar
1
ORCID: ORCID
Angel D. Gonzalez-Delgado
1
ORCID: ORCID

  1. University of Cartagena, Avenida del Consulado Calle 30 No. 48-152, Cartagena, Bolívar, Colombia
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Abstract

A wireless sensor system is an essential aspect in many fields. It consists of a great deal of sensor nodes. These sensor networks carry out a number of tasks, including interaction, distribution, recognition, and power supply. Data is transmitted from source to destination and plays an important role. Congestion may occur during data transmission from one node to another and also at cluster head locations. Congestion will arise as a result of either traffic division or resource allocation. Energy will be wasted due to traffic division congestion, which causes packet loss and retransmission of removed packets. As a result, it must be simplified; hence there are a few Wireless sensor networks with various protocols that will handle Congestion Control. The Deterministic Energy Efficient Clustering (DEC) protocol, which is fully based on residual energy and the token bucket method, is being investigated as a way to increase the energy efficiency. In the event of congestion, our proposal provides a way to cope with it and solves it using this method to improve lifespan of the sensor networks. Experiments in simulation show that the proposed strategy can significantly enhance lifetime, energy, throughput, and packet loss.
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Authors and Affiliations

Habibulla Mohammad
1
K. Phani Rama Krishna
1
Ch Gangadhar
1
Riazuddin Mohammed
2

  1. PVP Siddhartha Institute of Technology, India
  2. University of Alberta, Edmonton, AB, Canada

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