The removal of nitrates from aqueous solutions is cumbersome because of their high solubility in water. The use of zero-valent iron (ZVI) for the reduction of nitrates is the chemical process and it is an alternative method to the biological ones. The aim of the present study was to evaluate the eff ectiveness of nitrates removal from water solution by using the ZVI process. The process was coupled with the removal of COD, phosphates and turbidity by using by-products of nitrates reduction. Batch tests were performed to evaluate the eff ectiveness of ZVI in the removal of nitrates from aqueous solutions. The eff ectiveness of nitrates removal was analyzed after 5, 10, 20, 30 and 60 min. and compared to the initial concentration of pollutants. Simultaneously analysis of ammonium nitrogen and nitrites was controlled to identify products of nitrates reduction under various pH. The removal of COD, phosphates and turbidity was also performed in batch tests. The eff ectiveness of the emoval by using three types of chemicals was compared – PIX, FeSO4, and waste Fe2+/Fe3+ from the ZVI process. The results obtained in the study indicate that ZVI can be eff ectively used in the treatment of water polluted with nitrates and the by-products of the process could be further applied in the removal of COD, phosphates and turbidity. Based on the results the method should be advised as a promising alternative to the technologies used nowadays under technical scale as a technology that fits with a circular economy.
In this article a three-dimensional mathematical model of radiofrequency ablation during open-heart surgery is presented. It was developed to study temperature field distribution into myocardial tissue. This model uses an anatomically correct 3D model for the left atrium, obtained by magnetic resonance imaging (MRI) processing of a patient; takes into account thermoelectric characteristic differences depending on the area of electric current application; considers cooling by the air flow. An ex-vivo experiment on the pig’s heart was performed where the depth of myocardium tissue damage was measured for the model validation. It was shown that the deviation of the model data from the experiment is within the limits of instrumental measurement error. The developed model is proposed to be used for heart ablation procedures planning, or new equipment development.
Ultrasonic processing in the cavitation mode is used to produce the composite materials based on the metal matrix and reinforcing particles of micro- and nano-sizes. In such a case, the deagglomeration of aggregates and the uniform distribution of particles are the expected effects. Although the particles can not only fragment in the acoustic field, they also can coagulate, coarsen and precipitate. In this paper, a theoretical study of processes of deagglomeration and coagulation of particles in the liquid metal under ultrasonic treatment is made. The influence of various parameters of ultrasound and dispersion medium on the dynamics of particles in the acoustic field is considered on the basis of the proposed mathematical model. The criterion of leading process (coagulation or deagglomeration) has been proposed. The calculated results are compared with the experimental ones known from the scientific literature.
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